Ändra sökning
Avgränsa sökresultatet
1 - 28 av 28
RefereraExporteraLänk till träfflistan
Permanent länk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Träffar per sida
  • 5
  • 10
  • 20
  • 50
  • 100
  • 250
Sortering
  • Standard (Relevans)
  • Författare A-Ö
  • Författare Ö-A
  • Titel A-Ö
  • Titel Ö-A
  • Publikationstyp A-Ö
  • Publikationstyp Ö-A
  • Äldst först
  • Nyast först
  • Skapad (Äldst först)
  • Skapad (Nyast först)
  • Senast uppdaterad (Äldst först)
  • Senast uppdaterad (Nyast först)
  • Disputationsdatum (tidigaste först)
  • Disputationsdatum (senaste först)
  • Standard (Relevans)
  • Författare A-Ö
  • Författare Ö-A
  • Titel A-Ö
  • Titel Ö-A
  • Publikationstyp A-Ö
  • Publikationstyp Ö-A
  • Äldst först
  • Nyast först
  • Skapad (Äldst först)
  • Skapad (Nyast först)
  • Senast uppdaterad (Äldst först)
  • Senast uppdaterad (Nyast först)
  • Disputationsdatum (tidigaste först)
  • Disputationsdatum (senaste först)
Markera
Maxantalet träffar du kan exportera från sökgränssnittet är 250. Vid större uttag använd dig av utsökningar.
  • 1.
    Bender, R.
    et al.
    DECHEMA eV, Germany.
    Tidblad, Johan
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Zheludkevich, M.
    Helmholtz-Zentrum Hereon, Germany.
    Corrosion challenges towards a sustainable society2022Ingår i: Materials and corrosion - Werkstoffe und Korrosion, ISSN 0947-5117, E-ISSN 1521-4176, Vol. 73, nr 11, s. 1730-1751Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    A global transition towards more sustainable, affordable and reliable energy systems is being stimulated by the Paris Agreement and the United Nation's 2030 Agenda for Sustainable Development. This poses a challenge for the corrosion industry, as building climate-resilient energy systems and infrastructures brings with it a long-term direction, so as a result the long-term behaviour of structural materials (mainly metals and alloys) becomes a major prospect. With this in mind “Corrosion Challenges Towards a Sustainable Society” presents a series of cases showing the importance of corrosion protection of metals and alloys in the development of energy production to further understand the science of corrosion, and bring the need for research and the consequences of corrosion into public and political focus. This includes emphasis on the limitation of greenhouse gas emissions, on the lifetime of infrastructures, implants, cultural heritage artefacts, and a variety of other topics. © 2022 The Authors. 

  • 2.
    Bonin, Pierre
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion. Université de Toulouse, France.
    Roggero, Aurelien
    Université de Toulouse, France.
    Caussé, Nicolas
    Université de Toulouse, France.
    Pébère, Nadine
    Université de Toulouse, France.
    Thierry, Dominique
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Le Bozec, Natalie
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Impedance analysis of the barrier effect of coil-coated materials: Water uptake and glass transition variations2021Ingår i: Progress in organic coatings, ISSN 0300-9440, E-ISSN 1873-331X, Vol. 153, artikel-id 106163Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    In the present work, an industrial polyester coil-coated steel sample was characterized by electrochemical impedance spectroscopy. The diagrams were obtained for various immersion times in a 0.5 M NaCl solution for three different initial states of the same coil coating (as received, dried and dried after the impedance measurements). The aim of the study was to have a better knowledge of how the water uptake influences the coil coating physical properties and to extract relevant parameters of the ageing processes. From the high-frequency part of the impedance diagrams, the water uptake was calculated using a linear rule of mixtures. Two sorption regions were observed for the dried samples suggesting the presence of porosities already filled with ambient moisture for the as-received sample. It was shown that the water uptake was a slow process and, independently of the initial state of the sample, a saturation plateau was never reached, even after 456 h of immersion. A time constant, clearly visible on the phase angle of the impedance diagrams, was analysed through the dielectric permittivity formalism and attributed to the signature of the dielectric manifestation of the glass transition. This time constant was shifted to higher frequencies with increasing water fraction (increasing immersion time), consistent with a plasticization effect. This result was supported by differential scanning calorimetry measurements. Finally, the data obtained for the different initial states of the coating highlighted that, even if the water uptake was reversible, the sorption kinetics was different for the sample dried after the impedance measurements. This could be of importance in the degradation process of the coil coated steel. 

  • 3.
    Boubitsas, Dimitrios
    RISE., SP – Sveriges Tekniska Forskningsinstitut, CBI Betonginstitutet AB, Betong & Berg. Lund University, Sweden.
    Chloride transport and chloride threshold values: studies on concretes and mortars with Portland cement and limestone blended cement2016Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
    Abstract [en]

