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Evaluation of ceramic sacrificial coatings for improved alkaliinduced corrosion protection in biofuel-fired boilers
Goceram.
Chalmers Tekniska Högskola.
RISE - Research Institutes of Sweden, Swerea, Swerea IVF.ORCID iD: 0000-0001-6859-6830
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2013 (English)Conference paper, Oral presentation with published abstract (Refereed)
Abstract [en]

In the combustion of bio-based fuels the critically exposed burner parts in small boilers are typically uncooled and are usually made of FeCrNi alloys. These materials can suffer attack from the ashes because of the formation of alkali chromate. The reaction depletes the protective oxide in chromia, leading to accelerated corrosion. Selected "acidic" ceramic coatings based on Ti, Si, B and P have been evaluated for use as sacrificial layers to prevent the initial reaction of alkali and chromium. An accelerated oxidation test method including mild thermal shock has been utilized that previously proved useful to provide application-relevant results. A comparison of coated and uncoated specimens was performed with an austenitic high temperature steel as a substrate. The results indicate that the alkali released from the ash reacts with the respective "acidic" elements in the deposited coatings. This reaction has promoted initial formation of a thin and continuous chromium-rich protective oxide sub-layer. In addition, the oxide scale formed on the coated specimens appeared more coherent and crack-free. A significant enrichment of Ni at the steel-oxide interface also occurred that can promote high temperature corrosion resistance. 

Place, publisher, year, edition, pages
2013.
Keywords [en]
Accelerated corrosion; Accelerated oxidations; Alkali corrosion; Deposited coatings; High temperature corrosion resistance; Protective oxides; Sacrificial coatings; Steel-oxide interfaces, Biofuels; Ceramic coatings; Chromium; Coatings; Corrosion resistance; Corrosion resistant alloys; Scale (deposits); Screening; Testing; Thermal shock, Boilers
National Category
Ceramics
Identifiers
URN: urn:nbn:se:ri:diva-31865Scopus ID: 2-s2.0-84883092175OAI: oai:DiVA.org:ri-31865DiVA, id: diva2:1149811
Conference
NACE – International Corrosion Conference, Orlando, Fl, March 17-21.
Available from: 2017-10-17 Created: 2017-10-17 Last updated: 2017-10-24Bibliographically approved

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CiteExportLink to record
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Citation style
  • apa
  • harvard1
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