Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
On the temperature dependency and reversibility of sheet resistance of silver nanoparticles covered by 3-mercaptopropionic acid
Beijing Engineering Research Center of Printed Electronics, Beijing Institute of Graphic Communication, Beijing, China.
RISE, Innventia.
Beijing Engineering Research Center of Printed Electronics, Beijing Institute of Graphic Communication, Beijing, China.
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Science, Beijing, China.
Show others and affiliations
2017 (English)In: Journal of materials science. Materials in electronics, ISSN 0957-4522, E-ISSN 1573-482X, Vol. 28, no 5, 4035-4043 p.Article in journal (Refereed) Published
Abstract [en]

The temperature dependency and reversibility of the sheet resistance of silver nanoparticles covered by 3-mercaptopropionic acid (Ag-MPA) molecules, used in the printed temperature sensor, has been investigated. The microstructural evaluation, the FTIR spectra and thermal property analyses of the Ag-MPA films suggest co-existence of both weakly adsorbed as well as firmly adsorbed MPA molecules on the surface of Ag nanoparticles. The weakly adsorbed MPA molecules was to a great extent be desorbed and removed from the surfaces of silver nanoparticles when heated up to 180 °C for the first time. While the firmly adsorbed MPA molecules remain on the surfaces of silver nanoparticles even at higher temperature. Yet the firmly adsorbed MPA molecules are likely having gone through a transformation circle from/to the gauche and trans conformations in correspondence to a heating and cooling cycle, which results in temperature dependent and reversible sheet resistance. The MPA molecules in the gauche conformation are more densely packed on the surface of silver nanoparticles and can hinder the electron’s movability within the Ag-MPA film. While in the trans conformation with lower ‘surface space’ coverage by the MPA molecules, electrons move more freely within the film. Based on the temperature dependent nature, the fully printed temperature sensor using the Ag-MPA nanoparticles as the functional layer was made, of which the highest sensitivity is 5.12% °C−1 at 200 °C.

Place, publisher, year, edition, pages
2017. Vol. 28, no 5, 4035-4043 p.
Keyword [en]
printing, temperature, silver, nanoparticle
National Category
Materials Engineering
Identifiers
URN: urn:nbn:se:ri:diva-30308DOI: 10.1007/s10854-016-6017-9OAI: oai:DiVA.org:ri-30308DiVA: diva2:1131313
Available from: 2017-08-14 Created: 2017-08-14 Last updated: 2017-08-17Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full texthttps://rd.springer.com/article/10.1007/s10854-016-6017-9
By organisation
Innventia
In the same journal
Journal of materials science. Materials in electronics
Materials Engineering

Search outside of DiVA

GoogleGoogle Scholar

Altmetric score

Total: 1 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
v. 2.27.0