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Forces in dimethyldodecylamine oxide- and dimethyldodecylphosphine oxide- water systems measured with an osmotic stress technique
RISE, SP – Sveriges Tekniska Forskningsinstitut, SP Sveriges tekniska forskningsinstitut, YKI – Ytkemiska institutet.
RISE, SP – Sveriges Tekniska Forskningsinstitut, SP Sveriges tekniska forskningsinstitut, YKI – Ytkemiska institutet.
1993 (English)In: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 9, p. 2926-2932Article in journal (Refereed)
Abstract [en]

The structural parameters of the hexagonal and lamellar phase of the dimethyldodecylamine oxide (DDAO)-water and the dimethyl-dodecylphosphine oxide (DDPO)-water systems have been determined using X-ray diffraction. In addition the relative vapour pressure of water in equilibrium with these phases was determined as a function of surfactant concentration and temperature. This allowed the determination of the swelling pressure in the lamellar phase. It was found that the swelling pressure was considerably higher in the DDAO-water system than in DDPO-water. For both surfactants, but most pronounced so for DDPO, the swelling pressure decreased with increasing temperature. The results obtained are discussed in the light of the ongoing debates about i) the relative importance of steric/protrusion forces and hydration forces between surfactant bilayers, and ii) the molecular origin of the temperature dependence of the interactions displayed in several non-ionic - water systems.

Place, publisher, year, edition, pages
1993. Vol. 9, p. 2926-2932
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-27286OAI: oai:DiVA.org:ri-27286DiVA, id: diva2:1054290
Note
A845Available from: 2016-12-08 Created: 2016-12-08 Last updated: 2020-12-01Bibliographically approved

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