With the development of multicore hardware, concurrent, parallel and multicore software are becoming increasingly popular. Software companies are spending a huge amount of time and resources to nd and debug the bugs. Among all types of software bugs, concurrency bugs are also important and troublesome. This type of bugs is increasingly becoming an issue particularly due to the growing prevalence of multicore hardware. In this position paper, we propose a model for monitoring and debugging Starvation bugs as a type of concurrency bugs in multicore software. The model is composed into three phases: monitoring, detecting and debugging. The monitoring phase can support detecting phase by storing collected data from the system execution. The detecting phase can support debugging phase by comparing the stored data with starvation bug's properties, and the debugging phase can help in reproducing and removing the Starvation bug from multicore software. Our intention is that our model is the basis for developing tool(s) to enable solving Starvation bugs in software for multicore platforms.

In this paper we analyse two variants of SIMON family of light-weight block ciphers against linear cryptanalysis and present the best linear cryptanalytic results on these variants of reduced-round SIMON to date. We propose a time-memory trade-off method that finds differential/linear trails for any permutation allowing low Hamming weight differential/linear trails. Our method combines low Hamming weight trails found by the correlation matrix representing the target permutation with heavy Hamming weight trails found using a Mixed Integer Programming model representing the target differential/linear trail. Our method enables us to find a 17-round linear approximation for SIMON-48 which is the best current linear approximation for SIMON-48. Using only the correlation matrix method, we are able to find a 14-round linear approximation for SIMON-32 which is also the current best linear approximation for SIMON-32. The presented linear approximations allow us to mount a 23-round key recovery attack on SIMON-32 and a 24-round Key recovery attack on SIMON-48/96 which are the current best results on SIMON-32 and SIMON-48. In addition we have an attack on 24 rounds of SIMON-32 with marginal complexity.

We propose a simple and efficient searchable symmetric encryption scheme based on a Bitmap index that evaluates Boolean queries. Our scheme provides a practical solution in settings where communications and computations are very constrained as it offers a suitable trade-off between privacy and performance.

Characterization of the surface activity of previously obtained polymerizable dialkyl maleates is performed to find out the relation between the structure of surfactants and their performances. The given polymerizable surfactants were synthesized for using in the emulsion polymerization. Three groups of dialkyl maleates-nonionic, cationic and zwitterionic-with different chain lengths of hydrophobic alkyl groups are investigated. Critical micelle concentration (cmc) values are determined for water soluble surfactants. It is found that cmc decreases with increasing chain length of the hydrophobic alkyl group. For nonionic and cationic surfactants interfacial tension at the interface between water and dodecane is measured. Droplet size in oil-in-water (O/W) emulsions is determined for all given surfactants. Cationic and zwitterionic dialkyl maleates with the longest investigated alkyl chain (R=C16H33, C17H35) provide good stability of O/W emulsions. In order to compare the obtained results, measurements with well-known surfactants-nonionic nonylphenol-poly(ethylene oxide) (NPEO10) and cationic hexadecyltrimethyl ammonium bromide (CTAB)-are performed.

The success of the P2P idea has created a huge diversity of approaches, among which overlay networks, for example, Gnutella, Kazaa, Chord, Pastry, Tapestry, P-Grid, or DKS, have received specific attention from both developers and researchers. A wide variety of algorithms, data structures, and architectures have been proposed. The terminologies and abstractions used, however, have become quite inconsistent since the P2P paradigm has attracted people from many different communities, e.g., networking, databases, distributed systems, graph theory, complexity theory, biology, etc. In this paper we propose a reference model for overlay networks which is capable of modeling different approaches in this domain in a generic manner. It is intended to allow researchers and users to assess the properties of concrete systems, to establish a common vocabulary for scientific discussion, to facilitate the qualitative comparison of the systems, and to serve as the basis for defining a standardized API to make overlay networks interoperable.

