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Review: Bio-polyethylene from Wood Wastes
IMAM Instituto de Materiales de Misiones, Argentina.
IMAM Instituto de Materiales de Misiones, Argentina.
IMAM Instituto de Materiales de Misiones, Argentina.
RISE - Research Institutes of Sweden, Bioeconomy, PFI.ORCID iD: 0000-0002-6183-2017
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2019 (English)In: Journal of polymers and the environment, ISSN 1566-2543, E-ISSN 1572-8919Article in journal (Refereed) In press
Abstract [en]

There is a global trend of substitution of fossil fuels for renewable energy sources, which are preferred by reasons including sustainability, reduction of greenhouse gases that contribute to climate change, regional and social systems advancement, among others. This review is part of the studies carried out on the integral use of wood industrial wastes due to its low costs and high availability. A possible high-value product is ethylene, obtained by catalytic dehydration of second-generation bioethanol from lignocellulosic materials and which can be an effective alternative for the production of polymers such as polyethylene (PE), which is conventionally obtained from petroleum. Biobased polyethylene or biopolyethylene (BioPE) may potentially contribute to close a pine biorefinery scheme to obtain high-value products, using processes of low pollution and contributing to the global environmental balance. The process involves the following stages: pretreatment, enzymatic saccharification, fermentation, dehydration, and polymerization. This review includes the different processes for second generation (2G) bioethylene productions from pine wastes as an example and the technologies that can potentially be applied on an industrial scale for BioPE production, focusing on the catalytic dehydration of 2G bioethanol through the use of catalysts able to achieve high ethanol conversions and ethylene selectivity.

Place, publisher, year, edition, pages
Springer New York LLC , 2019.
Keywords [en]
Bioethylene, Biopolyethylene, Biorefinery, Heterogeneous catalysis, Lignocellulosic biomass, Bioethanol, Catalysis, Catalyst selectivity, Climate change, Costs, Dehydration, Ethanol, Ethylene, Fossil fuels, Greenhouse gases, Polyethylenes, Refining, Renewable energy resources, Saccharification, Sustainable development, Bio-ethylene, Biorefineries, Enzymatic saccharification, Lignocellulosic material, Renewable energy source, Second generation bioethanol, Industrial wastes
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-40848DOI: 10.1007/s10924-019-01582-0Scopus ID: 2-s2.0-85074581357OAI: oai:DiVA.org:ri-40848DiVA, id: diva2:1371759
Note

Funding details: Consejo Nacional de Investigaciones Científicas y Técnicas, CONICET; Funding details: Norges Forskningsråd, 271054; Funding details: Consejo Nacional de Investigaciones Científicas y Técnicas, CONICET, ELAC2015/T03-0715; Funding text 1: This work has been funded by the National University of Missions, the National Scientific and Technical Research Council (CONICET), and the ValBio-3D project Grant ELAC2015/T03-0715 Valorization of residual biomass for advanced 3D materials (Ministry of Science, Technology and Innovation Production of Argentina, and Research Council of Norway, Grant No. 271054). PE Polyethylene PVC Polyvinylchloride EHY Enzymatic hydrolysis yield EH Enzymatic hydrolysis AQ Anthraquinone SHF Hydrolysis and fermentation SSF Simultaneous saccharification and fermentation DMC Direct microbial conversion HMF Hydroxymethylfurfural PP Polypropylene E1 Mechanism of elimination reaction (unimolecular) E2 Mechanism of elimination reaction (bimolecular) SN1 Nucleophilic substitution reaction (unimolecular) SN2 Nucleophilic substitution reaction (bimolecular)

Available from: 2019-11-20 Created: 2019-11-20 Last updated: 2019-12-04Bibliographically approved

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Chinga-Carrasco, Gary

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