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Effect of thermomechanical pulp fibers and clay on the characteristics of high- and low-density polyethylene biocomposites
RISE Research Institutes of Sweden, Bioeconomy and Health, Sustainable Materials and Packaging.
RISE Research Institutes of Sweden, Bioeconomy and Health, Sustainable Materials and Packaging.
SINTEF, Norway.
SINTEF, Norway.
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2025 (English)In: Polymer Composites, ISSN 0272-8397, E-ISSN 1548-0569, Vol. 46, no 11, p. 10460-Article in journal (Refereed) Published
Abstract [en]

This study focused on the performance evaluation of clay and thermomechanical pulp (TMP) fiber to reinforce low- and high-density polyethylene (LDPE and HDPE) biocomposites. A 23 factorial experiment was designed using two levels of clay, TMP fibers, and PE as variables. Mechanical properties, thermal behavior, melt flow index, and water absorption were evaluated. In HDPE, the partial replacement of TMP fiber with 10 wt% clay increased the melting point. Clay also reduced the main polymer degradation temperature in both matrices (LDPE and HDPE). The mechanical properties of the samples with 20 wt% fiber and 10 wt% clay were similar to or better than those containing 30 wt% TMP, that is, tensile strength and modulus of 34 and 2700 MPa, compared to 30 and 2400 MPa, respectively. Although the water absorption increased with the addition of TMP fiber and clay, the water absorption of the composite with 20 wt% TMP and 10 wt% clay was relatively low and similar to the biocomposite containing 30 wt% TMP, that is, 1.15 and 1.07% after 30 days, respectively. The comparable properties of biocomposites with 30 wt% TMP and biocomposites with 20 wt% TMP and 10 wt% clay demonstrate the potential of clay to reduce the cost of the final product. Highlights: Clay enhances the tensile modulus and strength, and reduces the color darkening, compared to TMP. TMP fibers and clay reduce the melt flow index, elongation, and impact toughness. TMP fibers and clay increase the melting point and reduce the degradation temperature. Reduction in production costs of biocomposites by adding inorganic clay filler. 

Place, publisher, year, edition, pages
John Wiley and Sons Inc , 2025. Vol. 46, no 11, p. 10460-
Keywords [en]
Bulk Density; Clay products; Fracture toughness; High modulus textile fibers; Melting point; Polyethylenes; Pulp materials; Thermomechanical pulp; Thermomechanical pulping process; Biocomposite; Cellulose fiber; Impact energy; Lower density; Mechanical; Melt-flow index; Polyethylene biocomposite; Property; Pulp fibers; Thermo-mechanical; Tensile strength
National Category
Materials Engineering
Identifiers
URN: urn:nbn:se:ri:diva-78406DOI: 10.1002/pc.29632Scopus ID: 2-s2.0-85219727767OAI: oai:DiVA.org:ri-78406DiVA, id: diva2:1998794
Note

The Research Council of Norway supported the study through the knowledge-building WoBiCo project “From wood to sustainable biocomposites” (Grant no. 328773).

Available from: 2025-09-17 Created: 2025-09-17 Last updated: 2025-09-23Bibliographically approved

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Chinga Carrasco, Gary

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