Cellulose nanocrystals (CNCs) and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)- oxidized cellulose nanofibrils (T-CNFs) were tested as enhanced oil recovery (EOR) agents through core floods and microfluidic experiments. Both particles were mixed with low salinity water (LSW). The core floods were grouped into three parts based on the research objectives. In Part 1, secondary core flood using CNCs was compared to regular water flooding at fixed conditions, by reusing the same core plug to maintain the same pore structure. CNCs produced 5.8% of original oil in place (OOIP) more oil than LSW. For Part 2, the effect of injection scheme, temperature, and rock wettability was investigated using CNCs. The same trend was observed for the secondary floods, with CNCs performing better than their parallel experiment using LSW. Furthermore, the particles seemed to perform better under mixed-wet conditions. Additional oil (2.9–15.7% of OOIP) was produced when CNCs were injected as a tertiary EOR agent, with more incremental oil produced at high temperature. In the final part, the effect of particle type was studied. T-CNFs produced significantly more oil compared to CNCs. However, the injection of T-CNF particles resulted in a steep increase in pressure, which never stabilized. Furthermore, a filter cake was observed at the core face after the experiment was completed. Microfluidic experiments showed that both T-CNF and CNC nanofluids led to a better sweep efficiency compared to low salinity water flooding. T- CNF particles showed the ability to enhance the oil recovery by breaking up events and reducing the trapping efficiency of the porous medium. A higher flow rate resulted in lower oil recovery factors and higher remaining oil connectivity. Contact angle and interfacial tension measurements were conducted to understand the oil recovery mechanisms. CNCs altered the interfacial tension the most, while T-CNFs had the largest effect on the contact angle. However, the changes were not significant enough for them to be considered primary EOR mechanisms.

The use of wood-derived cellulose nanofibrils (CNFs) or galactoglucomannans (GGM) for emulsion stabilization may be a way to obtain new environmentally friendly emulsifiers. Both have previously been shown to act as emulsifiers, offering physical, and in the case of GGM, oxidative stability to the emulsions. Oil-in-water emulsions were prepared using highly charged (1352 ± 5 µmol/g) CNFs prepared by TEMPO-mediated oxidation, or a coarser commercial CNF, less charged (≈ 70 µmol/g) quality (Exilva forte), and the physical emulsion stability was evaluated by use of droplet size distributions, micrographs and visual appearance. The highly charged, finely fibrillated CNFs stabilized the emulsions more effectively than the coarser, lower charged CNFs, probably due to higher electrostatic repulsions between the fibrils, and a higher surface coverage of the oil droplets due to thinner fibrils. At a constant CNF/oil ratio, the lowest CNF and oil concentration of 0.01 wt % CNFs and 5 wt % oil gave the most stable emulsion, with good stability toward coalescence, but not towards creaming. GGM (0.5 or 1.0 wt %) stabilized emulsions (5 wt % oil) showed no creaming behavior, but a clear bimodal distribution with some destabilization over the storage time of 1 month. Combinations of CNFs and GGM for stabilization of emulsions with 5 wt % oil, provided good stability towards creaming and a slower emulsion destabilization than for GGM alone. GGM could also improve the stability towards oxidation by delaying the initiation of lipid oxidation. Use of CNFs and combinations of GGM and CNFs can thus be away to obtain stable emulsions, such as mayonnaise and beverage emulsions. © 2021, The Author(s).

Experiences regarding personal protection water mist systems installed in dwellings. Personal protection water mist systems can produce a water mist that can cool down and limit a fire in a small area in a dwelling. The system is equipped with sensitive detectors which can activate the system in the early stages of the fire and limit the fire spread, and in some cases extinguish the fire. This gives more time for evacuation, which can be especially important for vulnerable people with risk factors, like impaired cognitive and physical functioning. The goal of this study has been to map the experiences in Norway regarding personal protection water mist systems, considering how the municipalities have experienced the work related to the systems and whether the systems have activated and saved lives. This will shed light upon whether mobile water mist systems are appropriate measures for vulnerable people in the society, and the risk factors that determine whether the measure is appropriate or not. This study has used literature studies, questionnaires, and interviews to map the experiences of personal protection water mist systems in Norway. The results showed that personal protection water mist systems installed in Norwegian dwellings have been activated in connection with fire outbreaks, and thus limited or extinguished the fire. This has saved lives on several occasions and reduced the damage potential. There are many people who have risk factors that make it appropriate to install a mobile water mist system in their home, but there are also exceptions. The risk factors that indicate that it is beneficial to install mobile water mist systems in Norwegian dwellings are - Impaired cognitive abilities - Impaired physical abilities - Drug and alcohol problems - Smoking - Living alone The systems are particularly suitable when several of the risk factors are present at the same time. It was also shown that personal protection water mist systems are not suitable for mobile people who spend time in several places in the home and are therefore often outside the system's coverage area. Personal protection water mist systems are not recommended for people who may have the potential to sabotage the system. In questionnaires and interviews, it emerged that there are big differences between how Norwegian municipalities work with assigning, installing, operating, and maintaining personal protection water mist systems. In larger municipalities, there are more people who rely on routines and formal processes for the work, and there is therefore a greater proportion of the larger municipalities who distribute the facilities out to individuals than in the small municipalities where the work is more characterised by informal routines and personal relations. 3 Based on the results from this study, it is our opinion that the following aspects should be covered by future work: • Need for a new and updated cost-benefit analysis for personal protection water mist systems. • Need for a better statistical basis for assessment of the personal protection water mist systems. • Need for a Norwegian test standard for personal protection water mist systems. • Need for clear guidelines for assignment, procurement, installing, operation, and maintenance of personal protection water mist systems.