Proteoheparan sulphate can be adsorbed to a methylated silica surface in a monomolecular layer via its transmembrane hydrophobic protein core domain. As a result of electrostatic repulsion, its anionic glycosaminoglycan side chains are stretched out into the blood substitute solution, thereby representing one receptor site for specific lipoprotein binding through basic amino acid-rich residues within their apolipoproteins. The binding process was studied by ellipsometric techniques suggesting that high-density lipoprotein (HDL) has a high binding affinity and a protective effect on interfacial heparan sulphate proteoglycan layers with respect to low-density lipoprotein (LDL) and Ca2+ complexation. Low-density lipoprotein was found to deposit strongly at the proteoheparan sulphate-coated surface, particularly in the presence of Ca2+, apparently through complex formation 'proteoglycan-LDL-calcium'. This ternary complex build-up may be interpreted as arteriosclerotic nanoplaque formation on the molecular level responsible for the arteriosclerotic primary lesion. On the other hand, HDL bound to heparan sulphate proteoglycan protected against LDL deposition and completely suppressed calcification of the proteoglycan-lipoprotein complex. In addition, HDL was able to decelerate the ternary complex deposition. Therefore, HDL attached to its proteoglycan receptor sites is thought to raise a multidomain barrier, selection and control motif for transmembrane and paracellular lipoprotein uptake into the arterial wall. Although much remains unclear regarding the mechanism of lipoprotein depositions at proteoglycan-coated surfaces, it seems clear that the use of such systems offers possibilities for investigating lipoprotein deposition at a 'nanoscopic' level under close to physiological conditions. In particular, Ca2+-promoted LDL deposition and the protective effect of HDL even at high Ca2+ and LDL concentrations agree well with previous clinical observations regarding risk and beneficial factors for early stages of atherosclerosis. Considering this, the system was tested on its reliability in a biosensor application in order to unveil possible acute pleiotropic effects of the lipid lowering drug fluvastatin. The very low-density lipoprotein (VLDL)/intermediate-density lipoprotein (IDL)/LDL plasma fraction from a high risk patient with dyslipoproteinaemia and type 2 diabetes mellitus showed beginning arteriosclerotic nanoplaque formation already at a normal blood Ca2+ concentration, with a strong increase at higher Ca2+ concentrations. Fluvastatin, whether applied to the patient (one single 80 mg slow release matrix tablet) or acutely in the experiment (2.2 μmol L-1), markedly slowed down this process of ternary aggregational nanoplaque complexation at all Ca2+ concentrations used. This action resulted without any significant change in lipid concentrations of the patient. Furthermore, after ternary complex build-up, fluvastatin, similar to HDL, was able to reduce nanoplaque adsorption and size. These immediate effects of fluvastatin have to be taken into consideration while interpreting the clinical outcome of long-term studies.

The effects of divalent salts (CaCl2, MgCl2 and BaCl2) in promoting the adsorption of weakly charged polyelectrolyte (polyacrylic acid), PAA, Mw ~ 250000 g/mol) on mica surfaces and their role in tuning the nature of interactions between such adsorbed polyelectrolyte layers were studied using the interferometric surface forces apparatus. With mica surfaces in 3 mM MgCl2 solutions at pH ~8.0-9.0, the addition of 10 ppm PAA resulted in a long-range attractive bridging force and a short-range repulsive steric force. This force profile indicates a low surface coverage and weak adsorption. The range of the force can be related to the characteristic length scale RG of polyelectrolyte chains using a scaling description. An increase of the PAA concentration to 50 ppm changed the attractive force profile to a monotonic, long-range repulsive interaction extending up to 600 Å due to the increased surface coverage of polyelectrolyte chains on the mica surfaces. Comparison of the measured forces with a scaling mean field model suggests that the adsorbed polyelectrolyte chains are stretched, which eventually give rise to the polyelectrolyte brush like structure. When the mica surfaces were preincubated in 3 mM CaCl2 at pH ~8.0-9.0, in contrast to the case of 3 mM MgCl2, the addition of 10 ppm PAA resulted in a more complex force profile: long-range repulsive forces extending up to 800 Å followed by an attractive force regime and a second repulsive force regime at shorter separations. The long-range electrosteric forces can be attributed to strong adsorption of polyelectrolyte chains on mica surfaces (high surface coverage) which is facilitated by the presence of Ca2+ ions, while the intermediate range attractive forces can be ascribed to Ca2+ assisted bridging between adsorbed polyelectrolyte chains. Also interesting is to note various relaxation processes present in this system. In contrast to both MgCl2 and CaCl2 systems, with mica surfaces in 3 mM BaCl2 solution at pH ~8.0-9.0, the addition of 10 ppm PAA resulted in precipitation of polyelectrolyte chains on mica surfaces, resulting in an extremely long-range monotonic repulsive force profile. In summary, our study showed that divalent counterions (Mg2+, Ca2+, and Ba2+) exhibit significantly different behavior in promoting PAA adsorption on mica surfaces, modifying and controlling various surface interactions.

