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  • 1.
    Cedervall, Johan
    et al.
    Uppsala University, Sweden.
    Beran, Premysl
    Nuclear Physics Institute, Czech Republic.
    Vennström, Marie
    AB Sandvik, Sweden.
    Danielsson, Thererse
    Etteplan Sweden AB, Sweden.
    Ronneteg, Sabina
    AB Sandvik, Sweden.
    Höglin, Viktor
    Scienta Sauna Systems AB, Sweden.
    Lindell, David
    RISE, Swerea, KIMAB.
    Eriksson, Olle
    Uppsala University, Sweden.
    André, Gilles
    CEA-Saclay, France.
    Andersson, Yvonne
    Uppsala University, Sweden.
    Nordblad, Per
    Uppsala University, Sweden.
    Sahlberg, Martin
    Uppsala University, Sweden.
    Low temperature magneto-structural transitions in Mn3Ni20P62016In: Journal of Solid State Chemistry, ISSN 0022-4596, E-ISSN 1095-726X, Vol. 237, p. 343-348Article in journal (Refereed)
    Abstract [en]

    X-ray and neutron powder diffraction has been used to determine the crystal and magnetic structure of Mn3Ni20P6. The crystal structure can be described as cubic with space group Fm3¯m (225) without any nuclear phase transformation within studied temperature interval from room temperature down to 4 K. The magnetic structure of Mn3Ni20P6 is complex with two independent magnetic positions for the Mn atoms and the compound passes three successive magnetic phase transitions during cooling. At 30 K the spins of the Mn atoms on the Wyckoff 4a site (Mn1) order to form a primitive cubic antiferromagnetic structure with propagation vector k=(0 0 1). Between 29 and 26 K the Mn atoms on the Wyckoff 8c site (Mn2) order independently on already ordered Mn1 magnetic structure forming a commensurate antiferromagnetic structure with propagation vector k=(0 0 12) and below 26 K, both Mn positions order to form an incommensurate helical structure with propagation vector k=(0 0 ~0.45). Magnetization vs. temperature curve of Mn3Ni20P6 shows a steep increase indicating some magnetic ordering below 230 K and a sharp field dependent anomaly in a narrow temperature range around 30 K.

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