The Scandinavian countries have in later years seen several severe wildfires and is expected to exhibit more severe fire danger. While direct flame spread has been an important topic in wildfire research, there is a need for development and to ensure that experimental methods are relevant for Scandinavian wildfire characteristics. To ensure relevant lab conditions for fire-resilient material development work, large lab-scale (2×4 meters) experiments were conducted on various fuels. Its fire behaviour (such as rate of spread, fireline intensity and flame length) was compared with ongoing wildfire field studies from ongoing field studies in boreal and hemiboreal Sweden. The lab fire experiments show good potential to mimic relevant natural wildfire conditions in the laboratory once a standard design fire exposure for fire resilient materials is developed.

The late 90s and the early 2000s was a period with relative extensive research and innovation in the area of manual fire extinguishing methods and equipment for the fire service. New equipment such as the cutting extinguisher and extinguishing spears allowed to conduct offensive attacks from the exterior of a building, reducing the exposure of fire fighters to fire and smoke and their associated risks in general. This led to the development of new firefighting tactics, as for example the Quadrant Model of the Dutch fire service, which extends the “traditional” offensive interior attack and defensive exterior attack by the offensive exterior attack and defensive interior attack.Recently the research focus has furthermore increasingly shifted to environmental aspects, such as the water consumption and effect of additives (i.e., foam) on humans and the environment. Extinguishing with smaller amounts of water is beneficial for the environment, reduces water damage and lowers the burden on the water delivery system.ConclusionIn conclusion, the systems most relevant to be further tested in a fire situation in a small house or dwelling are the cutting extinguisher and the extinguishing spear.These systems are different in operation but have both shown to be promising with regard to fulfilling the different objectives of the overall project. Being relatively easy to utilize with the right training during internal extinguishing efforts executed from the outside of the building, and being only water based to minimize contamination, due to lower water consumption, of the surrounding areas give these systems advantages over conventional equipment.Especially if the systems are used in combination with an IR camera to locate the fire, the extinguishing efforts can be started early and effectively, and the water amount needed to control the fire may be reduced. The need for firefighters with breathing apparatus is reduced as well, hence reducing the smoke exposure to firefighters.The fact that the fire service also recognizes the potential of using these systems early in the extinguishing efforts, and is working on implementing them, prompts the need for scientific backup.

The RISE report 2019:04 «Charcoal and wood burning ovens in restaurants – Fire safety and documentation requirements» [1] investigated regulations and documental demands tied to charcoal and wood burning ovens in restaurants in Norway. A part of the conclusion in this report emphasized the need for, through physical testing, mapping whether existing test standards covers the safety requirements of charcoal ovens in restaurants. NS-EN 13240:2001 «Roomheaters fired with solid fuel. Requirements and test methods» [2] was chosen as a relevant test standard. Three test ovens (a closed test oven, a dummy oven and an open test oven) was produced at RISE Fire Research. Their construction with regard to insulation capabilities, materials and dimensions was based on existing charcoal ovens placed on the Norwegian marked. This was done to achieve an objective depiction of the issue, without the need for a specific brand of ovens. Restaurant oven charcoal was utilized to achieve as real heat development as possible in the test ovens. The test layout is based on NS-EN 12340:2001, with a test rigg constructed of two «safety walls», ceiling and floor attached with thermocouples. Temperatures from the test oven are registered in the safety walls at several positions according to a standardised grid, and in the ceiling and the floor each have one single measurement position measuring warmest point. Thermocouples in the chimney and exhaust duct measured the flue gas temperatures transported to the exhaust system. Four different tests were conducted, where the first one was a standardized safety test including the closed oven model. The second test was the same safety test setup with the dummy oven besides the closed oven. The dummy contained a built-in propane burner to simulate the heat load from a real oven. The purpose was to simulate two ovens placed next to each other. The third test was an overload test on the closed test oven with 150 % fuel load and higher refuelling frequency. The last test was a test of the open test oven. The safety test method described in NS-EN 13240:2001 is suitable to test the level of stable maximal temperature in the surrounding combustible materials, in the same way as for roomheaters, which the method is designed for. The method addresses safety aspects such as surface temperatures and handles on the oven. Tests show that the temperatures developed in the ovens have the potential to breech the temperature criterion given by the test standard, and therefore contribute to the ignition of surrounding combustible materials. Such situations pose a fire risk and safety measures regarding this aspect must be documented by the producer. NS-EN13240:2001 does not cover temperatures for exhaust duct and the production of sparks and their possible spread to combustible materials. These are important safety aspects which must be addressed when documenting the fire safety of restaurant grills. Tests show that sparks are created in the oven, including from restaurant charcoal fuel, and are transported into the exhaust duct, and out through the opening of the grill door. Together with high flue gas temperatures in the exhaust duct and deposits of soot and cooking oil this pose a fire risk. Documentation must therefore be presented, showing that the oven is equipped with measures (for instance spark screen) which guards the exhaust duct from sparks to a satisfactory degree. Operators of the oven must receive adequate training and must operate the closed oven with caution, as to avoid incidents with sparks being released though the door. The placement of ovens next to each other does not seem to increase the heat load on surrounding walls but may lead to increased temperatures in between the ovens. The consequences of temperature increases must be documented. Tests show that overloading with fuel and intensifying the refuelling intervals can lead to increased temperatures in the oven, which can affect materials and welding seams. Overloading can also affect the temperatures towards surrounding walls and exhaust ducts and therefore may affect fire safety negatively. NS-EN 13240:2001 requires the producer to documents how the oven is constructed and of what materials, and that the welding seams are dimensioned for the materials used. It is recommended that the producer documents the safety level of the oven materials with an overload test. It must also be documented that the exhaust ducts in which the flue gas are transported are constructed to handle the potential temperatures that can arise, including erroneous use.

