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Radical alternating copolymerization: A strategy for hyperbranched materials
Åbo Akademi University.
Åbo Akademi University.
RISE, Swerea, Swerea SICOMP.
2000 (English)In: Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, E-ISSN 1099-0518, Vol. 38, no 17, 3074-3085 p.Article in journal (Refereed)
Abstract [en]

Novel hyperbranched polymers were synthesized in a high yield without gelation through the free-radical alternating copolymerization of an AB/B′ (allyloxy maleic acid/maleic anhydride) system, in which group B and monomer B′ both could only alternately polymerize with group A. The arm number of the produced highly branched polymers was equal to the product of the linear chain length and the probability of pendent B groups being growing centers. The molecular weight of these novel hyperbranched polymers increased with increasing initiator concentration and prolonged polymerization times. The AB/B′ system, used as described, provides a new general methodology for highly branched and functional polymers.

Place, publisher, year, edition, pages
John Wiley & Sons Inc, New York, NY, United States , 2000. Vol. 38, no 17, 3074-3085 p.
National Category
Materials Engineering
Identifiers
URN: urn:nbn:se:ri:diva-13229OAI: oai:DiVA.org:ri-13229DiVA: diva2:973425
Available from: 2016-09-22 Created: 2016-09-22Bibliographically approved

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http://onlinelibrary.wiley.com/doi/10.1002/1099-0518%2820000901%2938:17%3C3074::AID-POLA80%3E3.0.CO;2-D/abstract
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Swerea SICOMP
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Journal of Polymer Science Part A: Polymer Chemistry
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