Carbon-negative valorization of biomass waste into affordable green hydrogen and battery anodesShow others and affiliations
2023 (English)In: International journal of hydrogen energy, ISSN 0360-3199, E-ISSN 1879-3487, Vol. 49, p. 459-Article in journal (Refereed) Published
Abstract [en]
The global Sustainable Development Goals highlight the necessity for affordable and clean energy, designated as SDG7. A sustainable and feasible biorefinery concept is proposed for the carbon-negative utilization of biomass waste for affordable H2 and battery anode material production. Specifically, an innovative tandem biocarbon + NiAlO + biocarbon catalyst strategy is constructed to realize a complete reforming of biomass pyro-vapors into H2+CO (as a mixture). The solid residues from pyrolysis are upgraded into high-quality hard carbon (HCs), demonstrating potential as sodium ion battery (SIBs) anodes. The product, HC-1600-6h, exhibited great electrochemical performance when employed as (SIBs) anodes (full cell: 263 Wh/kg with ICE of 89%). Ultimately, a comprehensive process is designed, simulated, and evaluated. The process yields 75 kg H2, 169 kg HCs, and 891 kg captured CO2 per ton of biomass achieving approx. 100% carbon and hydrogen utilization efficiencies. A life cycle assessment estimates a biomass valorization process with negative-emissions (−0.81 kg CO2/kg-biomass, reliant on Sweden wind electricity). A techno-economic assessment forecasts a notably profitable process capable of co-producing affordable H2 and hard carbon battery anodes. The payback period of the process is projected to fall within two years, assuming reference prices of 13.7 €/kg for HCs and 5 €/kg for H2. The process contributes to a novel business paradigm for sustainable and commercially viable biorefinery process, achieving carbon-negative valorization of biomass waste into affordable energy and materials.
Place, publisher, year, edition, pages
Elsevier Ltd , 2023. Vol. 49, p. 459-
Keywords [en]
Anodes; Bioconversion; Biomass; Carbon dioxide; Investments; Life cycle; Metal ions; Refining; Sodium-ion batteries; Affordable energy; Battery anodes; Biocarbon; Biomass wastes; Biorefineries; Energy; Hard carbon; Negative emission; Sodium ion batteries; Valorisation; Carbon
National Category
Mechanical Engineering
Identifiers
URN: urn:nbn:se:ri:diva-67666DOI: 10.1016/j.ijhydene.2023.09.096Scopus ID: 2-s2.0-85172247785OAI: oai:DiVA.org:ri-67666DiVA, id: diva2:1815848
Note
Financial supported by VINNOVA- the Swedish innovation fund Agency with project number 2021-03735 is highly appreciated. One of the authors, Hanmin Yang would like to acknowledge the financial support from the Chinese Scholarship Council (CSC) and Stiftelsen Energitekniskt Centrum i Piteå, Sweden.
2023-11-302023-11-302024-06-11Bibliographically approved