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Thermodynamics of the hydration of non-polar substances
YKI – Ytkemiska institutet.
1998 (English)In: Biophysical Chemistry, ISSN 0301-4622, E-ISSN 1873-4200, Vol. 70, 57-63 p.Article in journal (Refereed)
Abstract [en]

We re-examine the numerical value and physical significance of TS , the temperature where the entropy of transfer Δ WLCP fitting function. It is concluded that the interpretation of TS as the temperature where hydration ceases cannot be sustained. As previously reported [R.L. Baldwin, N. Muller, Proc. Natl. Acad. Sci. USA, 89 (1992) 7110], hydration must vanish at a temperature T1 >TS, where its experimental manifestation, i.e., ΔWL CP, is zero. We discuss the concept of water relaxation around a non-polar solute molecule and its relation to the hydration process.

Place, publisher, year, edition, pages
1998. Vol. 70, 57-63 p.
Keyword [en]
Hydrophobic effect, Aqueous solutions, Protein folding.
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-26325OAI: oai:DiVA.org:ri-26325DiVA: diva2:1053327
Note
A1190Available from: 2016-12-08 Created: 2016-12-08Bibliographically approved

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