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Effects of thermo-hygro-mechanical (THM) treatment on the viscoelasticity of in-situ lignin
Chinese Academy of Forestry, China.
Chinese Academy of Forestry, China.
Chinese Academy of Forestry, China.
RISE - Research Institutes of Sweden (2017-2019), Bioeconomy. RISE, Innventia.ORCID iD: 0000-0003-3534-1107
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2017 (English)In: Holzforschung, ISSN 0018-3830, E-ISSN 1437-434X, Vol. 71, no 6, p. 455-460Article in journal (Refereed) Published
Abstract [en]

For producing wood products without fractures based on thermo-hygro-mechanical (THM) treatments, it is essential to understand how steaming and compression change the wood softening and cell wall components. In this paper, the effects of compression combined with steam treatment (CS) on the viscoelasticity of the in-situ lignin of Chinese fir has been investigated through dynamic mechanical analysis (DMA) under fully saturated conditions. Several variations were studied, such as the softening temperature (Tg) and apparent activation energy (ΔHa) of the softening process in response to CS treatment conditions (such as steam temperature and compression ratio) under separate consideration of earlywood (EW) and latewood (LW). No difference between EW and LW with respect to the viscoelasticity was noted. Tg and ΔHa of the lignin softening were nearly unaffected by the compression ratio, but were highly influenced by the steam temperature. The Tg decreased significantly with CS treatments at or above 160oC, but showed no appreciable change, compared to the native wood, at the lower steaming temperature of 140oC. ΔHa increased at higher steam temperatures, while ΔHa showed a decreasing tendency with decreasing Tg. This indicates that lignin undergoes a simultaneous depolymerization as well as a condensation during CS treatment.

Place, publisher, year, edition, pages
Walter de Gruyter GmbH , 2017. Vol. 71, no 6, p. 455-460
Keywords [en]
Activation energy; Compression ratio (machinery); Dynamic mechanical analysis; Dynamics; Lignin; Steam; Viscoelasticity, Apparent activation energy; Dynamic mechanical analysis (DMA); Earlywood; Latewood; softening; Softening temperature; Steam temperature; Thermo-hygro-mechanical treatments, Wood
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:ri:diva-30032DOI: 10.1515/hf-2016-0201Scopus ID: 2-s2.0-85020397682OAI: oai:DiVA.org:ri-30032DiVA, id: diva2:1119692
Available from: 2017-07-04 Created: 2017-07-04 Last updated: 2020-12-01Bibliographically approved

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Salmen, Lennart

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