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A calorimeter for analyzing ejected and non-ejected heat during Li-ion battery thermal runaway
RISE Research Institutes of Sweden, Safety and Transport, Fire and Safety. Department of Chemistry - Ångström Laboratory, Uppsala University, Box 358, Uppsala, 751 21, Sweden.ORCID iD: 0000-0003-2160-8034
RISE Research Institutes of Sweden, Safety and Transport, Fire and Safety.ORCID iD: 0000-0001-7163-1692
RISE Research Institutes of Sweden, Safety and Transport, Fire and Safety. Division of Fire Safety Engineering, Lund University, Box 118, Lund, 221 00, Sweden.ORCID iD: 0000-0003-3690-387x
Department of Chemistry - Ångström Laboratory, Uppsala University, Box 358, Uppsala, 751 21, Sweden.
2025 (English)In: iScience, E-ISSN 2589-0042, Vol. 28, no 7, article id 112941Article in journal (Refereed) Published
Abstract [en]

Thermal runaway in lithium-ion battery cells poses significant safety risks due to rapid heat generation and potential thermal propagation within a battery system. This study investigates the total heat released and the fraction of energy contained in gas and particles ejected during thermal runaway using a purpose-built calorimeter setup. The results show that the fraction of ejected heat is significantly influenced by the state of charge (SOC) and cell mass loss. Notably, the non-ejected heat was higher at 75% SOC compared to 100% SOC due to higher fraction of ejected heat at high SOC. This will have implications in thermal propagation scenarios. Additionally, the study compares the results with accelerating rate calorimetry tests, highlighting the limitations of the latter in measuring the total heat released during thermal runaway. The findings show the need for comprehensive testing methods that can improve thermal management and safety in battery systems.

Place, publisher, year, edition, pages
Elsevier Inc. , 2025. Vol. 28, no 7, article id 112941
Keywords [en]
Energy storage, Energy systems, Thermal engineering
National Category
Energy Engineering Other Physics Topics
Identifiers
URN: urn:nbn:se:ri:diva-79430DOI: 10.1016/j.isci.2025.112941Scopus ID: 2-s2.0-105009512384OAI: oai:DiVA.org:ri-79430DiVA, id: diva2:2017792
Note

Article; Granskad

Available from: 2025-12-01 Created: 2025-12-01 Last updated: 2025-12-01Bibliographically approved

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Willstrand, OlaPushp, MohitAndersson, Petra

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