Upscaling of lignin precursor melt spinning by bicomponent spinning and its use for carbon fibre production
2021 (English)In: Philosophical Transactions. Series A: Mathematical, physical, and engineering science, ISSN 1364-503X, E-ISSN 1471-2962, Vol. 379, no 2209, article id 20200334Article in journal (Refereed) Published
Abstract [en]
Upscaling lignin-based precursor fibre production is an essential step in developing bio-based carbon fibre from renewable feedstock. The main challenge in upscaling of lignin fibre production by melt spinning is its melt behaviour and rheological properties, which differ from common synthetic polymers used in melt spinning. Here, a new approach in melt spinning of lignin, using a spin carrier system for producing bicomponent fibres, has been introduced. An ethanol extracted lignin fraction from LignoBoost process of commercial softwood kraft black liquor was used as feedstock. After additional heat treatment, melt spinning was performed in a pilot-scale spinning unit. For the first time, biodegradable polyvinyl alcohol (PVA) was used as a spin carrier to enable the spinning of lignin by improving the required melt strength. PVA-sheath/lignin-core bicomponent fibres were manufactured. Afterwards, PVA was dissolved by washing with water. Pure lignin fibres were stabilized and carbonized, and tensile properties were measured. The measured properties, tensile modulus of 81.1 ± 3.1 GPa and tensile strength of 1039 ± 197 MPa, are higher than the majority of lignin-based carbon fibres reported in the literature. This new approach can significantly improve the melt spinning of lignin and solve problems related to poor spinnability of lignin and results in the production of high-quality lignin-based carbon fibres. This article is part of the theme issue 'Bio-derived and bioinspired sustainable advanced materials for emerging technologies (part 2)'. © 2021 The Author(s).
Place, publisher, year, edition, pages
Royal Society Publishing , 2021. Vol. 379, no 2209, article id 20200334
Keywords [en]
carbon fibre, core-sheath structure, lignin, melt spinning, precursor, scale-up, Carbon fibers, Feedstocks, Spinning (fibers), Tensile strength, Bi-component fibers, Bicomponents, Core-sheath structures, Fiber production, Lignin fibres, New approaches, Spin carriers, Upscaling, Carbon, Cores, Ethanol, Lignins, Polyvinyl Acetate, Processes, Production
National Category
Paper, Pulp and Fiber Technology
Identifiers
URN: urn:nbn:se:ri:diva-56919DOI: 10.1098/rsta.2020.0334Scopus ID: 2-s2.0-85115821214OAI: oai:DiVA.org:ri-56919DiVA, id: diva2:1613855
Note
Funding details: Horizon 2020 Framework Programme, H2020, 667501; Funding details: Bio-Based Industries Joint Undertaking, BBI JU; Funding text 1: Data accessibility. More information can be found on CORDIS EU research results (https://cordis.europa.eu/ project/id/667501). Authors’ contributions. L.B. was responsible for lignin characterization and fibre spinning. O.H. was responsible for lignin separation/preparation, lignin characterization and conversion to carbon fibre. R.F. was responsible for spinning process adaption and nozzle design. A.H. supervise the whole work at Faserinstiut Bremen and was responsible for critical review. Formalities were divided equally between the authors. Competing interests. All authors have no competing interests. Funding. Presented results were generated during the GreenLight project. This project has received funding from the Bio-Based Industries Joint Undertaking under the European Union’s Horizon 2020 research and innovation programme under grant agreement no 667501. Acknowledgements. The authors thank Jens Haraldsson from RISE for assisting with carbon fibre’s characterisations, Daniel Weigel from Faserinstiut Bremen for supporting spinning trials and Teijin Carbon Europe GmbH for data release from KoNaVo-Project.
2021-11-232021-11-232024-03-03Bibliographically approved