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Carbon, glass and basalt fiber reinforced polybenzoxazine: The effects of fiber reinforcement on mechanical, fire, smoke and toxicity properties
University of Bremen, Germany; Fraunhofer, Germany.
Fraunhofer, Germany.
RISE Research Institutes of Sweden, Safety and Transport, Fire Technology. DTU Technical University of Denmark, Denmark.ORCID iD: 0000-0002-7001-9757
RISE Research Institutes of Sweden, Safety and Transport, Fire Technology.ORCID iD: 0000-0002-6430-6602
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2020 (English)In: Polymers, E-ISSN 2073-4360, Vol. 12, no 10, article id 2379Article in journal (Refereed) Published
Abstract [en]

Bisphenol F and aniline-based benzoxazine monomers were selected to fabricate basalt, glass and carbon fiber reinforced polybenzoxazine via vacuum infusion, respectively. The impacts of the type of fiber reinforcement on the resulting material properties of the fiber reinforced polymers (FRPs) were studied. FRPs exhibited a homogenous morphology with completely impregnated fibers and near-zero porosity. Carbon fiber reinforced polybenzoxazine showed the highest specific mechanical properties because of its low density and high modulus and strength. However, regarding the flammability, fire, smoke and toxicity properties, glass and basalt reinforced polybenzoxazine outperformed carbon fiber reinforced polybenzoxazine. This work offers a deeper understanding of how different types of fiber reinforcement affect polybenzoxazinebased FRPs and provides access to FRPs with inherently good fire, smoke and toxicity performance without the need for further flame retardant additives. © 2020 by the authors.

Place, publisher, year, edition, pages
MDPI AG , 2020. Vol. 12, no 10, article id 2379
Keywords [en]
Fibers, Fire, Mechanical properties, Polybenzoxazine, Polymer-matrix composites, Smoke and toxicity, Thermal properties, Additives, Aniline, Basalt, Density (specific gravity), Fiber reinforced plastics, Glass, Graphite fibers, Smoke, Toxicity, Benzoxazine monomers, Carbon fiber reinforced, Fiber reinforced polymers, Flame-retardant additives, Glass and carbon fibers, Toxicity properties, Vacuum infusion
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Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-50432DOI: 10.3390/polym12102379Scopus ID: 2-s2.0-85092892281OAI: oai:DiVA.org:ri-50432DiVA, id: diva2:1505285
Note

Funding details: Bundesministerium für Bildung und Forschung, BMBF, 03XP0001; Funding details: Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, CAPES, BEX 13458/13-2; Funding details: 777595; Funding text 1: Funding: This work is part of the Mat4Rail project, which has received funding from the Shift2Rail Joint Undertaking under the European Union’s Horizon 2020 research and innovation program under grant agreement No 777595. V.C. Beber acknowledges the funding from CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior) through the Science without Borders program under the grant BEX 13458/13-2. K. Koschek acknowledges the funding from the Bundesministerium für Bildung und Forschung (BMBF) through the NanoMatFutur award (DuroCycleFVK 03XP0001).

Available from: 2020-11-30 Created: 2020-11-30 Last updated: 2024-01-17Bibliographically approved

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Sandinge, AnnaBlomqvist, Per

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