    Reinforced concrete is one of the most widely used building materials and if it is properly designed and produced, it is an extremely durable material with a service life up to 100 years. However, under certain environmental conditions the service life of reinforced concrete structures is more limited. Deterioration ofconcrete structure is in most cases caused by the penetration of aggressive media from the surrounding environment. Chloride initiated reinforcement corrosion is one of the major causes of deterioration of Concrete structures. One conflicting issue is how replacing Portland cement with mineral additions influences chlorideinitiated reinforcement corrosion. This issue is of immediate interest, as there is a steady growth in the use of cement blended with mineral additions, such as blast-furnace slag, fly ash and limestone filler. This is done by the cement and concrete industry to reduce the CO2 emissions linked to Portland cement manufacturing, bylimiting the use of clinker in the cement.The main objective of this work has been to further clarify the role of limestone filler as partial substitute to Portland cement on the two main decisive parameters for chloride induced reinforcement corrosion: chloride ingress rate and chloride threshold values. In the first part of this work the chloride ingress was studied both with accelerated laboratory methods and also after field exposure. The initial focus for the second part of the study was to determine the chloride threshold values for the binders investigated in the first part, so a comprehensive view of the effect of limestone addition on chloride initiated corrosion could be presented.However, during the work the need for the development of a practice-related method for determining the chloride threshold values was identified and the focus of the research was redirected to meet that need.The efficiency of limestone filler concerning chloride ingress showed to be dependent on replacement ratio, time (age) and on the test method. It was not possible to draw any rigid conclusion of the limestone filler’s efficiency regarding chloride ingress. But part of the inconsistency in the results was identified to be that limestone filler has two opposite effects on chloride ingress, on one hand contribute to a refinement of microstructure and on the other hand diminishing the chloride binding.The steel surface condition was shown to have a strong effect on the corrosion initiation, and can likely be one of the most decisive parameters attributing to the variability in the reported chloride threshold values obtained in laboratory experiments. The chloride threshold value for the sulphate resistant Portland cement fromthe laboratory experiments was estimated to be about 1% by weight of binder. For the concrete with limestone blended cement (CEM II/A-LL 42.5R) tested in this work the chloride threshold value was at the same level as for the sulphate resistant Portland cement. From the field study but with a somewhat different definition ofchloride threshold value, a chloride threshold value of about 1% by weight of binder was also estimated for ordinary Portland cement and sulphate resistance Portland with 5% silica fume exposed to marine environment.

  • 4.
    Bulidon, Nicolas
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Pélissier, Krystel
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Boissy, Clément
    M.E.C.M Rond-point de l'échangeur, France.
    Mendibide, Christophe
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Maillot, Valérie
    Andra, France.
    Bourbon, Xavier
    Andra, France.
    Crusset, Didier
    Andra, France.
    Hydrogen production through aluminium corrosion in a cement-based matrix2023Ingår i: Materials and corrosion - Werkstoffe und Korrosion, ISSN 0947-5117, E-ISSN 1521-4176, Vol. 74, nr 11-12, s. 1765-1776Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    In France, deep geological disposal is considered for the storage of high and intermediate-level long-lived radioactive wastes. For aluminium, the possibility to encapsulate the wastes in a cement-based matrix is studied. However, cement being an alkaline environment, aluminium can lose its passivity, starts to corrode leading to hydrogen evolution in the infrastructures and generate a possible explosive hazard after decades of storage if hydrogen can accumulate somewhere in the facility. It is therefore necessary to study the corrosion behaviour of aluminium in the different cements considered for the encapsulation to estimate the possible amount of hydrogen that could be generated through corrosion and design the cement capsules accordingly. This work mainly focused on the reaction occurring at the aluminium-cement interface. Raman spectroscopy did not highlight significant differences in the nature of the corrosion products forming at the cement/aluminium interface, leading to the conclusion that it is not the chemistry of the cement that is the key factor controlling the corrosion rate but rather the physical properties of the cement matrix. 

  • 5.
    Caussé, Nicolas
    et al.
    Université de Toulouse, France.
    Bonin, Pierre
    RISE Research Institutes of Sweden, Material och produktion, Korrosion. Université de Toulouse, France.
    Thierry, Dominique
    RISE Research Institutes of Sweden, Material och produktion, Korrosion. Université de Toulouse, France.
    Le Bozec, Nathalie
    Université de Lyon, France.
    Roggero, Aurelien
    Université de Lyon, France.
    Pébère, Nadine
    Université de Toulouse, France.
    Ageing processes of coil-coated materials: Temperature-controlled electrochemical impedance analysis2023Ingår i: Progress in organic coatings, ISSN 0300-9440, E-ISSN 1873-331X, Vol. 183, artikel-id 107682Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    In the present work, an industrial polyester coil-coated steel was characterized by electrochemical impedance spectroscopy (EIS) during immersion in a 0.5 M NaCl solution for different temperatures (30, 40, 50 and 60 °C). The objective was to propose a methodology to follow the ageing of the coil-coated system, from the first stage of water uptake until the blistering appearance. Relevant parameters were extracted from the EIS diagrams to analyse ageing processes of the polymer and of the metal/polymer interface. Water uptake was determined from the high-frequency part of the impedance diagrams using a linear rule of mixtures. By increasing the temperature, both the water uptake kinetics and the water content in the coating increased. The effect of water uptake on the physical structure of the coating (plasticization) was discussed through the analysis of a time constant corresponding to the dielectric manifestation of the polymer glass transition. At 40, 50 and 60 °C, appearance of corrosion was detected on the impedance spectra by a decrease, at low frequency, of the impedance modulus and of the phase angle. For 60 °C, the corroded surface area as a function of time, was assessed from the EIS data analysis with adapted equivalent circuits. The corroded surface areas followed similar trend as blister surface areas determined from images analysis.

  • 6.
    Ejenstam, Lina
    et al.
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Polymer och fiber. KTH Royal Institute of Technology, Sweden.
    Swerin, Agne
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Material och ytteknik. KTH Royal Institute of Technology, Sweden.
    Pan, Jinshan
    KTH Royal Institute of Technology, Sweden.
    Claesson, Per M.
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Material och ytteknik. KTH Royal Institute of Technology, Sweden.
    Corrosion protection by hydrophobic silica particle-polydimethylsiloxane composite coatings2015Ingår i: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 99, s. 89-97Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    In this study, the time-dependent corrosion protection ability of 10-15. μm thin polydimethylsiloxane-nanoparticle composite coatings was evaluated using mainly open circuit potential and electrochemical impedance spectroscopy measurements. The best result was obtained for the coating containing 20. wt% hydrophobic silica nanoparticles, where it was possible to achieve protection for almost 80 days in 3. wt% NaCl solution. The protective properties offered by this coating are suggested to be due to a synergistic effect of the hydrophobicity of the polydimethylsiloxane matrix and the prolonged diffusion path caused by addition of hydrophobic silica particles.