We report on the synthesis, microstructure and mass transport properties of a colloidal hydrogel self-assembled from a mixture of colloidal silica and nontronite clay plates at different particle concentrations. The gel-structure had uniaxial long-range anisotropy caused by alignment of the clay particles in a strong external magnetic field. After gelation the colloidal silica covered the clay particle network, fixing the orientation of the clay plates. Comparing gels with a clay concentration between 0 and 0.7 vol%, the magnetically oriented gels had a maximum water permeability and self-diffusion coefficient at 0.3 and 0.7 vol% clay, respectively. Hence the specific clay concentration resulting in the highest liquid flux was pressure dependent. This study gives new insight into the effect of anisotropy, particle concentration and bound water on mass transport properties in nano/microporous materials. Such findings merit consideration when designing porous composite materials for use in for example fuel cell, chromatography and membrane technology.

The Internet traffic volume continues to grow at a great rate, now driven by video and TV distribution. For network operators it is important to avoid congestion in the network, and to meet service level agreements with their customers. This thesis presents work on two methods operators can use to reduce links loads in their networks: traffic engineering and content caching. This thesis studies access patterns for TV and video and the potential for caching. The investigation is done both using simulation and by analysis of logs from a large TV-on-Demand system over four months. The results show that there is a small set of programs that account for a large fraction of the requests and that a comparatively small local cache can be used to significantly reduce the peak link loads during prime time. The investigation also demonstrates how the popularity of programs changes over time and shows that the access pattern in a TV-on-Demand system very much depends on the content type. For traffic engineering the objective is to avoid congestion in the network and to make better use of available resources by adapting the routing to the current traffic situation. The main challenge for traffic engineering in IP networks is to cope with the dynamics of Internet traffic demands. This thesis proposes L-balanced routings that route the traffic on the shortest paths possible but make sure that no link is utilised to more than a given level L. L-balanced routing gives efficient routing of traffic and controlled spare capacity to handle unpredictable changes in traffic. We present an L-balanced routing algorithm and a heuristic search method for finding L-balanced weight settings for the legacy routing protocols OSPF and IS-IS. We show that the search and the resulting weight settings work well in real network scenarios.

Measurement and analysis of real traffic is important to gain knowledge about the characteristics of the traffic. Without measurement, it is impossible to build realistic traffic models. It is recent that data traffic was found to have self-similar properties. In this thesis work traffic captured on the network at SICS and on the Supernet, is shown to have this fractal-like behaviour. The traffic is also examined with respect to which protocols and packet sizes are present and in what proportions. In the SICS trace most packets are small, TCP is shown to be the predominant transport protocol and NNTP the most common application. In contrast to this, large UDP packets sent between not well-known ports dominates the Supernet traffic. Finally, characteristics of the client side of the WWW traffic are examined more closely. In order to extract useful information from the packet trace, web browsers use of TCP and HTTP is investigated including new features in HTTP/1.1 such as persistent connections and pipelining. Empirical probability distributions are derived describing session lengths, time between user clicks and the amount of data transferred due to a single user click. These probability distributions make up a simple model of WWW-sessions.

Several studies of Internet traffic have shown that it is a small percentage of the flows that dominate the traffic. This is often referred to as the mice and elephants phenomenon. It has been proposed that this might be one of very few invariants of Internet traffic and that this property could somehow be used for traffic engineering purposes. The idea being that one in a scalable way could control a major part of the traffic by only keeping track of a small number of flows. But for this the large flows must also be stable in the meaning that they should be among the largest flows during long periods of time. In this work we analyse packet traces of Internet traffic and study the temporal characteristics of large aggregated traffic flows defined by destination address prefixes.

Today video and TV distribution dominate Internet traffic and the increasing demand for high-bandwidth multimedia services puts pressure on Internet service providers. In this paper we simulate TV distribution with time-shift and investigate the effect of introducing a local cache close to the viewers. We study what impact TV program popularity, program set size, cache replacement policy and other factors have on the caching efficiency. The simulation results show that introducing a local cache close to the viewers significantly reduces the network load from TV-on-Demand services. By caching 4% of the program volume we can decrease the peak load during prime time by almost 50%. We also show that the TV program type and how program popularity changes over time can have a big influence on cache hit ratios and the resulting link loads.