This article presents an analysis of a fire in a municipal apartment building used as housing for people with challenges connected to drug addiction. The fire took place in Norway 7th of August 2021. The incident happened during the night and the fire was spreading quickly and intensely via the external wooden balconies. The combination of risk factors both connected to the fire development and the characteristics of the occupants raises the potential for fire fatalities. This analysis seeks to understand why the fire spread with such a speed, and how everyone in the building survived without injuries. The analysis identified both technical and human factors that may help to answer these questions. The findings suggest that there were deficiencies connected to the technical fire safety design that if improved could have reduced the fire damage. Factors promoting the fire spread and fire intensity include the choice of wood material used in the construction of the balconies, no sprinkler system installed on the balconies and a large fire load on the balconies caused by the occupants’ tendency to accumulate possessions on the balconies. Factors contributing to the outcome of no injuries or fatalities included occupants being awake during these late hours, and the strong social network between them. Such a network should be seen as a positive factor regarding robustness against fire and should be encouraged.

Alginate and cellulose nanofibrils (CNF) are attractive materials for tissue engineering and regenerative medicine. CNF gels are generally weaker and more brittle than alginate gels, while alginate gels are elastic and have high rupture strength. Alginate properties depend on their guluronan and mannuronan content and their sequence pattern and molecular weight. Likewise, CNF exists in various qualities with properties depending on, e.g., morphology and charge density. In this study combinations of three types of alginate with different composition and two types of CNF with different charge and degree of fibrillation have been studied. Assessments of the composite gels revealed that attractive properties like high rupture strength, high compressibility, high gel rigidity at small deformations (Young’s modulus), and low syneresis was obtained compared to the pure gels. The effects varied with relative amounts of CNF and alginate, alginate type, and CNF quality. The largest effects were obtained by combining oxidized CNF with the alginates. Hence, by combining the two biopolymers in composite gels, it is possible to tune the rupture strength, Young’s modulus, syneresis, as well as stability in physiological saline solution, which are all important properties for the use as scaffolds in tissue engineering.

Packaging plays a critical role in ensuring food safety and shelf life by protecting against e.g., moisture, gases, and light. Polyethylene (PE) is widely used in food packaging, but it is mainly produced from non-renewable resources and it is an inefficient oxygen and light barrier. In this study, the layer-by-layer (LbL) assembly of a sustainably produced lignin-based polymer (EH) with polyethylenimine (PEI) or chitosan (CH) was used to fabricate (partially or fully) bio-based coatings with the aim of improving barrier properties of PE films. The charge density of EH was calculated using a polyelectrolyte titration method and the hydrodynamic diameters of EH, PEI and CH were determined by Dynamic Light Scattering (DLS). LbL assembly was monitored in situ via Quartz Crystal Microbalance with Dissipation (QCM-D) and Stagnation Point Adsorption Reflectometry (SPAR). PE films were coated with a variable number of PEI/EH or CH/EH bilayers (BL) using an immersive LbL assembly method. Coated films were studied in terms of light-blocking ability, wettability, thermal behaviour, surface structure, as well as oxygen and water vapor barrier properties. QCM-D and SPAR data showed a stepwise multilayer formation and strong interactions between the oppositely charged polymers, with PEI/EH coating having a greater amount of deposited polymer compared to CH/EH coating at the same number of BL. Overall, light barrier properties and wettability of the coated films increased with the number of deposited bilayers. Coated PE films maintained the overall thermal behaviour of PE. A number of BL of 20 was found to be the most promising based on the studied properties. Selected samples showed improved oxygen and water vapor barrier properties, with PEI/EH coating performing better than CH/EH coating. Taken altogether, we demonstrated that a novel and sustainable lignin-based polymer can be combined with PEI or CH to fabricate (partially or fully) bio-based coatings for food packaging. 

This paper introduces a novel approach to designing autonomous gate drivers for soft-switched buck converters. The objective is to reduce switching losses, enhance converter efficiency, and reduce electromagnetic interference (EMI). The uniqueness of this converter is that the pulse-width modulation is performed autonomously on the gate driver. The gate driver makes quick decisions on switching times, capitalizing on the minimal time delay between measurements and switching. In the proposed buck converter configuration, the gate driver senses both the current and voltage across the switches to avoid delay. When a slightly negative voltage is detected across the switch, it rapidly turns on, resulting in a zero-voltage switching (ZVS). With an external snubber capacitor placed across the switches, the turn-off switching losses are zero (ZVS). Hence, both the turn-on and turn-off of the switch are soft. To enable the switch to turn off, a reference value of the switch current needs to be sent out to the gate driver using a galvanically isolated current sensor. Through this approach, the efficiency of the 7 kW buck converter has been calculated to exceed 99% without including the filter losses. Additional benefits include reduced switch stresses, diminished electromagnetic interference (EMI), and simplified thermal management.

Short-term traffic prediction allows Intelligent Transport Systems to proactively respond to events before they happen. With the rapid increase in the amount, quality, and detail of traffic data, new techniques are required that can exploit the information in the data in order to provide better results while being able to scale and cope with increasing amounts of data and growing cities. We propose and compare three models for short-term road traffic density prediction based on Long Short-Term Memory (LSTM) neural networks. We have trained the models using real traffic data collected by Motorway Control System in Stockholm that monitors highways and collects flow and speed data per lane every minute from radar sensors. In order to deal with the challenge of scale and to improve prediction accuracy, we propose to partition the road network into road stretches and junctions, and to model each of the partitions with one or more LSTM neural networks. Our evaluation results show that partitioning of roads improves the prediction accuracy by reducing the root mean square error by the factor of 5. We show that we can reduce the complexity of LSTM network by limiting the number of input sensors, on average to 35% of the original number, without compromising the prediction accuracy. .

The digitization of a supply chain involves satisfying several functional and non-functional context specific requirements. The work presented herein builds on efforts to elicit trust and profit requirements from actors in the Swedish livestock supply chain, specifically the beef supply chain. Interviewees identified several benefits related to data sharing and traceability but also emphasized that these benefits could only be realized if concerns around data security and data privacy were adequately addressed. We developed a data sharing platform as a response to these requirements. Requirements around verifiability, traceability, secure data sharing of potentially large data objects, fine grained access control, and the ability to link together data objects was realized using distributed ledger technology and a distributed file system. This paper presents this data sharing platform together with an evaluation of its usefulness in the context of beef supply chain traceability. 

