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Surface interactions during polyelectrolyte multilayer build-up. 2. The effect of ionic strength on the structure of preformed multilayers
YKI – Ytkemiska institutet.
YKI – Ytkemiska institutet.
2006 (English)In: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 22, no 9, 4153-4157 p.Article in journal (Refereed)
Abstract [en]

Interactions between surfaces bearing multilayer films of poly(allylamine hydrochloride) (PAH) and poly-(styrenesulfonate sodium salt) (PSS) were investigated across a range of aqueous KBr solutions. Three layer films (PAH/PSS/PAH) were preassembled on mica surfaces, and the resulting interactions were measured with the interferometric surface force apparatus (SFA). Increasing the ionic strength of the medium resulted in a progressive swelling of the multilayer films. Interactions in solutions containing more than 10-3 M KBr were dominated by a long-ranged steric repulsion originating from compression of polyelectrolyte segments extending into solution. In 10-1 M KBr, repeated measurements at the same contact position showed a considerable reduction of the range and the strength of the steric force, indicating a flattening of the film during initial approach. Furthermore, this flattening was irreversible on the time scale of the experiments, and measurements performed up to 72 h after the initial compression showed no signs of relaxation. These studies aid in understanding the dominant interactions between polyelectrolyte multilayers, including polyelectrolyte films deposited on colloidal particles, which is important for the preparation of colloidally stable nanoengineered particles.

Place, publisher, year, edition, pages
2006. Vol. 22, no 9, 4153-4157 p.
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-27159OAI: oai:DiVA.org:ri-27159DiVA: diva2:1054163
Note
A1865Available from: 2016-12-08 Created: 2016-12-08Bibliographically approved

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