The thermo-oxidative durability of polyethylene reinforced with wood-based fibresShow others and affiliations
2020 (English)In: Polymer degradation and stability, ISSN 0141-3910, E-ISSN 1873-2321, Vol. 181, article id 109374Article in journal (Refereed) Published
Abstract [en]
Aiming at better understanding the ageing behaviour of cellulose composites, the accelerated thermo-oxidative ageing of polyethylene reinforced with two types of wood-based cellulose fibres was studied. Materials were prepared by extrusion mixing of either un-stabilized or stabilized polyethylene reinforced with 5 and 20 vol % cellulose content. The materials were extruded into strips and then aged at 90°C in circulating air. The effect of accelerated ageing up to 31 days was assessed by oxidation induction time and mechanical properties in tension. The results indicated that the added cellulose fibres did not increase the degradation of the composites during this ageing. Reinforcement with 20 % cellulose fibre having a 28 % lignin content together with 0.005 % Irganox 1010 antioxidant resulted in a remarkable improvement in the resistance against accelerated thermo-oxidation, compared to the pure polyethylene with added antioxidant. The findings of increased lifetime of LDPE by addition of wood-based reinforcement is of great interest, since the durability aspect is crucial to understand and predict before usage in commercial applications and especially as structural composites.
Place, publisher, year, edition, pages
Elsevier Ltd , 2020. Vol. 181, article id 109374
Keywords [en]
Accelerated ageing, Extrusion, Thermo-oxidation, Thermomechanical properties, Wood-based cellulose composites, Aliphatic compounds, Antioxidants, Cellulose, Durability, Polyethylenes, Tensile strength, Textile fibers, Thermooxidation, Wood, Cellulose composites, Cellulose content, Commercial applications, Oxidation induction time, Pure polyethylenes, Structural composites, Thermo-oxidative ageing, Reinforcement
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-49468DOI: 10.1016/j.polymdegradstab.2020.109374Scopus ID: 2-s2.0-85091628290OAI: oai:DiVA.org:ri-49468DiVA, id: diva2:1477908
Note
Funding text 1: The authors thank the Swedish Research Council Formas and Chalmers University of Technology for financial support. The Swedish Research Institute (RISE) is acknowledged for assistance with the ageing and testing equipment. The authors also thank Stora Enso for the supply of thermomechanical pulp as well as Södra Skogsägarna for the analysis of the cellulosic tissue. Axel Martinsson at the department of chemistry and chemical engineering is gratefully acknowledged for assistance in analysing the carbohydrate content of both cellulosic tissue and TMP. Dr J. A. Bristow is gratefully acknowledged for the linguistic revision of the manuscript.
2020-10-202020-10-202023-05-26Bibliographically approved