IPTV, where television is distributed over the Internet Protocol in a single operator network, has become popular and widespread. Many telecom and broadband companies have become TV providers and distribute TV channels using multicast over their backbone networks. IPTV also means an evolution to time-shifted television where viewers now often can choose to watch the programs at any time. However, distributing individual TV streams to each viewer requires a lot of bandwidth and is a big challenge for TV operators. In this paper we present an empirical IPTV workload model, simulate IPTV distribution with time-shift, and show that local caching can limit the bandwidth requirements significantly.

The focus of this paper is on traffic engineering in ambient networks. We describe and categorize different alternatives for making the routing more adaptive to the current traffic situation and discuss the challenges that ambient networks pose on traffic engineering methods. One of the main objectives of traffic engineering is to avoid congestion by controlling and optimising the routing function, or in short, to put the traffic where the capacity is. The main challenge for traffic engineering in ambient networks is to cope with the dynamics of both topology and traffic demands. Mechanisms are needed that can handle traffic load dynamics in scenarios with sudden changes in traffic demand and dynamically distribute traffic to benefit from available resources. Trade-offs between optimality, stability and signaling overhead that are important for traffic engineering methods in the fixed Internet becomes even more critical in a dynamic ambient environment.

Dynamic Transfer Mode (DTM) is a ring based MAN technology that provides a channel abstraction with a dynamically adjustable capacity. TCP is a reliable end to end transport protocol capable of adjusting its rate. The primary goal of this work is investigate the coupling of dynamically allocating bandwidth to TCP flows with the affect this has on the congestion control mechanism of TCP. In particular we wanted to find scenerios where this scheme does not work, where either all the link capacity is allocated to TCP or congestion collapse occurs and no capacity is allocated to TCP. We have created a simulation environment using ns-2 to investigate TCP over networks which have a variable capacity link. We begin with a single TCP Tahoe flow over a fixed bandwidth link and progressively add more complexity to understand the behaviour of dynamically adjusting link capacity to TCP and vice versa.

Today increasingly large volumes of TV and video are distributed over IP-networks and over the Internet. It is therefore essential for traffic and cache management to understand TV program popularity and access patterns in real networks. In this paper we study access patterns in a large TV-on-Demand system over four months. We study user behaviour and program popularity and its impact on caching. The demand varies a lot in daily and weekly cycles. There are large peaks in demand, especially on Friday and Saturday evenings, that need to be handled. We see that the cacheability, the share of requests that are not first-time requests, is very high. Furthermore, there is a small set of programs that account for a large fraction of the requests. We also find that the share of requests for the top most popular programs grows during prime time, and the change rate among them decreases. This is important for caching. The cache hit ratio increases during prime time when the demand is the highest, and aching makes the biggest difference when it matters most. We also study the popularity (in terms of number of requests and rank) of individual programs and how that changes over time. Also, we see that the type of programs offered determines what the access pattern will look like.

Free space optics is an interesting alternative for telemetry with medical implants, due to the high data bandwidths available at optical frequencies. Especially implanted brain-computer interfaces gives rise to large data sets that needs to be transmitted transcutaneous. In this paper we show that it is possible to establish such a link at near-IR wavelengths using a modulated reflector in the implant, thus keeping the laser and the detector on the outside. In addition, we show that it will not only work on short, i.e. touch, distances but also at larger distances, in the range of a meter. We have used an electro absorption modulator to modulate the reflection of an external laser source back towards an external detector. The only part of this system that needs to be implanted is the modulator and drive electronics. The study has been done both by Monte-Carlo simulations of a multi-layer model of a rat skull, and with an experiment demonstrating the feasibility of the link when transmitted through biological tissue. The results show that it is possible to establish a transcutaneous link with an external laser source and light detector, and an internal modulated reflector.

The degradation of three- and four-ring polycyclic aromatic hydrocarbons (PAHs) in Kirk medium by Anthracophyllum discolor, a white-rot fungus isolated from the forest of southern Chile, was evaluated. In addition, the removal efficiency of three-, four- and five-ring PAHs in contaminated soil bioaugmented with A. discolor in the absence and presence of indigenous soil microorganisms was investigated. Production of lignin-degrading enzymes and PAH mineralization in the soil were also determined. A. discolor was able to degrade PAHs in Kirk medium with the highest removal occurring in a PAH mixture, suggesting synergistic effects between PAHs or possible cometabolism. A high removal capability for phenanthrene (62%), anthracene (73%), fluoranthene (54%), pyrene (60%) and benzo(a)pyrene (75%) was observed in autoclaved soil inoculated with A. discolor in the absence of indigenous microorganisms, associated with the production of manganese peroxidase (MnP). The metabolites found in the PAH degradation were anthraquinone, phthalic acid, 4-hydroxy-9-fluorenone, 9-fluorenone and 4,5-dihydropyrene. A. discolor was able to mineralize 9% of the phenanthrene. In non-autoclaved soil, the inoculation with A. discolor did not improve the removal efficiency of PAHs. Suitable conditions must be found to promote a successful fungal bioaugmentation in non-autoclaved soils. © 2010 Elsevier B.V.

