Upscaling lignin-based precursor fibre production is an essential step in developing bio-based carbon fibre from renewable feedstock. The main challenge in upscaling of lignin fibre production by melt spinning is its melt behaviour and rheological properties, which differ from common synthetic polymers used in melt spinning. Here, a new approach in melt spinning of lignin, using a spin carrier system for producing bicomponent fibres, has been introduced. An ethanol extracted lignin fraction from LignoBoost process of commercial softwood kraft black liquor was used as feedstock. After additional heat treatment, melt spinning was performed in a pilot-scale spinning unit. For the first time, biodegradable polyvinyl alcohol (PVA) was used as a spin carrier to enable the spinning of lignin by improving the required melt strength. PVA-sheath/lignin-core bicomponent fibres were manufactured. Afterwards, PVA was dissolved by washing with water. Pure lignin fibres were stabilized and carbonized, and tensile properties were measured. The measured properties, tensile modulus of 81.1 ± 3.1 GPa and tensile strength of 1039 ± 197 MPa, are higher than the majority of lignin-based carbon fibres reported in the literature. This new approach can significantly improve the melt spinning of lignin and solve problems related to poor spinnability of lignin and results in the production of high-quality lignin-based carbon fibres. This article is part of the theme issue 'Bio-derived and bioinspired sustainable advanced materials for emerging technologies (part 2)'. © 2021 The Author(s).
The in situ cometary dust particle instrument COSIMA (COmetary Secondary Ion Mass Analyser) onboard ESA's Rosetta mission has collected about 31 000 dust particles in the inner coma of comet 67P/Churyumov-Gerasimenko since August 2014. The particles are identified by optical microscope imaging and analysed by time-of-flight secondary ion mass spectrometry. After dust particle collection by low speed impact on metal targets, the collected particle morphology points towards four families of cometary dust particles. COSIMA is an in situ laboratory that operates remotely controlled next to the comet nucleus. The particles can be further manipulated within the instrument by mechanical and electrostatic means after their collection by impact. The particles are stored above 0°C in the instrument and the experiments are carried out on the refractory, ice-free matter of the captured cometary dust particles. An interesting particle morphology class, the compact particles, is not fragmented on impact. One of these particles was mechanically pressed and thereby crushed into large fragments. The particles are good electrical insulators and transform into rubble pile agglomerates by the application of an energetic indium ion beam during the secondary ion mass spectrometry analysis. This article is part of the themed issue 'Cometary science after Rosetta'. © 2017 The Authors.