Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Liquid phase acetoxylation of α-pinene over Amberlyst-70 ion-exchange resin
Umeå University, Sweden.
Umeå University, Sweden.
RISE, SP – Sveriges Tekniska Forskningsinstitut, SP Processum.ORCID iD: 0000-0001-7600-8971
Aditya Birla Domsjö Fabriker AB, Sweden.ORCID iD: 0000-0001-6682-2910
Show others and affiliations
2012 (English)In: Applied Catalysis A: General, ISSN 0926860X, Vol. 435-436, p. 43-50Article in journal (Refereed) Published
Abstract [en]

Heterogeneously-catalyzed and solvent-catalyzed liquid phase acetoxylation of α-pinene with acetic acid acting as both a solvent and a reagent was studied. Both solvent-catalyzed and catalytic experiments were carried out and various reaction conditions were studied. The influence of temperature, pressure, solvent and gas milieu were taken into account. Bornyl, fenchyl, verbenyl as well as α-terpinyl acetates, limonene, camphene and γ-terpinene were found among reaction products. The addition of the catalyst allowed for maximization of the yield of bornyl acetate. The predominant products obtained were α-terpinyl, verbenyl and bornyl acetates. The reaction pathways were identified and evaluated. The aim of this work was to study the feasibility of batch acetoxylation of α-pinene. The analysis of the complex product distribution is not trivial and, consequently, resolving the reaction network was important. The optimized reaction conditions were searched for aiming at an efficient conversion of α-pinene to a mixture of valuable products.

Place, publisher, year, edition, pages
2012. Vol. 435-436, p. 43-50
Keywords [en]
α-Pinene acetoxylation, α-Terpinyl acetate, Amberlyst 70, Biorefinery, Heterogeneous catalyst
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-191DOI: 10.1016/j.apcata.2012.05.034Scopus ID: 2-s2.0-84864548149OAI: oai:DiVA.org:ri-191DiVA, id: diva2:936054
Available from: 2016-06-13 Created: 2016-06-13 Last updated: 2021-06-18Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus

Authority records

Blomberg Saitton, DavidGrundberg, Hans

Search in DiVA

By author/editor
Blomberg Saitton, DavidGrundberg, Hans
By organisation
SP Processum
Natural Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 86 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf