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Initial formation of corrosion products on pure zinc and MgZn2 examinated by XPS
RISE - Research Institutes of Sweden, Materials and Production, KIMAB. Universite de Brest, France. (Institut de la Corrosion)
Universite de Brest, France.
Universite de Brest, France.
Universite de Brest, France.
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2014 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 79, p. 83-88Article in journal (Refereed) Published
Abstract [en]

A corrosion behaviour study of pure phases of zinc and zinc-magnesium (MgZn2) exposed to humid air at 35°C for 4days is presented. For zinc, hydroxide formation at the surface and zinc oxide in the first innerlayers is observed. The corrosion of the MgZn2 leads to the segregation of magnesium at the surface to mainly form magnesium hydroxycarbonate: the presence of magnesium modifies the corrosion products. At larger depths, metallic zinc coexists with magnesium oxide and hydrozincite. The higher reactivity of MgZn2 alloy can be attributed to the interaction with carbonate ions.

Place, publisher, year, edition, pages
2014. Vol. 79, p. 83-88
Keywords [en]
A. Magnesium, A. Zinc, B. XPS, C. Atmospheric corrosion, Carbonate ions, Corrosion behaviour, Corrosion products, Exposed to, Humid air, Hydroxy carbonates, Hydrozincite, Pure zinc, Atmospheric corrosion, Surface segregation, X ray photoelectron spectroscopy, Zinc, Magnesium
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:ri:diva-40398DOI: 10.1016/j.corsci.2013.10.029Scopus ID: 2-s2.0-84890216871OAI: oai:DiVA.org:ri-40398DiVA, id: diva2:1361496
Available from: 2019-10-16 Created: 2019-10-16 Last updated: 2019-10-16Bibliographically approved

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