  • 7.
    Ejenstam, Lina
    et al.
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Polymer och fiber. KTH Royal Institute of Technology, Sweden.
    Tuominen, Mikko
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Material och ytteknik.
    Haapanen, Janne
    Tampere University of Technology, Finland.
    Mäkelä, Jyrki M.
    Tampere University of Technology, Finland.
    Pan, Jinshan
    KTH Royal Institute of Technology, Sweden.
    Swerin, Agne
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Material och ytteknik. KTH Royal Institute of Technology, Sweden.
    Claesson, Per M.
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Material och ytteknik. KTH Royal Institute of Technology, Sweden.
    Long-term corrosion protection by a thin nano-composite coating2015Ingår i: Applied Surface Science, ISSN 0169-4332, E-ISSN 1873-5584, Vol. 357, nr Part B, s. 2333-2342Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    We report and discuss the corrosion protective properties of a thin nano-composite coating system consisting of an 11μm thick polyester acrylate (PEA) basecoat, covered by an approximately 1-2μm thick layer of TiO2 nanoparticles carrying a 0.05μm thick hexamethyl disiloxane (HMDSO) top coat. The corrosion protective properties were evaluated on carbon steel substrates immersed in 3wt% NaCl solution by open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) measurements. The protective properties of each layer, and of each pair of layers, were also evaluated to gain further understanding of the long-term protective properties offered by the nano-composite coating. The full coating system showed excellent corrosion protective properties in the corrosive environment of 3wt% NaCl-solution for an extended period of 100 days, during which the coating impedance, at the lower frequency limit (0.01Hz), remained above 108 Ωcm2. We suggest that the excellent corrosion protective properties of the complete coating system is due to a combination of (i) good adhesion and stability of the PEA basecoat, (ii) the surface roughness and the elongated diffusion path provided by the addition of TiO2 nanoparticles, and (iii) the low surface energy provided by the HMDSO top coat.

  • 8.
    Fast, Lars
    et al.
    RISE - Research Institutes of Sweden.
    Lang, Jenny
    RISE - Research Institutes of Sweden.
    Nygren, Kristian
    Impact Coatings AB, Sweden.
    Bodén, Andreas
    PowerCell AB, Sweden.
    Baumann Ofstad, Axel
    PowerCell AB, Sweden.
    Leisner, Peter
    RISE - Research Institutes of Sweden. Jönköping University, Sweden.
    Successful Development of Coating for Bipolar Plates for Proton exchange Membrane Fuel Cell2015Ingår i: EAST Forum 2015, 2015Konferensbidrag (Refereegranskat)
  • 9.
    Hedberg, Y. S.
    et al.
    KTH Royal Institute of Technology, Sweden; Karolinska Institute, Sweden.
    Pradhan, S.
    KTH Royal Institute of Technology, Sweden.
    Cappellini, F.
    Karolinska Institute, Sweden.
    Karlsson, M. -E
    KTH Royal Institute of Technology, Sweden.
    Blomberg, Eva
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Life Science. KTH Royal Institute of Technology, Sweden.
    Karlsson, H. L.
    Karolinska Institute, Sweden.
    Odnevall Wallinder, I.
    KTH Royal Institute of Technology, Sweden.
    Hedberg, J. F.
    KTH Royal Institute of Technology, Sweden.
    Electrochemical surface oxide characteristics of metal nanoparticles (Mn, Cu and Al) and the relation to toxicity2016Ingår i: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 212, s. 360-371Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Most metal nanoparticles (NPs), except noble metal NPs, rapidly form a thin surface oxide in ambient conditions. The protective properties of these oxides improve or worsen depending on the environment, e.g., the human lung. Several properties, including the chemical/electrochemical stability and defect density, determine the capacity of these surface oxides to hinder the bulk metal from further oxidation (corrosion). The aim of this study was to investigate whether electrochemical surface oxide characterization of non-functionalized base metal NPs of different characteristics (Al, Mn and Cu) can assist in understanding their bioaccessibility (metal release) in cell media (DMEM+) and their cytotoxic properties following exposure in lung epithelial (A549) cells. The composition and valence states of surface oxides of metal NPs and their electrochemical activity were investigated using an electrochemical technique based on a graphite paste electrode to perform cyclic voltammetry in buffer solutions and open circuit potential measurements in DMEM+. The electrochemical surface oxide characterization was complemented and verified by Raman spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The open circuit potential trends in DMEM+ correlated well with metal release results in the same solution, and provided information on the kinetics of oxide dissolution in the case of Cu NPs. Extensive particle agglomeration in cell medium (DMEM+) was observed by means of photon-cross correlation spectroscopy for all metal NPs, with sedimentation taking place very quickly. As a consequence, measurements of the real dose of added non-functionalized metal NPs to cell cultures for cytotoxicity testing from a sonicated stock solution were shown necessary. The cytotoxic response was found to be strongly correlated to changes in physico-chemical and electrochemical properties of the surface oxides of the metal NPs, the most potent being Cu NPs, followed by Mn NPs. No cytotoxicity was observed for Al NPs. The electrochemical surface oxide characterization corresponded well with other tools commonly used for nanotoxicological characterization and provided additional information.

