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Ionic Liquid Synthesis of (Et3S)[Ag4I5] – A Structure Containing Basket-Like Silver-Iodide Cages with Ag22+ Pairs
RISE Research Institutes of Sweden, Bioeconomy and Health, Chemical Process and Pharmaceutical Development. KTH Royal Institute of Technology, Sweden.ORCID iD: 0000-0003-2410-7366
Sweden.
2021 (English)In: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 647, no 2-3, p. 59-63Article in journal (Refereed) Published
Abstract [en]

The compound (Et3S)[Ag4I5], 1, is readily synthesized from room-temperature, ionic-liquid media and displays a complex network structure of Ag6I6 cages with Ag22+ pairs forming 1D-chains linked into layers distinctly separate from the disordered sulphonium cations. The compound should be regarded as a large-bandgap semiconductor, but its significant structural voids qualify the compound a candidate for optoelectronic applications through the inclusion of suitable guest molecules. © 2020 The Authors. 

Place, publisher, year, edition, pages
Wiley-VCH Verlag , 2021. Vol. 647, no 2-3, p. 59-63
Keywords [en]
band structure, crystal structure, host-guest chemistry, Iodoargentate
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-52099DOI: 10.1002/zaac.202000338Scopus ID: 2-s2.0-85099451274OAI: oai:DiVA.org:ri-52099DiVA, id: diva2:1522699
Note

Funding details: Energimyndigheten, 46379‐1; Funding details: Stiftelsen Åforsk, 17‐594; Funding details: Vetenskapsrådet, VR, 2016‐03223; Funding text 1: The Strategic Research (SSF) with Grant FID15‐0023, ÅForsk foundation under Grant 17‐594, the Swedish Energy Agency (Grant ID: 46379‐1), and the Swedish Research Council (ID: 2016‐03223) are acknowledged for their financial support.

Available from: 2021-01-26 Created: 2021-01-26 Last updated: 2023-06-05Bibliographically approved

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Svensson, Per H

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