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Demonstrating oxy-fuel combustion of pulverized forest residues in a down-fired furnace with external flue gas recirculation
Thermochemical Energy Conversion Laboratory, Department of Applied Physics and Electronics, Umeå University, Umeå, 90187, Sweden.
Thermochemical Energy Conversion Laboratory, Department of Applied Physics and Electronics, Umeå University, Umeå, 90187, Sweden.
RISE Research Institutes of Sweden, Bioeconomy and Health, Biorefinery and Energy.ORCID iD: 0000-0002-9395-9928
Thermochemical Energy Conversion Laboratory, Department of Applied Physics and Electronics, Umeå University, Umeå, 90187, Sweden.
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2027 (English)In: Fuel, ISSN 0016-2361, E-ISSN 1873-7153, Vol. 429Article in journal (Refereed) Published
Abstract [en]

Solid biomass oxy-fuel combustion with external recirculation was demonstrated in a 100-kW atmospheric, down-fired combustor operated close to stoichiometry. The external recirculation setup comprised a particulate filter, a condenser, a fan and O2 addition before the burner inlet. A theoretical description of the recirculation process is presented and validated. Two fuels, softwood (SW) and forest residues (FR), with similar residence times, were compared. Gaseous species, including potassium (K) compounds (atomic K, KOH, and KCl), and gas temperature were quantified in real-time by tunable diode laser absorption spectroscopy (TDLAS) and photofragmentation TDLAS at two locations in the reactor core. Major species (CO2, H2O, O2, and N2) were also measured at the exhaust. Flue gas particles collected with a low-pressure impactor at the exhaust were analyzed by X-ray powder diffraction and scanning electron microscopy. The average CO2 purity (dry) was 90 % for SW and 86 % for FR. The NO concentration was higher for FR due to the larger nitrogen content in the fuel. The gaseous K species concentrations were higher for FR than for SW (factor 2–3), but not as high as expected from the difference in fuel K content (factor 7), likely due to the high content of Si and Al in FR. Gas-phase K was significantly lower than predicted by thermodynamic equilibrium calculations (TEC), probably due to K adsorption by soot particles. The fine and coarse particle concentrations were significantly higher for FR than for SW due to the higher ash content of FR. The FR fine mode particles consisted mainly of K2SO4 and KCl, in good quantitative agreement with TEC of gas phase condensation. Apatite, Ca5(PO4)3OH, likely formed from vaporized Ca and P, was found in the fine mode in all recirculation cases

Place, publisher, year, edition, pages
Elsevier BV , 2027. Vol. 429
Keywords [en]
Forest residues, Laser spectroscopy, Oxy-fuel combustion, Potassium, Recirculation, Solid biomass
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:ri:diva-82222DOI: 10.1016/j.fuel.2026.140753Scopus ID: 2-s2.0-105045818064OAI: oai:DiVA.org:ri-82222DiVA, id: diva2:2089929
Available from: 2026-08-05 Created: 2026-08-05 Last updated: 2026-08-05Bibliographically approved

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Wiinikka, HenrikSepman, Alexey

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