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Carbon Fibers from Lignin-Cellulose Precursors: Effect of Carbonization Conditions
RISE Research Institutes of Sweden, Bioeconomy and Health, Biorefinery and Energy.ORCID iD: 0000-0003-3346-5501
RISE Research Institutes of Sweden, Bioeconomy and Health, Material and Surface Design.ORCID iD: 0000-0002-4697-9192
KTH Royal Institute of Technology, Sweden.
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2020 (English)In: ACS Sustainable Chemistry and Engineering, E-ISSN 2168-0485, Vol. 8, no 17, p. 6826-6833Article in journal (Refereed) Published
Abstract [en]

Carbon fibers (CFs) are gaining increasing importance in lightweight composites, but their high price and reliance on fossil-based raw materials stress the need for renewable and cost-efficient alternatives. Kraft lignin and cellulose are renewable macromolecules available in high quantities, making them interesting candidates for CF production. Dry-jet wet spun precursor fibers (PFs) from a 70/30 w/w blend of softwood kraft lignin (SKL) and fully bleached softwood kraft pulp (KP) were converted into CFs under fixation. The focus was to investigate the effect of carbonization temperature and time on the CF structure and properties. Reducing the carbonization time from 708 to 24 min had no significant impact on the tensile properties. Increasing the carbonization temperature from 600 to 800 °C resulted in a large increase in the carbon content and tensile properties, suggesting that this is a critical region during carbonization of SKL:KP PFs. The highest Young's modulus (77 GPa) was obtained after carbonization at 1600 °C, explained by the gradual transition from amorphous to nanocrystalline graphite observed by Raman spectroscopy. On the other hand, the highest tensile strength (1050 MPa) was achieved at 1000 °C, a decrease being observed thereafter, which may be explained by an increase in radial heterogeneity.

Place, publisher, year, edition, pages
American Chemical Society , 2020. Vol. 8, no 17, p. 6826-6833
Keywords [en]
carbon fiber, carbonization, cellulose, dry-jet wet spinning, fully bleached softwood kraft pulp, softwood kraft lignin
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:ri:diva-44995DOI: 10.1021/acssuschemeng.0c01734Scopus ID: 2-s2.0-85084748026OAI: oai:DiVA.org:ri-44995DiVA, id: diva2:1433611
Available from: 2020-06-01 Created: 2020-06-01 Last updated: 2023-05-09Bibliographically approved

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Bengtsson, AndreasSommertune, JensSedin, MariaSjöholm, Elisabeth

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