Blockchain and verifiable identities have a lot of potential in future distributed software applications e.g. smart cities, eHealth, autonomous vehicles, networks, etc. In this paper, we proposed a novel technique, namely VeidBlock 1 , to generate verifiable identities by following a reliable authentication process. These entities are managed by using the concepts of blockchain ledger and distributed through an advance mechanism to protect them against tampering. All identities created using VeidBlock approach are verifiable and anonymous therefore it preserves user’s privacy in verification and authentication phase. As a proof of concept, we implemented and tested the VeidBlock protocols by integrating it in a SDN based infrastructure. Analysis of the test results yield that all components successfully and autonomously performed initial authentication and locally verified all the identities of connected components.

Reducing the heterogeneity of technical lignin is essential to obtain predictable and high-performance polymeric materials that are suitable for high-value applications. Organic solvents with different polarities and solubilities can be used to fractionate lignin and reduce the complexity and diversity of its chemical structure. Among the various solvents and solvent mixtures, acetone-water mixtures offer an energy-efficient, cost-effective, and environmentally friendly means of lignin fractionation. In the present study, temperature-induced acetone-water fractionation was investigated to refine the properties of a technical softwood Kraft lignin, i.e., LignoBoost™ lignin. Relatively mild operating conditions were tested, namely, temperatures of 70-110°C and autogenous pressure. A factorial experimental design was developed using the Design-Expert® software, and three factors (temperature, time, and acetone concentration) were investigated. It was found that temperature-induced fractionation could increase lignin homogeneity and maintain high lignin solubilization with a short processing time (<1 h). It was also possible to tune the properties of the soluble lignin fraction (yield and weight-average molecular weight) based on the factorial models developed. The techno-economic evaluation confirmed the commercial viability of this fractionation process. 

We propose a simple and efficient searchable symmetric encryption scheme based on a Bitmap index that evaluates Boolean queries. Our scheme provides a practical solution in settings where communications and computations are very constrained as it offers a suitable trade-off between privacy and performance.

In this deliverable from the SeCoHeat project, profits that can be made with 1 MWh of electricity production capacity on existing ancillary service markets are evaluated in 2020 and 2021. Profits are evaluated for four different marginal production costs corresponding to the following fuels for a CHP power plant: waste (assumed fuel price: 0 kr/MWh), recycled wood (10 kr/MWh), wood chips (20 kr/MWh) and wood pellets (30 kr/MWh). The results show that except for wood chips and wood pellets in 2020, the most profitable ancillary service markets are FFR (fast-frequency response) and aFRR down (automatic frequency restoration reserves for down-regulation). The reasons are that (1) producers don’t have to withhold capacity from the day-ahead market when their participate in these two markets and (2) producers get compensated for the capacity reserved for the ancillary service markets. For wood chips, the FFR market was the most profitable in 2020, followed by the mFRR down market (manual frequency restoration reserves for down-regulation). The reason for the mFRR down market to be more profitable than the aFRR down market for this fuel is that the profits from mFRR down depend on the avoided fuel costs, which are higher for wood chips than for waste and recycled wood. In 2021, all prices started increasing significantly, which decreased the relative profitability of the mFRR down compared to other markets. For wood pellets, the mFRR down market was also the second most profitable market in 2020, for the same reasons. The most profitable one in 2020 was the mFRR up market (manual frequency restoration reserves for up-regulation). The reason is that the higher fuel price of these two fuels entails low participation in the day-ahead market. Therefore, withholding capacity from the day-ahead market to be able to participate on the mFRR up market brings additional profits. In 2021, however, day-ahead prices started increasing significantly (a trend that continued into 2022) and the mFRR up market became the least profitable market for these two fuels. The profit evaluation performed in this deliverable is purely economic. It does not include the sector coupling to the heat sector (which entails limitation of the available electricity production capacity but also a possibility to store heat if storage is available) nor does it include other technical limitations such as ramp rates. These aspects will be considered in follow-up work in this project. This report has been compiled within the scope of the project SeCoHeat - Sector coupling of district heating with the electricity system: profitability and operation. The project is financed by the Research and Development Foundation of Göteborg Energi.

Recently, there has been an increase in apartments with a large number of inhabitants, i.e., high residential density. This is partly due to a housing shortage in general but also increased migration, particularly in suburbs of major cities. This paper specifies issues that might be caused by high residential density by investigating the technical parameters influenced in Swedish apartments that are likely to have high residential density. Interviews with 11 employees at housing companies were conducted to identify issues that might be caused by high residential density. Furthermore, simulations were conducted based on extreme conditions described in the interviews to determine the impact on the energy use, indoor environmental quality, and moisture loads. In addition, the impact of measures to mitigate the identified issues was determined. Measures such as demand-controlled ventilation, increase of a constant ventilation rate, and moisture buffering are shown to reduce the risk for thermal discomfort, mold growth, and diminished indoor air quality; while still achieving a lower energy use than in a normally occupied apartment. The results of this study can be used by authorities to formulate incentives and/or recommendations for housing owners to implement measures to ensure good indoor environmental quality for all, irrespective of residential density conditions.

This research investigates the potential of a game-theoretic-based Active Yaw Control (AYC) strategy to enhance power generation in wind farms. The proposed AYC strategy in this study replaces traditional look-up tables with a trained Artificial Neural Network (ANN) that determines the optimal yaw misalignment for turbines under time-varying atmospheric conditions. The study examines a hypothetical 3x2 rectangular arrangement of NREL 5-MW wind turbines. The FAST.Farm simulation tool, utilizing the dynamic wake meandering (DWM) model, is employed to assess both the power performance and structural load on the wind turbines. When tested with two different inflow directions and ambient turbulence (10%), the AYC strategy demonstrated a maximum increase in total power output of 2.6%, although it affected individual turbines differently. It also exhibits an increase in some structural loads, such as tower-top torque, while some components experience a slight reduction in load. The results underscore the effectiveness of the ANN-guided game-theoretic algorithm in improving wind farm power generation by mitigating the negative impact of wake interference, offering a scalable and efficient method for optimizing large-scale wind farm. However, it is essential to evaluate the overall impact of AYC on wind farm efficiency in terms of both Annual Energy Production (AEP) and structural loading under various atmospheric conditions. 