  • 10.
    Helbert, Varvara
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Nazarov, Andrei
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Taryba, Maryna
    Universidade de Lisboa, Portugal.
    Vucko, Flavien
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Montemor, Fatima
    Universidade de Lisboa, Portugal.
    Thierry, Dominique
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Kinetics of corrosion reactions on press hardened steel in atmospheric conditions under thin electrolyte films2023Ingår i: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 458, artikel-id 142500Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Steels with high mechanical performance are prone to hydrogen embrittlement and environmental assisted cracking. Under atmospheric corrosion conditions, the source of hydrogen can be the steel corrosion process itself or galvanic coupling with a metallic coating. Electrochemical behaviour of Press Hardened Steel (PHS) under electrolyte films of different thicknesses using local electrochemical techniques was studied on a fundamental level. Scanning Vibrated Electrode Technique (SVET) was applied to study the evolution and localization of the corrosion process during PHS immersion in NaCl electrolyte. Kelvin Probe (KP) was used as a reference electrode to obtain cathodic and anodic polarization curves on PHS surfaces which were covered by thin electrolyte films (60 to 500 µm) of 0.1 M NaOH and 0.6 M NaCl. For both electrolytes, a strong increase in the oxygen reduction rate due to the decreasing of electrolyte thickness has been clearly demonstrated. Data are correlated well with a theoretical plot determined by Nernst-Fick equation. The influence of the rust layers on the kinetics of corrosion reactions under thin electrolyte films was investigated using KP. © 2023

  • 11.
    Helbert, Varvara
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Rioual, S.
    University of Brest, France.
    Le Bozec, Nathalie
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Thierry, Dominique
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Corrosion behavior of additively manufactured AISI 316L stainless steel under atmospheric conditions2022Ingår i: Materials and corrosion - Werkstoffe und Korrosion, ISSN 0947-5117, E-ISSN 1521-4176, Vol. 73, nr 11, s. 1833-Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    This study investigated the corrosion behavior of AISI 316L produced by direct energy deposition (DED). Microstructural and chemical analysis showed a homogeneous distribution of Si and Si–Mn inclusions of 0.5–1 µm and the Cr and Mo enrichment within interdendritic areas. Scanning Kelvin probe analysis of additively manufactured stainless steel highlighted a regular “striped-like” surface potential feature with a potential gradient of 30 mV for a mean value of 0.320 ± 0.017 V versus standard hydrogen electrode. It can be related to the presence of the residual stress in the oxide film and the complex thermal history due to the fabrication process. A cyclic corrosion test simulating atmospheric conditions revealed the same corrosion properties for stainless steel fabricated by DED compared to cold rolled one. Various surface preparations of 316L were also exposed for corrosion tests. It was found that the “as-received” and “brushed” surfaces exhibited poorer corrosion resistance due to the presence of an as-build defective layer. However, prior passivation of brushed surface, machining, or mechanical grinding down to P1200 improve significantly the corrosion resistance. © 2022 French Corrosion Institute part of RISE Research Institutes of Sweden. Materials and Corrosion published by Wiley-VCH GmbH.

  • 12.
    Jafarzadeh, Shadi
    et al.
    KTH Royal Institute of Technology, Sweden.
    Claesson, Per M.
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Material och ytteknik. KTH Royal Institute of Technology, Sweden.
    Sundell, Per-Erik
    SSAB EMEA AB, Sweden.
    Tyrode, Eric
    KTH Royal Institute of Technology, Sweden.
    Pan, Jinshan
    KTH Royal Institute of Technology, Sweden.
    Active corrosion protection by conductive composites of polyaniline in a UV-cured polyester acrylate coating2016Ingår i: Progress in organic coatings, ISSN 0300-9440, E-ISSN 1873-331X, Vol. 90, s. 154-162Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Polyaniline doped with phosphoric acid (PANI-PA) was synthesized and characterized by impedance and Raman spectroscopy. Exposure to UV-light resulted in a slight decrease in the PANI's electrical conductivity and no significant change in the oxidation state (of an emeraldine salt). Composite coatings containing 0, 1, 3 and 5 wt.% PANI-PA in a UV-curable polyester acrylate (PEA) resin were prepared and applied on polished carbon steel. Closely packed PANI-PA particles of several tens of nanometers were observed inside the composite coating by scanning electron microscopy, and a connected conductive network across the film was detected by Peak Force TUNA atomic force microscopy. The evolution of open circuit potential and impedance data during long-term exposure to 3 wt.% NaCl electrolyte revealed that the short-term barrier-type corrosion protection provided by the insulating PEA coating can be turned into a long-term and active protection by addition of as little as 1 wt.% PANI-PA to the formulation. Stable ennoblement in the corrosive media was observed for the coatings containing conducting polymer up to 3 wt.%. However, higher content of PANI-PA (5 wt.%) led to poorer protective properties, probably due to the hydrophilicity of PANI-PA facilitating water transport in the coating and the presence of potentially weaker spots in the film. An iron oxide layer was found to fully cover the metal surface beneath the coatings containing PANI-PA after final failure observed by electrochemical testing.

  • 13.
    Kharitonov, Dimitry
    et al.
    Polish Academy of Sciences, Poland.
    Zimowska, Malgorzata
    Polish Academy of Sciences, Poland.
    Ryl, Jacek
    Gdansk University of Technology, Poland.
    Zieliński, Artur
    Gdansk University of Technology, Poland.
    Osipenko, Maria
    Belarusian State Technological University, Belarus.
    Adamiec, Janusz
    Silesian University of Technology, Poland.
    Wrzesińska, Angelika
    Lodz University of Technology, Poland.
    Claesson, Per M.
    RISE Research Institutes of Sweden. KTH Royal Institute of Technology, Sweden.
    Kurilo, Irina
    Belarusian State Technological University, Belarus.
    Aqueous molybdate provides effective corrosion inhibition of WE43 magnesium alloy in sodium chloride solutions2021Ingår i: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 190, artikel-id 109664Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Corrosion and corrosion inhibition of WE43 magnesium alloy were investigated in NaCl solutions containing different amounts of sodium molybdate. Electrochemical, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. Electrochemical data showed that Na2MoO4 inhibitor provides reliable inhibition at concentrations at and above 100 mM. Raman and XPS spectroscopy demonstrated that the formed surface layer consists of mixed Mo(V, IV) species. This layer provided inhibition with an efficiency of 91–99 % after 24 h of exposure. A two-step oxidation-reduction mechanism of corrosion inhibition of the WE43 alloy by aqueous molybdates was proposed. © 2021 The Author(s)

