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Lab-scale versus industrial-scale thermal runaway tests for lithium-ion battery cells
RISE Research Institutes of Sweden, Safety and Transport, Fire and Safety. Department of Chemistry - Ångström Laboratory, Uppsala University, Box 358, Uppsala, 751 21, Sweden.ORCID iD: 0000-0003-2160-8034
Department of Chemistry - Ångström Laboratory, Uppsala University, Box 358, Uppsala, 751 21, Sweden; Scania Technical Centre, Scania CV AB, Södertälje, 151 87, Sweden.
RISE Research Institutes of Sweden, Safety and Transport, Fire and Safety. Division of Fire Safety Engineering, Lund University, Box 118, Lund, 221 00, Sweden.ORCID iD: 0000-0003-3690-387x
Department of Chemistry - Ångström Laboratory, Uppsala University, Box 358, Uppsala, 751 21, Sweden.
2025 (English)In: Journal of Energy Storage, ISSN 2352-152X, E-ISSN 2352-1538, Vol. 129, article id 117275Article in journal (Refereed) Published
Abstract [en]

Lithium-ion battery safety is a topic of large importance, and testing is associated with large costs. Safety evaluation is therefore needed also at an early stage in cell design and development, in order to evaluate potential short-comings or to screen large platforms of materials and cells. Previous thermal runaway tests on lab-scale cells have, however, indicated differences in heat release and temperature increase as compared to commercial cells. On the other hand, these could also vary between different commercial cells due to differences in cell materials, size, format, and design. In this work, thermal runaway characteristics of industrial-scale cells are compared against each other as well as with lab-scale cells. Tests were performed on lab-scale coin cells and five different industrial-scale cells ranging from 5 to 157 Ah, covering different cell formats and materials. The coin cells were built using electrodes and separator extracted from one of the industrial-scale cells. The results show that the thermal runaway will be less violent and reach lower maximum temperatures using lab-scale cells, depending on the lower proportion of active materials as compared to inactive components. It is also shown that the ratio between cell capacity and heat capacity is a useful indicator for the comparability of thermal runaway scenarios. This ratio varies considerably for small cells, but not so much for different commercial cells. The data available suggests that a cell capacity of at least 1 Ah is needed to achieve a good comparison of the thermal runaway scenario with larger commercial cells.

Place, publisher, year, edition, pages
Elsevier Ltd , 2025. Vol. 129, article id 117275
Keywords [en]
Gas production, Heat production, Lab-scale cell, Li-ion battery, Thermal runaway, Cell design, Cell-be, Cell/B.E, Gas productions, Industrial scale, Ion batteries, Lithium ions, Thermal runaways, Gas fuel manufacture
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:ri:diva-79402DOI: 10.1016/j.est.2025.117275Scopus ID: 2-s2.0-105006976098OAI: oai:DiVA.org:ri-79402DiVA, id: diva2:2017652
Note

Article; Granskad

Available from: 2025-12-01 Created: 2025-12-01 Last updated: 2025-12-03Bibliographically approved

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Willstrand, OlaAndersson, Petra

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