Lightweight, energy-efficient materials in building construction typically include polymeric and composite foams. However, these materials pose significant fire hazards due to their high combustibility and toxic gas emissions, including carbon monoxide and hydrogen cyanide. This study delves into the latter aspects by comparing hybrid systems based on nanofiber-reinforced silica-based Pickering foams with a synthetic reference (polyurethane foams). The extent and dynamics of fire retardancy and toxic gas evolution were assessed, and the results revealed the benefits of combining the thermal insulation of silica with the structural strength of biobased nanofibers, the latter of which included anionic and phosphorylated cellulose as well as chitin nanofibers. We demonstrate that the nanofiber-reinforced silica-based Pickering foams are thermal insulative and provide both fire safety and energy efficiency. The results set the basis for the practical design of hybrid foams to advance environmental sustainability goals by reducing energy consumption in built environments. 

Nanocellulose (NC)-based hybrid coatings and films containing CeO2 and SiO2 nanoparticles (NPs) to impart UV screening and hardness properties, respectively, were prepared by solvent casting. The NC film-forming component (75 wt % of the overall solids) was composed entirely of cellulose nanocrystals (CNCs) or of CNCs combined with cellulose nanofibrils (CNFs). Zeta potential measurements indicated that the four NP types (CNC, CNF, CeO2, and SiO2) were stably dispersed in water and negatively charged at pH values between 6 and 9. The combination of NPs within this pH range ensured uniform formulations and homogeneous coatings and films, which blocked UV light, the extent of which depended on film thickness and CeO2 NP content, while maintaining good transparency in the visible spectrum (∼80%). The addition of a low amount of CNFs (1%) reduced the film hardness, but this effect was compensated by the addition of SiO2 NPs. Chiral nematic self-assembly was observed in the mixed NC film; however, this ordering was disrupted by the addition of the oxide NPs. The roughness of the hybrid coatings was reduced by the inclusion of oxide NPs into the NC matrix perhaps because the spherical oxide NPs were able to pack into the spaces between cellulose fibrils. We envision these hybrid coatings and films in barrier applications, photovoltaics, cosmetic formulations, such as sunscreens, and for the care and maintenance of wood and glass surfaces, or other surfaces that require a smooth, hard, and transparent finish and protection from UV damage.

From a circular economy perspective, one-pot strategies for the isolation of cellulose nanomaterials at a high yield and with multifunctional properties are attractive. Here, the effects of lignin content (bleached vs unbleached softwood kraft pulp) and sulfuric acid concentration on the properties of crystalline lignocellulose isolates and their films are explored. Hydrolysis at 58 wt % sulfuric acid resulted in both cellulose nanocrystals (CNCs) and microcrystalline cellulose at a relatively high yield (>55%), whereas hydrolysis at 64 wt % gave CNCs at a lower yield (<20%). CNCs from 58 wt % hydrolysis were more polydisperse and had a higher average aspect ratio (1.5-2×), a lower surface charge (2×), and a higher shear viscosity (100-1000×). Hydrolysis of unbleached pulp additionally yielded spherical nanoparticles (NPs) that were <50 nm in diameter and identified as lignin by nanoscale Fourier transform infrared spectroscopy and IR imaging. Chiral nematic self-organization was observed in films from CNCs isolated at 64 wt % but not from the more heterogeneous CNC qualities produced at 58 wt %. All films degraded to some extent under simulated sunlight trials, but these effects were less pronounced in lignin-NP-containing films, suggesting a protective feature, but the hemicellulose content and CNC crystallinity may be implicated as well. Finally, heterogeneous CNC compositions obtained at a high yield and with improved resource efficiency are suggested for specific nanocellulose uses, for instance, as thickeners or reinforcing fillers, representing a step toward the development of application-tailored CNC grades. © 2023 The Authors. 

The biotechnological applications of cellulose nanocrystals (CNCs) continue to grow due to their sustainable nature, impressive mechanical, rheological, and emulsifying properties, upscaled production capacity, and compatibility with other materials, such as protein and polysaccharides. In this study, hydrogels from CNCs and pectin, a plant cell wall polysaccharide broadly used in food and pharma, were produced by calcium ion-mediated internal ionotropic gelation (IG). In the absence of pectin, a minimum of 4 wt% CNC was needed to produce self-supporting gels by internal IG, whereas the addition of pectin at 0.5 wt% enabled hydrogel formation at CNC contents as low as 0.5 wt%. Experimental data indicate that CNCs and pectin interact to give robust and self-supporting hydrogels at solid contents below 2.5 %. Potential applications of these gels could be as carriers for controlled release, scaffolds for cell growth, or wherever else distinct and porous network morphologies are required.

Wind-induced dynamic excitation is becoming a governing design action determin-ing size and shape of modern Tall Timber Buildings (TTBs). The wind actions generate dynamic loading, causing discomfort or annoyance for occupants due to the perceived horizontal sway – i.e. vibration serviceability failure. Although some TTBs have been instrumented and meas-ured to estimate their key dynamic properties (natural frequencies and damping), no systematic evaluation of dynamic performance pertinent to wind loading has been performed for the new and evolving construction technology used in TTBs. The DynaTTB project, funded by the Forest Value research program, mixes on site measurements on existing buildings excited by heavy shakers, for identification of the structural system, with laboratory identification of building elements mechanical features coupled with numerical modelling of timber structures. The goal is to identify and quantify the causes of vibration energy dissipation in modern TTBs and pro-vide key elements to FE modelers.

