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In-situ study of substrate - catalyst interactions in a Juliá-Colonna epoxidation using quartz crystal microbalance with dissipation
KTH Royal Institute of Technology, Sweden.
Rovira i Virgili University, Spain.
Rovira i Virgili University, Spain.
Rovira i Virgili University, Spain.
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2016 (English)In: Journal of Colloid and Interface Science, ISSN 0021-9797, E-ISSN 1095-7103, Vol. 469, p. 263-268Article in journal (Refereed) Published
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Abstract [en]

Quartz crystal microbalance with dissipation (QCM-D) analysis of the hexa-l-Leucine (PLL)-catalyzed epoxidation of chalcone gives in-situ experimental evidences which demonstrate that the reaction proceeds mainly via the formation of a PLL-bound hydroperoxide complex followed by the reversible addition of chalcone. The observations offer an alternative rationalization for the viability of the preferred catalytic pathway.

Place, publisher, year, edition, pages
Academic Press, 2016. Vol. 469, p. 263-268
Keywords [en]
catalysis, Juliá-Colonna epoxidation, poly-l-leucine (PLL), quartz crystal microbalance with dissipation (QCM-D)
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Physical Chemistry Other Chemistry Topics
Identifiers
URN: urn:nbn:se:ri:diva-103DOI: 10.1016/j.jcis.2016.01.076Scopus ID: 2-s2.0-84958244146OAI: oai:DiVA.org:ri-103DiVA, id: diva2:932168
Available from: 2016-05-31 Created: 2016-04-28 Last updated: 2019-06-14Bibliographically approved

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Rutland, Mark W.

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