Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
The split network analysis for exploring composition-structure correlations in multi-component glasses: II. Multinuclear NMR studies of alumino-borosilicates and glass-wool fibers
RISE, SP – Sveriges Tekniska Forskningsinstitut, Glafo Glasforskningsinstitutet.
RISE, SP – Sveriges Tekniska Forskningsinstitut, Glafo Glasforskningsinstitutet.
2011 (English)In: Journal of Non-Crystalline Solids, ISSN 0022-3093, E-ISSN 1873-4812, Vol. 357, no 6, 1587-1594 p.Article in journal (Refereed)
Abstract [en]

The preceding part [M. Edén, J. Non.-Cryst. Solids, 357, (2011) 1595-1602] introduced the "split network" strategy for estimating the network polymerization degree (r A) and mean number of bridging oxygen (BO) atoms (N̄BOA) for a network former A, given that these parameters are known for all other network builders in the multi-component oxide glass. However, as the detailed ordering of BO and non-bridging oxygen (NBO) species is often difficult to assess experimentally, we summarize some "rules of thumb" for predicting the coordination number and tendency to accept NBO ions for Al 3+, B 3+, Si 4+ and P 5+ cations: they are helpful in scenarios devoid of experimental data. Using the parameters r and N̄BO, we present expressions for the BO/NBO distributions among tetrahedrally coordinated cations, as predicted from the binary and random models. Multinuclear 11B, 27Al and 29Si solid-state NMR is exploited to derive the split network representations of a set of Na-Ca-(Al)-(B)-Si-O glasses. These results are subsequently used to gain structural insight into two commercial glass-wool fibers that constitute alumino-borosilicate networks modified by Na +, K +, Ca 2+ and Mg 2+ ions. © 2010 Elsevier B.V.

Place, publisher, year, edition, pages
2011. Vol. 357, no 6, 1587-1594 p.
Keyword [en]
Chemical engineering
Keyword [sv]
Kemiteknik
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:ri:diva-907DOI: 10.1016/j.jnoncrysol.2010.11.101Scopus ID: 2-s2.0-79952003500OAI: oai:DiVA.org:ri-907DiVA: diva2:958448
Available from: 2016-09-07 Created: 2016-09-07 Last updated: 2017-11-21Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus
By organisation
Glafo Glasforskningsinstitutet
In the same journal
Journal of Non-Crystalline Solids
Chemical Engineering

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 15 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
v. 2.29.1