  • 14.
    Larché, Nicolas
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Leballeur, Charles
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Diler, Erwan
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Thierry, Dominique
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Crevice Corrosion of High-Grade Stainless Steels in Seawater: A Comparison Between Temperate and Tropical Locations2023Ingår i: Corrosion, ISSN 0010-9312, E-ISSN 1938-159X, Vol. 79, nr 9, s. 1106-1117Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The corrosion risk for stainless steel components is not the same in all seawaters, with more failures generally reported in tropical seas. In this study, the influence of biofilm on electrochemical behavior and corrosion resistance of passive films of high-grade alloys was studied in different seawaters, including temperate seawater (France-Brest, North Atlantic Ocean), tropical seawater (Malaysia-Kelatan, Meridional China Sea), and intermediate conditions in terms of temperature (Brazil-Arraial do Cabo, South Atlantic Ocean). The stabilized open-circuit potentials and the polarization behavior of high-grade stainless steels were measured as a function of temperature in all of the tested field marine stations, providing quantified data and direct comparison of the biofilm-enhanced corrosion risks. Significant differences were measured in tropical and in temperate seawaters in heated conditions. Above 37°C, the biofilm activity was much more pronounced in tropical seawater compared to Atlantic Ocean sites, leading to much higher localized corrosion risk. Crevice corrosion of eight high-grades passive alloys was also studied with the use of crevice formers specifically developed for tube geometries. Duplex UNS S32205, superduplex UNS S32750, hyperduplex UNS S33207 and S32707, and 6Mo stainless steels UNS S31266 have been evaluated together with Ni-based alloys UNS N06845 and N06625. In the more severe conditions, the high-grade alloys UNS S32707 and the 6%Mo UNS S31266, both with pitting resistant equivalent number (PREN) around 50, showed better performance than commonly used superduplex UNS S32750 and UNS S39274 (PREN 40). The corrosion results are discussed regarding the monitored biofilm-induced depolarization measured in the different test conditions.

  • 15.
    Li, Jing
    et al.
    KTH Royal Institute of Technology, Sweden.
    Ecco, Luiz
    University of Trento, Italy.
    Ahniyaz, Anwar
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Material och ytteknik.
    Fedel, Michele
    RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Kemi Material och Ytor, Material och ytteknik.
    Pan, Jinshan
    KTH Royal Institute of Technology, Sweden.
    In situ AFM and electrochemical study of a waterborne acrylic composite coating with CeO2 nanoparticles for corrosion protection of carbon steel2015Ingår i: Journal of the Electrochemical Society, ISSN 0013-4651, E-ISSN 1945-7111, Vol. 162, nr 10, s. C610-C618Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The corrosion protection of a waterborne acrylic composite coating with 1 wt% ceria nanoparticles (CeNP) coated on carbon steel in 3 wt% NaCl solution was investigated by ex-situ and in situ as well as electrochemical atomic force microscopy (AFM) observations, combined with open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) measurements. The synthesized CeNP were stabilized by acetic acid. The transmission electron microscopy characterization showed fine nano-size of as-synthesized CeNP, the ex-situ AFM imaging revealed uniform dispersion of the CeNP in the composite coating and greatly reduced nano-sized pinholes in the coating. The in situ and electrochemical (EC) AFM investigations indicate release of some CeNP and aggregates from the coating surface and then precipitation of some particles and cerium-compounds during the exposure. The OCP and EIS results demonstrated that the addition of 1 wt% CeNP leads to a significantly improved long term barrier type corrosion protection of the waterborne acrylic composite coating for carbon steel in 3 wt% NaCl solution. The beneficial effect of the CeNP is attributed to the blocking of nano-sized defects and inhibition by the cerium compounds originated from the acetic acid stabilized CeNP.

  • 16.
    Linder, Clara
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion. Linköping University, Sweden.
    Mehta, Bharat
    Chalmers University of Technology, Sweden; KTH Royal Institute of Technology, Sweden.
    Sainis, Salil
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Lindén, Johan B
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Zanella, Caterina
    Jönköping University, Sweden; Trento University, Italy.
    Nyborg, Lars
    Chalmers University of Technology, Sweden.
    Corrosion resistance of additively manufactured aluminium alloys for marine applications2024Ingår i: npj Materials Degradation, ISSN 2397-2106, Vol. 8, nr 1, artikel-id 46Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Additive manufacturing opens new possibilities for designing light-weight structures using aluminium alloys. The microstructure of two Al alloys and their corrosion resistance in NaCl and natural seawater environments were investigated. The newly designed Al-Mn-Cr-Zr based alloy showed a higher corrosion resistance than reference AlSi10Mg alloy in both environments in as printed and heat-treated conditions. The corrosion initiated in the Al matrix along the precipitates in the alloys where the Volta potential difference was found the highest. The coarser microstructure and precipitate composition of the new Al-alloy led to the formation of a resistant passive film which extended the passivity region of the Al-Mn-Cr-Zr alloy compared to the AlSi10Mg alloy. The effect of heat treatment could be seen in the microstructure as more precipitates were found in between the melt pool boundaries, which affected the corrosion initiation and slightly the pitting resistance. Overall, this study shows that a newly designed Al-alloy for additive manufacturing has a suitable corrosion resistance for applications in marine environments. .