The first building, from a list of 8, was modelled and tested at full scale in December 2019. Some results are presented in this paper. Four other buildings will be modelled and tested in spring 2020.

Wind-induced dynamic excitation is a governing design action determining size and shape of modern Tall Timber Buildings (TTBs). The wind actions generate dynamic loading, causing discomfort or annoyance for occupants due to the perceived horizontal sway, i.e. vibration serviceability problem. Although some TTBs have been instrumented and measured to estimate their key dynamic properties (eigenfrequencies, mode shapes and damping), no systematic evaluation of dynamic performance pertinent to wind loading had been performed for the new and evolving construction technologies used in TTBs. The DynaTTB project, funded by the ForestValue research program, mixed on site measurements on existing buildings excited by mass inertia shakers (forced vibration) and/or the wind loads (ambient vibration), for identification of the structural system, with laboratory identification of building elements mechanical features, coupled with numerical modelling of timber structures. The goal is to identify and quantify the causes of vibration energy dissipation in modern TTBs and provide key elements to finite element models. This paper presents an overview of the results of the project and the proposed Guidelines for design of TTBs in relation to their dynamic properties.

Dispersing Multi-Walled Carbon Nanotubes (MWCNTs) into concrete at low (<1 wt% in cement) concentrations may improve concrete performance and properties and provide enhanced functionalities. When MWCNT-enhanced concrete is fragmented during remodelling or demolition, the stiff, fibrous and carcinogenic MWCNTs will, however, also be part of the respirable particulate matter released in the process. Consequently, systematic aerosolizing of crushed MWCNT-enhanced concretes in a controlled environment and measuring the properties of this aerosol can give valuable insights into the characteristics of the emissions such as concentrations, size range and morphology. These properties impact to which extent the emissions can be inhaled as well as where they are expected to deposit in the lung, which is critical to assess whether these materials might constitute a future health risk for construction and demolition workers. In this work, the impact from MWCNTs on aerosol characteristics was assessed for samples of three concrete types with various amounts of MWCNT, using a novel methodology based on the continuous drop method. MWCNT-enhanced concretes were crushed, aerosolized and the emitted particles were characterized with online and offline techniques. For light-weight porous concrete, the addition of MWCNT significantly reduced the respirable mass fraction (RESP) and particle number concentrations (PNC) across all size ranges (7 nm – 20 μm), indicating that MWCNTs dampened the fragmentation process by possibly reinforcing the microstructure of brittle concrete. For normal concrete, the opposite could be seen, where MWCNTs resulted in drastic increases in RESP and PNC, suggesting that the MWCNTs may be acting as defects in the concrete matrix, thus enhancing the fragmentation process. For the high strength concrete, the fragmentation decreased at the lowest MWCNT concentration, but increased again for the highest MWCNT concentration. All tested concrete types emitted <100 nm particles, regardless of CNT content. SEM imaging displayed CNTs protruding from concrete fragments, but no free fibres were detected. 

Connected vehicles can make roads traffic safer andmore efficient, but require the mobile networks to handle timecriticalapplications. Using the MONROE mobile broadbandmeasurement testbed we conduct a multi-access measurementstudy on buses. The objective is to understand what networkperformance connected vehicles can expect in today’s mobilenetworks, in terms of transaction times and availability. The goalis also to understand to what extent access to several operatorsin parallel can improve communication performance.In our measurement experiments we repeatedly transfer warningmessages from moving buses to a stationary server. Wetriplicate the messages and always perform three transactionsin parallel over three different cellular operators. This creates adataset with which we can compare the operators in an objectiveway and with which we can study the potential for multi-access.In this paper we use the triple-access dataset to evaluate singleaccessselection strategies, where one operator is chosen for eachtransaction. We show that if we have access to three operatorsand for each transaction choose the operator with best accesstechnology and best signal quality then we can significantlyimprove availability and transaction times compared to theindividual operators. The median transaction time improves with6% compared to the best single operator and with 61% comparedto the worst single operator. The 90-percentile transaction timeimproves with 23% compared to the best single operator andwith 65% compared to the worst single operator.

Free space optics is an interesting alternative for telemetry with medical implants, due to the high data bandwidths available at optical frequencies. Especially implanted brain-computer interfaces gives rise to large data sets that needs to be transmitted transcutaneous. In this paper we show that it is possible to establish such a link at near-IR wavelengths using a modulated reflector in the implant, thus keeping the laser and the detector on the outside. In addition, we show that it will not only work on short, i.e. touch, distances but also at larger distances, in the range of a meter. We have used an electro absorption modulator to modulate the reflection of an external laser source back towards an external detector. The only part of this system that needs to be implanted is the modulator and drive electronics. The study has been done both by Monte-Carlo simulations of a multi-layer model of a rat skull, and with an experiment demonstrating the feasibility of the link when transmitted through biological tissue. The results show that it is possible to establish a transcutaneous link with an external laser source and light detector, and an internal modulated reflector.

Sweden has an ambitious plan to fully decarbonise district heating by 2030 and to contribute with negative emissions of greenhouse gases in 2050. The vagaries of the energy market associated with climate, political, and social changes entail cross-sectoral integration that can fulfill these national targets. Fifth-generation district heating and cooling (5GDHC) is a relatively new concept of district energy systems that features a simultaneous supply of heating and cooling using power-to-heat technologies. This paper presents best practices for developing 5GDHC systems in Sweden to reach a consensus view on these systems among all stakeholders. A mixed-method combining best practice and roadmapping workshops has been used to disseminate mixed knowledge and experience from middle agents representing industry professionals and practitioners. Four successful implementations of 5GDHC systems are demonstrated and the important learned lessons are shared. The best practices are outlined for system planning, system modeling and simulation, prevailing business models for energy communities, and system monitoring. A roadmap from the middle agents’ point of view is composed and can be utilised to establish industry standards and common regulatory frameworks. © 2023 The Author(s)

Dissolution of cellulose from various sources (microcrystalline cellulose and different dissolving grade pulp fibers) is investigated in solvent systems based on triethyl(n-octyl)ammonium chloride (N2228Cl). Clear cellulose solutions are obtained with N2228Cl in a variety of solvents, e.g., dimethyl sulfoxide, N,N-dimethylacetamide, and acetone. It is possible to prepare clear cellulose solutions from pulp fibers with concentrations up to 15 wt%. However, it is found that the cellulose is degraded, especially when neat (i.e., molten) N2228Cl is used as a solvent. The present work includes comprehensive rheological characterization of the cellulose solutions, both with shear and extensional rheology. In most cases, the viscosity values are low (complex viscosities below 100 Pa s for 5–10 wt% dissolved cellulose), and the solutions show more Newtonian than viscoelastic behavior. 

