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The challenge of predicting spinnability: Investigating benefits of adding lignin to cellulose solutions in air-gap spinning
RISE Research Institutes of Sweden, Materials and Production, Chemistry, Biomaterials and Textiles. Chalmers University of Technology, Sweden.ORCID iD: 0000-0002-2513-4289
RISE Research Institutes of Sweden, Materials and Production, Chemistry, Biomaterials and Textiles.ORCID iD: 0000-0003-2893-8554
RISE Research Institutes of Sweden, Materials and Production, Chemistry, Biomaterials and Textiles.ORCID iD: 0000-0003-1259-6414
Chalmers University of Technology, Sweden.
2021 (English)In: Journal of Applied Polymer Science, ISSN 0021-8995, E-ISSN 1097-4628, Vol. 138, no 26, article id 50629Article in journal (Refereed) Published
Abstract [en]

In this study, the underlying mechanism for improved spinnability when mixing lignin and cellulose in solution was investigated. Co-processing of lignin and cellulose has previously been identified as a potential route for production of inexpensive and bio-based carbon fibers. The molecular order of cellulose contributes to the strength of the fibers and the high carbon content of lignin improves the yield during conversion to carbon fibers. The current work presents an additional benefit of combining lignin and cellulose; solutions that contain both lignin and cellulose could be air-gap spun at substantially higher draw ratios than pure cellulose solutions, that is, lignin improved the spinnability. Fibers were spun from solutions containing different ratios of lignin, from 0 to 70 wt%, and the critical draw ratio was determined at various temperatures of solution. The observations were followed by characterization of the solutions with shear and elongational viscosity and surface tension, but none of these methods could explain the beneficial effect of lignin on the spinnability. However, by measuring the take-up force it was found that lignin seems to stabilize against diameter fluctuations during spinning, and plausible explanations are discussed

Place, publisher, year, edition, pages
John Wiley and Sons Inc , 2021. Vol. 138, no 26, article id 50629
Keywords [en]
cellulose and other wood products, extrusion, rheology, Cellulose, Fibers, Graphite fibers, Shear flow, Spinning (fibers), Beneficial effects, Cellulose solutions, Coprocessing, Diameter fluctuations, Elongational viscosity, High carbon content, Molecular ordering, Pure cellulose, Lignin
National Category
Paper, Pulp and Fiber Technology
Identifiers
URN: urn:nbn:se:ri:diva-52521DOI: 10.1002/app.50629Scopus ID: 2-s2.0-85101204470OAI: oai:DiVA.org:ri-52521DiVA, id: diva2:1536792
Note

Funding details: Chalmers Tekniska Högskola; Funding details: Kungliga Tekniska Högskolan, KTH; Funding details: Energimyndigheten; Funding text 1: This work was partly performed within the project LightFibre, a collaboration between RISE, Chalmers University of Technology, The Royal Institute of Technology, Valmet AB and SCA Forest Products AB, financed by the Swedish Energy Agency.

Available from: 2021-03-12 Created: 2021-03-12 Last updated: 2023-06-08Bibliographically approved

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Bengtsson, JennyJedvert, KerstinKöhnke, Tobias

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