    Ladda ner fulltext (pdf)
    fulltext
  • 17.
    Linder, Clara
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Metodik för produktframtagning. Linköping University, Sweden.
    Rao, S. G.
    Linköping University, Sweden.
    Boyd, R. D.
    Linköping University, Sweden.
    Le Febvrier, A.
    Linköping University, Sweden.
    Eklund, P.
    Linköping University, Sweden.
    Munktell, S.
    Swerim AB, Sweden.
    Björk, E. M.
    Linköping University, Sweden.
    Corrosion Resistance and Catalytic Activity toward the Oxygen Reduction Reaction of CoCrFexNi (0 ≤ x ≤ 0.7) Thin Films2022Ingår i: ACS Applied Energy Materials, E-ISSN 2574-0962, Vol. 5, nr 9, s. 10838-10848Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Corrosion resistance and catalytic activity toward the oxygen reduction reaction (ORR) in an alkaline environment are two key properties for water recombination applications. In this work, CoCrFexNi (0 ≤ x ≤ 0.7) thin films were deposited by magnetron sputtering on polished steel substrates. The native passive layer was 2-4 nm thick and coherent to the columnar grains determined by transmission electron microscopy. The effect of Fe on the corrosion properties in 0.1 M NaCl and 1 M KOH and the catalytic activity of the films toward ORR were investigated. Electrochemical impedance spectroscopy and potentiodynamic polarization measurements indicate that CoCrFe0.7Ni and CoCrFe0.3Ni have the highest corrosion resistance of the studied films in NaCl and KOH, respectively. The high corrosion resistance of the CoCrFe0.7Ni film in NaCl was attributed to the smaller overall grain size, which leads to a more homogeneous film with a stronger passive layer. For CoCrFe0.3Ni in KOH, it was attributed to a lower Fe dissolution into the electrolyte and the build-up of a thick and protective hydroxide layer. Scanning Kelvin probe force microscopy showed no potential differences globally in any of the films, but locally, a potential gradient between the top of the columns and grain boundaries was observed. Corrosion of the films was likely initiated at the top of the columns where the potential was lowest. It was concluded that Fe is essential for the electrochemical activation of the surfaces and the catalytic activity toward ORR in an alkaline medium. The highest catalytic activity was recorded for high Fe-content films (x ≥ 0.5) and was attributed to the formation of platelet-like oxide particles on the film surface upon anodization. The study showed that the combination of corrosion resistance and catalytic activity toward ORR is possible for CoCrFexNi, making this material system a suitable candidate for water recombination in an alkaline environment. 

  • 18.
    Mendibide, Christophe
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Dessolin, Carole
    Metal'in, France.
    Selective Dissolution Forming on Duplex Stainless Steels during Sour Testing. Is it a Pass or a Fail?2023Ingår i: Corrosion, ISSN 0010-9312, E-ISSN 1938-159X, Vol. 79, nr 2, s. 174-192Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    In this study, the effect of test conditions on the formation of selective dissolution during sour testing was investigated on a cold-rolled duplex stainless steel UNS S32750. All experiments were conducted in NaCl 150 g/L and pH2S = 0.3 bar. Different pHs between 3.3 and 4.5 were studied at 80°C. Based on tests performed under varying conditions, it is demonstrated that selective dissolution (SD) competes with cracking and that under conditions leading to the formation of a large area with SD, the presence of this type of corrosion can hide the susceptibility of the material to cracking. The presence of only SD after testing must therefore be considered with caution. SD initiated also without applied stress showing that the phenomenon is correlated to a loss of passivity. From electron backscattered diffraction (EBSD) analyses and electrochemical monitoring the formation of SD under the test conditions considered in this work is correlated to the instability of the passive film and not to any superficial singularities of the material or specific crystallographic orientations. 

  • 19.
    Mendibide, Christophe
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Vucko, Flavien
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Martinez, M
    IFP Energies Nouvelles, France.
    Joshi, GR
    IFP Energies Nouvelles, France.
    Kittel, J
    IFP Energies Nouvelles, France.
    Effect of degraded environmental conditions on the service behavior of a X65 pipeline steel not designed for hydrogen transport2024Ingår i: International journal of hydrogen energy, ISSN 0360-3199, E-ISSN 1879-3487, Vol. 52, s. 1019-Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    With the international drive to deploy green energies and decarbonized intermediates in the place of fossil fuel sources, a large number of developed countries are actively preparing for a future where hydrogen plays a strategic role as an energy storage medium. Producing and using hydrogen requires the rapid expansion of a dedicated, economically viable industrial sector. Nevertheless, questions on how to safely store, transport and distribute hydrogen remain an important priority today. In countries with existing natural gas transport grids, the possibility to retrofit these networks to store and transport hydrogen-natural gas blends is being studied. A key challenge is to evaluate how pressurized H2 would interact with steel structures with regards structural embrittlement of the latter, with a view to exploiting existing transport infrastructures for storage and transport applications. In this work, we evaluate the H2-performance of a non-hydrogen service ×65 pipeline steel. The cracking susceptibility of this steel grade has been evaluated at 100 bar H2 using slow strain rate testing, Constant strain testing and fracture toughness measurements. Accompanying hydrogen permeation tests under pressure provide diffusion data and elucidate the discussion. Exposures were carried out in dry or wet H2 and with or without H2S contamination at levels representative of biogas. The results underline that the impact of dry or wet hydrogen on this grade are moderate. The presence of traces of H2S together with humidity could risk seriously degrading the mechanical performance of the ×65 steel grade. © 2023 The Authors