Masonry bridges are among the most sustainable structures ever to have been built. The long service time, the resilience to carry larger loads than originally intended, and significantly lower life cycle cost compared to other bridge types suggest that we should consider the design and construction of new masonry bridges, even if their initial cost is greater than that of steel or concrete bridges The aim of this work is to understand the structural behaviour and study the collapse of a single-span masonry hydrostatic shell, that is a shell designed specifically to carry a hydrostatic load. Due to the complexity of the masonry shell interacting with fill, it is necessary to use a combination of computational methods and load tests on physical models in their structural assessment. We perform a load test to failure on a physical model spanning 770 mm made from 3D printed blocks and analyse the model using the Discrete Element Method (DEM) in Dassault Systemes Abaqus. ` The physical model behaved well and predicts that the bridge could be used at full scale. The preliminary results from a computational DEM model are found to be qualitatively good, but greatly overestimate the collapse load of the bridge.

The mechanical reliability and aesthetic appearance of ceramic dental prostheses are strongly influenced by the presence of defects. When several processes are used during fabrication of ceramic dental prostheses, additional defects are unavoidably introduced in each process step; these are in addition to the ones that already exist in raw materials. To avoid the degeneration of material performance by the accumulated defect population, process optimization is needed to minimize the defects introduced. Standardized mechanical evaluations are usually performed on samples with carefully prepared surfaces in order to minimize the influence from the defects usually induced by fabrication processes. The results from such mechanical evaluation indicate the strength level that is achievable by the material with the given population of bulk defects. In order to avoid a reduction in the performance of the ceramic material by the additional defects normally induced by the fabrication process, it must be understood how these defects are introduced, and solutions must be found to reduce their size and frequency through modifications of the material and processes. The aim of this chapter is to elucidate the sources of defects that are common for ceramic dental prostheses and to determine how to minimize them.

A suspension of zirconia powder (TZ3YSE) with a solids loading of 50. vol% was prepared by ball milling. Binders were added and some of the suspension was diluted to 40, 30 and 20. vol% before freeze granulation was performed. A spray dried material (TZ3YSEB) was used as a reference. The pore size distribution of the different granules was evaluated and from the microstructure it was shown that inhomogeneities were present in both the freeze granulated as well as in the spray dried granules. In addition, the density, microstructure as well as the strength of sintered materials prepared from the granules were studied. The results showed that a high green density or sintered density was not sufficient in order to achieve a high strength material. It was further shown that the strength was significantly influenced by the granule density and not by the inhomogeneities found in the granules.

Through the confinement of gas in nanoporous materials, it is possible to significantly increase the path length for light–gas interaction. This enables the observation of much stronger absorption features for the confined gas molecules. In this work, we systematically characterized a variety of disordered strongly scattering ZrO2 and Al2O3 nanoporous ceramic materials to exploit the potential of gas in scattering media absorption spectroscopy. As a result, we identified a material with an unprecedented performance in terms of optical path length enhancement. In ZrO2 with thicknesses above 6 mm, the path enhancement exceeds 1000. The results obtained with near-infrared absorption spectroscopy on oxygen were validated by time-of-flight measurements at 700 nm, thus demonstrating their robustness. Finally, we report quantitative oxygen concentration measurement using nanoporous materials as miniaturized random-scattering multipass cell with an extremely simple and low-cost setup.

A DBR laser is step-wise tunable thanks to a superimposed fiber grating external cavity. The stability against tuning current variations in the DBR is excellent. Single-mode operation is achieved with SMSR better than 30 dB.

To ensure traffic safety and proper operation of vehicular networks, safety messages or beacons are periodically broadcasted in Vehicular Adhoc Networks (VANETs) to neighboring nodes and road side units (RSU). Thus, authenticity and integrity of received messages along with the trust in source nodes is crucial and highly required in applications where a failure can result in life-threatening situations. Several digital signature based approaches have been described in literature to achieve the authenticity of these messages. In these schemes, scenarios having high level of vehicle density are handled by RSU where aggregated signature verification is done. However, most of these schemes are centralized and PKI based where our goal is to develop a decentralized dynamic system. Along with authenticity and integrity, trust management plays an important role in VANETs which enables ways for secure and verified communication. A number of trust management models have been proposed but it is still an ongoing matter of interest, similarly authentication which is a vital security service to have during communication is not mostly present in the literature work related to trust management systems. This paper proposes a secure and publicly verifiable communication scheme for VANET which achieves source authentication, message authentication, non repudiation, integrity and public verifiability. All of these are achieved through digital signatures, Hash Message Authentication Code (HMAC) technique and logging mechanism which is aided by blockchain technology.