Manganese peroxidase (MnP) produced by Anthracophyllum discolor, a Chilean white rot fungus, was immobilized on nanoclay obtained from volcanic soil and its ability to degrade polycyclic aromatic hydrocarbons (PAHs) compared with the free enzyme was evaluated. At the same time, nanoclay characterization was performed.Nanoclay characterization by transmission electronic microscopy showed a particle average size smaller than 100nm. The isoelectric points (IEP) of nanoclay and MnP from A. discolor were 7.0 and 3.7, respectively, as determined by micro electrophoresis migration and preparative isoelectric focusing. Results indicated that 75% of the enzyme was immobilized on the nanoclay through physical adsorption. As compared to the free enzyme, immobilized MnP from A. discolor achieved an improved stability to temperature and pH. The activation energy (Ea) value for immobilized MnP (51.9kJmol -1) was higher than that of the free MnP (34.4kJmol -1).The immobilized enzyme was able to degrade pyrene (>86%), anthracene (>65%), alone or in mixture, and to a less extent fluoranthene (<15.2%) and phenanthrene (<8.6%). Compared to free MnP from A. discolor, the enzyme immobilized on nanoclay enhanced the enzymatic transformation of anthracene in soil.Overall results indicate that nanoclay, a carrier of natural origin, is a suitable support material for MnP immobilization. In addition, immobilized MnP shows an increased stability to high temperature, pH and time storage, as well as an enhanced PAHs degradation efficiency in soil. All these characteristics may suggest the possible use of nanoclay-immobilized MnP from A. discolor as a valuable option for in situ bioremediation purposes. © 2010 Elsevier Ltd.

In this study, different growth conditions of Anthracophyllum discolor Sp4 including the effect of agitation, additions of lignocellulosic support, inducer and surfactant were evaluated on the MnP production in Kirk medium using a culture system made up of the tubes containing the glass bead. The highest MnP production (1,354 U/L on day 13) was obtained when the medium was supplemented with wheat grain and 0.25 mM MnSO 4 as inducer, under static conditions at 30°C. Two isoenzymes were purified (35 and 38 kDa respectively). MnP presented a maximal activity in the pH range between 4.5 and 5.5, a relatively high temperature tolerance (50°C) and a high catalytic activity for 2,6-dimethoxyphenol and hydrogen peroxide.

The reactivity ratios r1 (EO) and r2 (PO) for the copolymerization of ethylene oxide (EO) and propylene oxide (PO) have been determined. The reactions were carried out in dry dimethyl formamide at 90°C using the potassium salt of ethylene glycol as initiator. The polymer composition at different EO/PO ratios in the feed was determined by 1H-NMR. Using the Fineman-Ross method to calculate reactivity ratios from the values of polymer composition, rl- and r2-values of 1.8 and 0.3, respectively, were obtained.

Peer instruction is a method for activating students during lectures, which has gained a considerable amount of attention in higher education due to claims of dramatic improvement in learning gains. The purpose of this qualitative research study is to investigate what types of discussions engineering students engage in during a peer instruction session and what learning possibilities that are enabled by these different types of discussions. We observed twelve students during six separate and simulated peer instruction sessions and the students were interviewed individually after the sessions.Ananalysis of the data revealed that the students engaged in three qualitatively different types of discussions: affirmative discussions, motivating discussions, and argumentative discussions. We characterize these different types of discussions in terms of the number of alternative answers the students discuss, the extent to which they draw on prior knowledge and experiences, as well as the fundamental difference between an explanation and an argument. A good opportunity for learning is opened up when students are aspiring to find the truth, not simply being satisfied with what they believe to be true. We conclude that students do not always engage in discussions that support their learning in the best way, and we discuss implications for using peer instruction as a teaching method.

