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Reactive surfactants in heterophase polymerization for high performance polymers. Part 1. Synthesis of functionalized poly(ethylene oxide)-b-poly(butylene oxide) copolymers as surfmers inisurfs and transurfs in heterophase polymerization
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1998 (English)In: Colloid and Polymer Science, ISSN 0303-402X, E-ISSN 1435-1536, Vol. 276, p. 402-411Article in journal (Refereed)
Abstract [en]

A variety of non-ionic reactive surfactants have been prepared from block copolymers precursors. These precursors are formed from a commercially available polyethylene glycol monoethylether as the hydrophilic sequence of the surfactant; this product is used as initiator of living polymerization of butylene oxide. Finally the reactive surfactants are obtained after proper functionalization of the precursors. The reactive surfactants are an inisurf with an asymmetric azo compound, a transurf with a thiol group, and a few surfmers with acrylic, methacrylic, styrenic and a-methylstyrenic reactive groups. These compounds have been engaged in styrene emulsion or dispersion polymerization. Several of them are useful to prepare stable latexes.

Place, publisher, year, edition, pages
1998. Vol. 276, p. 402-411
Keywords [en]
Block-copolymers, polyethylene oxide, polybutylene oxide, reactive surfactants, emulsion polymerization, dispersion polymerization
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-26362OAI: oai:DiVA.org:ri-26362DiVA, id: diva2:1053364
Note
A1085Available from: 2016-12-08 Created: 2016-12-08 Last updated: 2017-11-29Bibliographically approved

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