    Ladda ner fulltext (pdf)
    fulltext
  • 20.
    Moya Nunez, Alice
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Norling, Rikard
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Effect of KCl on high-temperature corrosion of low-alloyed steel under low oxygen partial pressure2024Ingår i: Materials and corrosion - Werkstoffe und Korrosion, ISSN 0947-5117, E-ISSN 1521-4176Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Low oxygen environments in biomass gasification and the presence of chlorine in feedstocks can influence the corrosion rate of steel by affecting the formation of protective oxide scales. The effect of KCl on the high-temperature corrosion of low-alloyed steel (13CrMo4-5) under low oxygen partial pressure is investigated by KCl salt spray (0.1 mg·cm−2) and exposure to 3 vol% H2 + 30 vol% H2O + Ar (balance) at 500°C for up to 168 h. Specimens without KCl salt are exposed for reference. Specimens are characterized after exposure by mass change, SEM/EDS, and XRD. KCl-deposited specimens exhibit about 30% lower mass gain after exposure compared to non-sprayed specimens. Their scale shows a porous innermost layer and a denser layer on top. No Fe or Cr chlorides are identified. The specimens without salt exhibit a similar two-layered scale, with a porous inner Fe-Cr oxide, followed by a denser and thicker Fe-oxide above. KCl could potentially protect the surface from further degradation by physically covering the specimen, altering the scale morphology, and forming a less permeable barrier, hindering the transport of species through the scale. 

    Ladda ner fulltext (pdf)
    fulltext
  • 21.
    Nagels, Maarten
    et al.
    KU Leuven, Belgium.
    Verhoeven, Brent
    KU Leuven, Belgium.
    Larché, Nicolas
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Dewil, Raf
    KU Leuven, Belgium.
    Rossi, Barbara
    KU Leuven, Belgium; University of Oxford, UK.
    Corrosion behaviour of lean duplex stainless steel in advanced oxidation process (AOP) based wastewater treatment plants2022Ingår i: Engineering Failure Analysis, ISSN 1350-6307, E-ISSN 1873-1961, Vol. 136, artikel-id 106170Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The corrosion of lean duplex stainless steel alloys is examined when applied as a construction material in advanced oxidation processes. Both electrochemical and immersion experiments have been carried out when subjecting wastewater to ozone or Fenton oxidation. The electrochemical experiments suggest that the presence of dissolved ozone at the levels tested does not result in an increased pitting susceptibility for none of the alloys included in the research. However, the application of Fenton reagents induces pitting corrosion to the studied lean duplex alloys. The immersion experiments highlight that crevice corrosion occurs during wastewater treatment with both ozone and Fenton reagents. 

  • 22.
    Peltier, Fabienne
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Thierry, Dominique
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Development of Reliable Accelerated Corrosion Tests for Aluminum Alloys Used in the Aerospace Industry2023Ingår i: Corrosion, ISSN 0010-9312, E-ISSN 1938-159X, Vol. 79, nr 9, s. 1006-1016Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Aluminum alloys are not immune to corrosion which can take the form of localized corrosion. Thus, the assessment of the corrosion behavior of aluminum alloys under atmospheric conditions is a major topic for the aerospace industry. One major difficulty in this task is the lack of robust and reliable accelerated corrosion test(s) in this field. Indeed, several tests as the neutral salt spray test (ASTM B117) are used to assess the general corrosion resistance of aluminum, but these tests were not developed specifically for the aerospace industry and are not representative of service conditions. The aim of the present study was to compare the results of various accelerated corrosion test conditions (ASTM B117, VDA 233-102, Volvo STD 423-0014) with newly developed test conditions. Hence, different accelerated corrosion tests were designed by varying several parameters in the Volvo STD 423-0014 such as the salt concentration, time of wetness, and relative humidity. The results obtained on eight aluminum alloys (2xxx, 7xxx, and Al-Li alloys) were then compared to marine exposures. From the results, one test provides the same type of corrosion attacks on the different alloys under atmospheric exposures in the marine site and a good acceleration factor.

  • 23.
    Peltier, Fabienne
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Thierry, Dominique
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Long-term atmospheric corrosion of Cr-free painted aluminum alloys during outdoor worldwide exposures2023Ingår i: Materials and corrosion - Werkstoffe und Korrosion, ISSN 0947-5117, E-ISSN 1521-4176, Vol. 74, nr 7, s. 1022-Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Cr-free paints applied on different aluminum alloys were exposed for 5 years at different atmospheric weathering sites worldwide. By image analysis, the extent, and the type of corrosion (filiform or blistering) were determined after 1, 2, and 5 years. In that way, it was possible to rank the different systems as a function of their resistance to corrosion. The kinetics of degradation of each system at all sites was also determined. From the results, it is shown that the kinetics of degradation is system dependent. It is also shown that it is the combination of several climatic parameters which contributes to the corrosivity of the site and not only one single parameter such as chloride deposition, relative humidity, and so on. 

  • 24.
    Peltier, Fabienne
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Thierry, Dominique
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Review of Cr-Free Coatings for the Corrosion Protection of Aluminum Aerospace Alloys2022Ingår i: Coatings, ISSN 2079-6412, Vol. 12, nr 4, artikel-id 518Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Aluminum alloys are known to have many advantages (e.g., light weight and low cost) but they are not immune to corrosion. So, it is important to assess their corrosion behavior, in particular under atmospheric conditions. To protect aluminum alloys against corrosion, paints are generally applied onto the materials. Corrosion protection in the aerospace industry consists of a conversion or anodized coating, an inhibited primer, and a top-coat. Chromate conversion coating (CCC) and primers containing chromate pigments have been widely used in the aerospace industry over the last decades. However, new environmental regulations have led to major changes for aluminum corrosion protection. By limiting or prohibiting some chemicals, for instance Cr(VI), the European regulation REACH (Regulation on Registration Evaluation, Authorization and Restriction of Chemicals) has induced major changes to some of the finishing processes of aluminum alloys (e.g., chromate conversion, chromic acid anodizing, and chromate sealing). Interesting results have been obtained while seeking replacements for Cr(VI), for example, with the incorporation of cerium, lithium salt, or nanocontainers loaded with corrosion inhibitors in organic coatings. For several years, hybrid sol–gel coatings able to replace the pre-treatment and primer steps have been under development, showing interesting results. New prospects for the future involve the use of photo-polymerization to reduce the energy-intensive heat treatment needed in sol–gel technology. It will also be necessary to test these new technologies in service conditions or in accelerated corrosion tests before being able to conclude on the real effectiveness of these coatings. This review summarizes the recent developments in Cr-free coatings for aluminum alloys. Their advantages and draw-backs are also discussed. 

