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Molecular exchange in thermal equilibrium between dissolved and crystalline tripalmitin by NMR
RISE, SP – Sveriges Tekniska Forskningsinstitut, SP Sveriges tekniska forskningsinstitut, YKI – Ytkemiska institutet.
RISE, SP – Sveriges Tekniska Forskningsinstitut, SP Sveriges tekniska forskningsinstitut, YKI – Ytkemiska institutet.
2003 (English)In: Journal of the American Oil Chemists Society, ISSN 0003-021X, E-ISSN 1558-9331, Vol. 80, p. 1187-1192Article in journal (Refereed)
Abstract [en]

An NMR technique to measure the exchange kinetics at thermal equilibrium in dispersions of moderately soluble crystalline material is presented. By monitoring the exchange of molecules between pools in solid and dissolved form one can characterize the surface specific exchange rate. Illustrative experiments were performed in a model system with b-type crystals of tripalmitin as the solid phase and tripalmitin, a fraction of it deuterated, dissolved in a medium chain triglyceride oil as the liquid phase. The concentration of deuterated tripalmitin in the solvent was followed by 2H NMR after the crystals, that initially lack deuterated tripalmitin, were immersed in the liquid. The variation of the 2H concentration in the solvent provided the surface specific exchange rate. No systematic errors, due to the slight difference in properties of the deuterated tripalmitin (2H-PPP) compared to hydrogenated tripalmitin (1H-PPP), were observed. The methodology worked well between crystal concentrations of 2 and 4-wt%.

Place, publisher, year, edition, pages
2003. Vol. 80, p. 1187-1192
Keywords [en]
Dispersion, triglyceride, deuterium NMR, areas of Colloid and Surface Chemistry<
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-26984OAI: oai:DiVA.org:ri-26984DiVA, id: diva2:1053987
Note
A1487Available from: 2016-12-08 Created: 2016-12-08 Last updated: 2020-12-01Bibliographically approved

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