Background: Lignocellulosic substrates and pulping process streams are of increasing relevance to biorefineries for second generation biofuels and biochemical production. They are known to be rich in sugars and inhibitors such as phenolic compounds, organic acids and furaldehydes. Phenolic compounds are a group of aromatic compounds known to be inhibitory to fermentative organisms. It is known that inhibition of Sacchromyces cerevisiae varies among phenolic compounds and the yeast is capable of in situ catabolic conversion and metabolism of some phenolic compounds. In an approach to engineer a S. cerevisiae strain with higher tolerance to phenolic inhibitors, we selectively investigated the metabolic conversion and physiological effects of coniferyl aldehyde, ferulic acid, and p-coumaric acid in Saccharomyces cerevisiae. Aerobic batch cultivations were separately performed with each of the three phenolic compounds. Conversion of each of the phenolic compounds was observed on time-based qualitative analysis of the culture broth to monitor various intermediate and final metabolites. Result: Coniferyl aldehyde was rapidly converted within the first 24 h, while ferulic acid and p-coumaric acid were more slowly converted over a period of 72 h. The conversion of the three phenolic compounds was observed to involved several transient intermediates that were concurrently formed and converted to other phenolic products. Although there were several conversion products formed from coniferyl aldehyde, ferulic acid and p-coumaric acid, the conversion products profile from the three compounds were similar. On the physiology of Saccharomyces cerevisiae, the maximum specific growth rates of the yeast was not affected in the presence of coniferyl aldehyde or ferulic acid, but it was significantly reduced in the presence of p-coumaric acid. The biomass yields on glucose were reduced to 73 and 54 % of the control in the presence of coniferyl aldehyde and ferulic acid, respectively, biomass yield increased to 127 % of the control in the presence of p-coumaric acid. Coniferyl aldehyde, ferulic acid and p-coumaric acid and their conversion products were screened for inhibition, the conversion products were less inhibitory than coniferyl aldehyde, ferulic acid and p-coumaric acid, indicating that the conversion of the three compounds by Saccharomyces cerevisiae was also a detoxification process. Conclusion: We conclude that the conversion of coniferyl aldehyde, ferulic acid and p-coumaric acid into less inhibitory compounds is a form of stress response and a detoxification process. We hypothesize that all phenolic compounds are converted by Saccharomyces cerevisiae using the same metabolic process. We suggest that the enhancement of the ability of S. cerevisiae to convert toxic phenolic compounds into less inhibitory compounds is a potent route to developing a S. cerevisiae with superior tolerance to phenolic compounds.

IEEE konferens och IFIP 10:4 huvudkonferens, San Francisco

Conducting polyaniline (Pani) was prepared in the presence of methane sulfonic acid (MeSA) as dopant by chemical oxidative polymerization. The Pani–MeSA polymer was characterized by FT-IR, UV–vis, X-ray diffraction (XRD) and impedance spectroscopy. The polymer was dispersed in polyvinylacetate and coated on carbon steel samples by a dipping method. The electrochemical behavior and anticorrosion properties of the coating on carbon steel in 3% NaCl were investigated using open-circuit potential (OCP) versus time of exposure, and electrochemical techniques including electrochemical impedance spectroscopy (EIS), potentiodynamic polarization and cyclic voltammetry (CV). During initial exposure, the OCP dropped about 0.35 V and the interfacial resistance increased several times, indicating a certain reduction of the polymer and oxidation of the steel surface. Later the OCP shifted to the noble direction and remained at a stable value during the exposure up to 60 days. The EIS monitoring also revealed the initial change and later stabilization of the coating. The stable high OCP and low coating impedance suggest that the conducting polymer maintains its oxidative state and provides corrosion protection for carbon steel throughout the investigated period. The polarization curves and CV show that the conducting polymer coating induces a passive-like behavior and greatly reduces the corrosion of carbon steel.

Conducting polypyrrole electrodes were prepared by electrochemical polymerization of pyrrole on vacuum-metallized glass substrates. These electrodes were modified by doping with a range of metal halides as dopant ions having different electronegativity. Electrochemical reduction of nitrobenzene using these electrodes was studied by means of cyclic voltammetry technique in acetonitrile medium containing aqueous HClO4 (0.1M) as supporting electrolyte. It was found that the electronegativity of the dopant ion played a very important role in the electrocatalytic activity. Polypyrrole doped with nickel chloride gave the highest anodic current at the reduction potential of nitrobenzene. The results were explained on the basis of charge transfer efficiency at the electrode-electrolyte interface, which was associated with the acceptor state created by the dopant in the semi-conducting polymer.