  • 25.
    Prestat, Michel
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Corrosion of structural components of proton exchange membrane water electrolyzer anodes: A review2023Ingår i: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 556, artikel-id 232469Artikel, forskningsöversikt (Refereegranskat)
    Abstract [en]

    Proton exchange membrane (PEM) water electrolysis is one of the low temperature processes for producing green hydrogen when coupled with renewable energy sources. Although this technology has already reached a certain level of maturity and is being implemented at industrial scale, its high capital expenditures deriving from the utilization of expensive corrosion-resistant materials limit its economic competitiveness compared to the widespread fossil fuel-based hydrogen production, such as steam reforming. In particular, the structural elements, like bipolar plates (BPP) and porous transports layers (PTL), are essentially made of titanium protected by precious metal layers in order to withstand the harsh oxidizing conditions in the anode compartment. This review provides an analysis of literature on structural element degradation on the oxygen side of PEM water electrolyzers, from the early investigations to the recent developments involving novel anti-corrosion coatings that protect more cost-effective BPP and PTL materials like stainless steels. © 2022 The Author

  • 26.
    Pålsson, Namurata
    et al.
    RISE Research Institutes of Sweden, Material och produktion, Korrosion.
    Khamsuk, P.
    National Science and Technology Development Agency, Thailand.
    Sorachot, S.
    National Science and Technology Development Agency, Thailand.
    Wongpinkaew, K.
    National Science and Technology Development Agency, Thailand.
    Thaiwirot, W.
    King Mongkut's University of Technology North Bangkok, Thailand.
    Phaebua, K.
    King Mongkut's University of Technology North Bangkok, Thailand.
    Klomjit, P.
    National Science and Technology Development Agency, Thailand.
    Corrosion behavior of zinc and copper coated structural steels in soil environments2022Ingår i: Materialwissenschaft und Werkstofftechnik, ISSN 0933-5137, E-ISSN 1521-4052, Vol. 53, nr 1, s. 68-79Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Corrosion behavior of structural carbon steels grade SS400 coated with copper and zinc exposed to soil sample extracted from the central part of Thailand is studied using weight loss analyses and electrochemical methods, including open circuit potential monitoring for 3600 seconds, electrochemical impedance spectroscopic analyses and potentiodynamic polarization measurements. Bare carbon steels are also examined as a reference. Open circuit potential and polarization resistance of all samples are measured on (1, 2, 3, 4, 7, 10, 15, 30, 45, 60, 77 and 91) days of exposure. Corrosion potential is monitored only on the first and last days. After 91 days, corrosion rate in millimeter per year is calculated from weight loss and corrosion product is characterized. Effects of coating material, thickness and process on corrosion resistance of carbon steel subjected to soil environment are reported and discussed. 

  • 27.
    Zhu, Baiwei
    et al.
    Jönköping University, Sweden.
    Fedel, Michele
    University of Trento, Italy.
    Andersson, Nils-Eric
    Jönköping University, Sweden.
    Leisner, Peter
    RISE - Research Institutes of Sweden, Säkerhet och transport, Elektronik. Jönköping University, Sweden.
    Deflorian, Flavio
    University of Trento, Italy.
    Zanella, Caterina
    Jönköping University, Sweden.
    Effect of Si content and morphology on corrosionresistance of anodized cast Al-Si alloys2017Ingår i: Journal of the Electrochemical Society, ISSN 0013-4651, E-ISSN 1945-7111, Vol. 164, nr 7, s. C435-C441Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    This paper investigates the influence of Si content and Si particle morphology on the corrosion protection of anodized oxide layers on Al-Si alloys. Two Al alloys with low Si concentrations (2.43 wt-% and 5.45 wt-%, respectively) were studied and compared with 6082-T6 via electrochemical impedance spectroscopy (EIS) in 3 wt-% NaCl solution prior to oxide layer sealing. Si particles were also modified by the addition of Sr to study the influence of Si particle morphology on the corrosion protection of the oxide layer. The EIS showed that the corrosion protection provided by the oxide layer on Al-Si alloys is significantly affected by the presence of Si particles. Si particles make the oxide layer locally thinner and more defective in the eutectic region, thereby increasing the ease of substrate corrosion attack. However, the addition of Sr can improve the corrosion protection of anodized Al-Si alloys significantly. Furthermore, it was proved that higher Si level influences negatively the anodized oxide corrosion protection due to the higher amount of cracks and defects, but Sr modification is efficient in preventing this negative effect.

  • 28.
    Zhu, Baiwei
    et al.
    Jönköping University, Sweden.
    Fedel, Michele
    University of Trento, Italy.
    Andersson, Nils-Eric
    Jönköping University, Sweden.
    Leisner, Peter
    RISE - Research Institutes of Sweden, Säkerhet och transport, Elektronik. Jönköping University, Sweden.
    Deflorian, Flavio
    University of Trento, Italy.
    Zanella, Caterina
    Jönköping University, Sweden.
    Influence of the Srmodification and post-treatment on corrosion resistance of oxide layer of cast Al-(low)Si alloys2017Konferensbidrag (Refereegranskat)
1 - 28 av 28
RefereraExporteraLänk till träfflistan
Permanent länk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf