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Infrared electrochromic conducting polymer devices
Linköping University, Sweden.
Linköping University, Sweden.
Linköping University, Sweden.
RISE - Research Institutes of Sweden, ICT, Acreo. Linköping University, Sweden.
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2017 (English)In: Journal of Materials Chemistry C, ISSN 2050-7526, E-ISSN 2050-7534, Vol. 5, no 23, p. 5824-5830Article in journal (Refereed) Published
Abstract [en]

The conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) is well known for its electrochromic properties in the visible region. Less focus has been devoted to the infrared (IR) wavelength range, although tunable IR properties could enable a wide range of novel applications. As an example, modern day vehicles have thermal cameras to identify pedestrians and animals in total darkness, but road and speed signs cannot be easily visualized by these imaging systems. IR electrochromism could enable a new generation of dynamic road signs that are compatible with thermal imaging, while simultaneously providing contrast also in the visible region. Here, we present the first metal-free flexible IR electrochromic devices, based on PEDOT:Tosylate as both the electrochromic material and electrodes. Lateral electrochromic devices enabled a detailed investigation of the IR electrochromism of thin PEDOT:Tosylate films, revealing large changes in their thermal signature, with effective temperature changes up to 10 °C between the oxidized (1.5 V) and reduced (-1.5 V) states of the polymer. Larger scale (7 × 7 cm) vertical electrochromic devices demonstrate practical suitability and showed effective temperature changes of approximately 7 °C, with good optical memory and fast switching (1.9 s from the oxidized state to the reduced state and 3.3 s for the reversed switching). The results are highly encouraging for using PEDOT:Tosylate for IR electrochromic applications.

Place, publisher, year, edition, pages
2017. Vol. 5, no 23, p. 5824-5830
Keywords [en]
Conducting polymers, Electrochromic devices, Infrared imaging, Polymer films, Roads and streets, Sulfur compounds, Temperature, Effective temperature, Electro-chromic applications, Electrochromic materials, Electrochromic properties, Infrared wavelengths, Novel applications, Poly(3, 4 ethylenedioxythiophene) (PEDOT), Thermal signatures, Electrochromism
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Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-31115DOI: 10.1039/c7tc00257bScopus ID: 2-s2.0-85021669689OAI: oai:DiVA.org:ri-31115DiVA, id: diva2:1136522
Available from: 2017-08-28 Created: 2017-08-28 Last updated: 2017-08-28Bibliographically approved

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