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Effect of temperature on corrosion in saturated ammonium chloride solution
RISE Research Institutes of Sweden, Materials and Production, Corrosion.
RISE Research Institutes of Sweden, Materials and Production, Corrosion.ORCID iD: 0000-0002-2339-9443
RISE Research Institutes of Sweden, Materials and Production, Corrosion.ORCID iD: 0000-0001-5399-9274
2024 (English)In: AMPP Annual Conference and Expo 2024, Association for Materials Protection and Performance , 2024Conference paper, Published paper (Refereed)
Abstract [en]

The highly corrosive behavior of ammonium chloride (NH4Cl) is known to originate from its intrinsic hygroscopic nature. Refining and co-processing process units for biofuels are often exposed to highly concentrated NH4Cl solution either resulting from water vaporization from an HCl and NH3 containing solution when the temperature increases or salt deposition from vapor phase when the temperature drops. For the latter case, once it reacts with water vapor present in the process, the deposited NH4Cl salts forms a concentrated and corrosive solution through deliquescence (unlike in conventional refinery). Consequently, severe pitting and localized corrosion are reported in hydrogenation and fluid cracking units. Therefore, studying corrosion resistance alloys (CRA) compatibility in the presence of concentrated NH4Cl salt solution is crucial to mitigate corrosion in the process. This paper reports the experimental evaluation of corrosion resistance of different CRAs, based on corrosion rate and stress corrosion cracking, exposed to saturated NH4Cl solution in the temperature range of 130-220°C. 

Place, publisher, year, edition, pages
Association for Materials Protection and Performance , 2024.
Keywords [en]
Atmospheric corrosion; Chlorine compounds; Corrosion protection; Corrosion rate; Corrosion resistance; Corrosion resistant alloys; Corrosive effects; Driers (materials); Pitting; Seawater corrosion; Ammonium chloride; Biorefining; Chloride solutions; Coprocessing; Corrosion in biorefining process; Corrosion-resistant alloys; Effects of temperature; Exposed to; Hygroscopic nature; Stress-corrosion; Stress corrosion cracking
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:ri:diva-76499Scopus ID: 2-s2.0-85210883426OAI: oai:DiVA.org:ri-76499DiVA, id: diva2:1931448
Conference
Association for Materials Protection and Performance Annual Conference and Expo 2024. New Orleans, USA. 3 March 2024 through 7 March 2024
Available from: 2025-01-27 Created: 2025-01-27 Last updated: 2025-01-27Bibliographically approved

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Norling, RikardMendibide, Christophe

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