The temperature characteristics of the birefringence of side-hole fibers filled with liquids or metal are investigated, aiming at providing a basis for on/off temperature sensing. Short pieces of fiber are filled and the change in birefringence is registered using measurements in reflective mode of the transmitted power through a linear polarizer at 1550 nm. The rapid change in the birefringence behavior of the fiber at the temperature of the phase transition of the filler substance is shown, and from the measurement data the phase transition temperatures can be determined as well as an estimation of the birefringence change with temperature. The experimental results are supported by numerical simulations.