This research presents a novel approach to 28 (Formula presented.) impulse radio ultra-wideband (IR-UWB) transmission using pulse position modulation (PPM) over an analog radio-over-fiber (ARoF) link, investigating the impact of fiber-based fronthaul on the overall performance of the communication system. In this setup, an arbitrary waveform generator (AWG) is employed for PPM signal generation, while demodulation is performed with a commercial time-to-digital converter (TDC) based on an event timer. To enhance the reliability of transmitted reference PPM (TR-PPM) signals, the transmission system integrates Gray coding and Consultative Committee for Space Data Systems (CCSDS)-standard-compliant Reed-Solomon (RS) error correcting code (ECC). System performance was evaluated by transmitting pseudorandom binary sequences (PRBSs) and measuring the bit error ratio (BER) across a 5-m wireless link between two 20 (Formula presented.) gain horn (Ka-band) antennas, with and without a 20 (Formula presented.) single-mode optical fiber (SMF) link in transmitter side and ECC at the receiver side. The system achieved a BER of less than 8.17 × 10−7, using a time bin duration of 200 (Formula presented.) and a pulse duration of 100 (Formula presented.), demonstrating robust performance and significant potential for space-to-ground telecommunication applications.