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New techniques for determining the extent of crosslinking in coatings
YKI – Ytkemiska institutet.
YKI – Ytkemiska institutet.
YKI – Ytkemiska institutet.
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2001 (English)In: Progress in organic coatings, ISSN 0300-9440, E-ISSN 1873-331X, Vol. 43, 85-98 p.Article in journal (Refereed)
Abstract [en]

Crosslinking reactions in latex and alkyd systems offer an attractive way to achieve film formation at low temperatures while also achieving a final hard coating. There is a strong need for techniques to characterise the extent of crosslinking as a function of time and depth in this type of coating. Here magnetic resonance imaging (MRI) (using a magnet specifically designed for coatings) and a quartz crystal microbalance with energy dissipation are both used as non-invasive techniques for this purpose. The crosslinking in alkyd films containing a cobalt drier is found to be non-uniform with depth. In a latex, crosslinking depth profiles are likewise non-uniform, most likely as a result of oxygen inhibition of the initiator

Place, publisher, year, edition, pages
2001. Vol. 43, 85-98 p.
Keyword [en]
Latex film formation, crosslinking, magnetic resonance imaging, QCM-D, alkyd emulsions
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-27433OAI: oai:DiVA.org:ri-27433DiVA: diva2:1054437
Note
A1462Available from: 2016-12-08 Created: 2016-12-08Bibliographically approved

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