Manufacturers of automated systems and their components have been allocating an enormous amount of time and effort in R&D activities, which led to the availability of prototypes demonstrating new capabilities as well as the introduction of such systems to the market within different domains. Manufacturers need to make sure that the systems function in the intended way and according to specifications. This is not a trivial task as system complexity rises dramatically the more integrated and interconnected these systems become with the addition of automated functionality and features to them. This effort translates into an overhead on the V&V (verification and validation) process making it time-consuming and costly. In this paper, we present VALU3S, an ECSEL JU (joint undertaking) project that aims to evaluate the state-of-the-art V&V methods and tools, and design a multi-domain framework to create a clear structure around the components and elements needed to conduct the V&V process. The main expected benefit of the framework is to reduce time and cost needed to verify and validate automated systems with respect to safety, cyber-security, and privacy requirements. This is done through identification and classification of evaluation methods, tools, environments and concepts for V&V of automated systems with respect to the mentioned requirements. VALU3S will provide guidelines to the V&V community including engineers and researchers on how the V&V of automated systems could be improved considering the cost, time and effort of conducting V&V processes. To this end, VALU3S brings together a consortium with partners from 10 different countries, amounting to a mix of 25 industrial partners, 6 leading research institutes, and 10 universities to reach the project goal.

Verification and Validation (V&V) of automated systems is becoming more costly and time-consuming because of the increasing size and complexity of these systems. Moreover, V&V of these systems can be hindered if the methods and processes are not properly described, analysed, and selected. It is essential that practitioners use suitable V&V methods and enact adequate V&V processes to confirm that these systems work as intended and in a cost-effective manner. Previous works have created different taxonomies and models considering different aspects of V&V that can be used to classify V&V methods and tools. The aim of this work is to provide a broad, comprehensive and a easy to use framework that addresses characterisation needs, rather than focusing on individual aspects of V&V methods and processes.To this end, in this paper, we present a multi-domain and multi-dimensional framework to characterize and classify V&V methods and tools in a structured way. The framework considers a comprehensive characterization of different relevant aspects of V&V. A web-based repository has been implemented on the basis of the framework, as an example of use, in order to collect information about the application of V&V methods and tools. This way, practitioners and researchers can easily learn about and identify suitable V&V processes.

Ethanol derived from biomass has the potential to be a renewable transportation fuel that can replace gasoline. This work was carried out to establish an optimized ethanol organosolv pretreatment of Norway spruce (Picea abies) for bioethanol production (63 wt% EtOH, pH ~3.5 in aqueous phase, 170–240 °C, 90 min) utilizing hydrolytic enzymes in the saccharification step. To test the generality of the method, a series of ethanol organosolv pretreatments were also performed on sugarcane bagasse (50 wt% EtOH, pH ~3.5 in aqueous phase, 155–210 °C, 90–120 min). The degree of delignification increased with increasing temperature during pretreatment, and the fastest increase was observed with sugarcane bagasse. The pretreatments were carried out in a batch mode. The maximum degree of delignification of ~65 % was reached at ~235 °C for Norway spruce, while sugarcane bagasse reached ~80 % at ~210 °C. Cellulose was subjected to degradation (5–10 % points) at these temperatures. Subsequent enzymatic hydrolysis (30 FPU/g cellulose, 32 pNPGU/g cellulose, 50 °C, 48 h) of ethanol organosolv-pretreated biomass achieved complete conversion for both raw materials at the highest degrees of delignification.

The behavior of fibers suspended in a flow between two flat counter-rotating discs has been studied experimentally. Captured images of the fibers in the flow were analyzed by steerable filters, to extract positions and orientations of the fibers. Experiments were performed for gaps between the discs of less than one fiber length, and for equal absolute values of the angular velocities for the discs. The length-to-diameter ratio of the fibers was approximately 14. During certain conditions, the fibers organized themselves in a distinct manner, which we will denote as fiber trains, in which three or more fibers are aligned next to each other, at the same radial position, with a short fiber-to-fiber distance. The direction of the individual fibers is radial and the direction of the whole train is tangential. Trains containing more than 60 fibers have been observed and are quite impressing.

Rapporten behandlar digitalisering – att införa ny digital teknik – i förvaltningsverksamheten av broar. Omfattningen är en förstudie med syftet att identifiera behovet av framtida forskning för en långsiktig utveckling av broförvaltningen. En grundläggande ansats var att en digitalisering ska minska behovet av kostsamma underhållsåtgärder men bibehålla en hög säkerhet för våra broar. Projektets mål var att samla information om digitala informationsmodeller som skapas under investeringsskedet, utvärdera överlämningen av digitala modeller till förvaltningsskedet, och värdera den eventuella nyttan med digital informationsinsamling för tillståndsbedömning och underhållsplanering. En viktig del av detta var beskrivningen av dagens förvaltningssystem och hur det skulle kunna utvecklas. Studierna har bedrivits genom en enkätundersökning med respondenter från konsultfirmor aktiva inom broprojektering, intervjuer med tekniska experter och litteratursökningar. Resultatet visar att projekteringen av broar idag huvudsakligen görs genom byggnads-informationsmodellering (BIM). Inriktningen är mot byggskedet där samordning och kommunikation bedöms vara de största nyttorna. Överlämningen till förvaltningen består dock av relationsritningar i formen av enkla ritningsfiler. Trots att Trafikverkets strategi för BIM beskriver att en informationsmodell bör leva kvar under hela brons livslängd, finns det tveksamheter huruvida en modell från projekteringen är lämplig som förvaltningsmodell. Istället lyfts andra metoder fram för att skapa en modell av det byggda utförandet. Till exempel optiska metoder för skanning och fotogrammetri. Förvaltningssystemen bör utvecklas med funktioner för att lagra och tillgängliggöra stora mängder digital information från sensorer maskinella inspektioner. Syftet är att minska osäkerheterna i det byggda utförandet och graden av nedbrytning, för att slutligen skapa ett bättre underlag för beslut om åtgärder. Ett framtida scenario är en digital tvilling som speglar den verkliga konstruktionen och uppdateras kontinuerligt genom sensordata. Gällande hårdvara för mätningar behöver sensorer och system utvecklas med avseende på energiförbrukning, energiskördning och underhållsåtgärder, t.ex. genom kombinationer av utbytbara komponenter med kort livslängd och andra delar med lång livslängd. Fiberoptiska sensorer visar på lovande egenskaper men utveckling behövs för att göra dem mer kostnadseffektiva i relation till konventionella sensorer.