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Primary and digested sludge-derived char as a Cd sorbent: Feasibility of local utilisation
Mälardalen University, Sweden.ORCID iD: 0000-0002-9373-2774
University of Oulu, Finland.
University of Oulu, Finland.
Mälardalen University, Sweden.
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2023 (English)In: Water Science and Technology, ISSN 0273-1223, E-ISSN 1996-9732, Vol. 88, no 11, p. 2917-2930Article in journal (Refereed) Published
Abstract [en]

Cadmium (Cd) is a highly toxic metal, occurring in municipal wastewater and stormwater as well as in wastewater from various industries. Char derived from the pyrolysis of municipal sewage sludge has the potential to be a low-cost sorption media for the removal of Cd. However, the balance between possible local char production and demand has not been assessed previously. In this study, the Cd sorption capacities of chars derived from primary (PSC) and secondary sludge (DSC), as well as the feasibility of char production for Cd sorbent purposes, and the pyrolysis energy balance were evaluated. Results showed that the sorption capacity of PSC (9.1 mg/g; 800 C, 70 min) was superior to that of DSC (6.0 mg/g; 800 C, 70 min), and increased with a higher pyrolysis temperature. Pyrolysis of primary sludge had a more favourable energy balance compared with the pyrolysis of digested sludge; however, when accounting for loss of biogas production the energy balance of primary sludge pyrolysis was negative. Assessment of the regional demand (Västeras, Sweden) indicated that PSC or DSC may cover the local Cd sorbent demand. However, it was estimated that large char volumes would be required, thus making the use of DSC/PSC less feasible. 

Place, publisher, year, edition, pages
IWA Publishing , 2023. Vol. 88, no 11, p. 2917-2930
Keywords [en]
adsorbent, adsorption, biochar, biosolids, biosorbent, Energy balance, Pyrolysis, Sewage sludge, Sorption, Biosorbents, Digested sludges, Low-costs, Municipal sewage sludge, Municipal wastewaters, Primary sludge, Sorption capacities, Stormwaters, Toxic metals, Cadmium, biogas, char, charcoal, sorbent, storm water, unclassified drug, activated sludge, sewage, stormwater, wastewater, anaerobic digestion, Article, biosolid, comparative study, controlled study, dewatering, moisture, municipal wastewater, sludge digestion, waste water management, waste water treatment plant, feasibility study, high temperature, Sweden, Feasibility Studies, Hot Temperature
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:ri:diva-72388DOI: 10.2166/wst.2023.356Scopus ID: 2-s2.0-85179766907OAI: oai:DiVA.org:ri-72388DiVA, id: diva2:1846670
Available from: 2024-03-25 Created: 2024-03-25 Last updated: 2024-04-02Bibliographically approved

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