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Washing Post-Consumer Flexible Polyethylene Packaging Waste
Chalmers University of Technology, Sweden.
RISE Research Institutes of Sweden, Materials and Production, Polymeric Materials and Composites.ORCID iD: 000-0001-7365-2921
Chalmers University of Technology, Sweden.
2022 (English)In: Recycling, E-ISSN 2313-4321, Vol. 7, no 6, article id 90Article in journal (Refereed) Published
Abstract [en]

The mechanical and thermal properties of injection-molded recycled polyethylene were studied, specifically with respect to the influence of large-scale washing and melt-compounding of polyethylene from post-consumer packaging waste. Three types of materials were studied: those taken after sorting, after sorting and washing, and after sorting, washing, and melt-compounding, including melt-filtration, all from a large-scale material flow. The materials were further processed on a laboratory scale and compared. The results showed that large-scale washing significantly reduced thermo-oxidative stability, as well as molar mass and melt viscosity. The degradation during large-scale washing made the material susceptible to further degradation in the subsequent extrusion compounding, as shown by the differences in compounding at 240 and 200 °C using a high-shear screw configuration. The compounding parameters, screw configuration, and compounding temperature did not influence the stiffness and strength of the unwashed and large-scale-washed materials, but the elongation-at-break varied, specifically, with the increased temperature. Washing had an influence on the mechanical properties as well, and the unwashed material provided molded samples with stiffness measurements of approximately 550 MPa, whereas the large-scale-washed material provided stiffness of approximately 400 MPa. The strength measurements were approximately 15 MPa for samples made of both unwashed and large-scale-washed material, and the elongation-at-break measurements were between 50 and 150%. The large-scale-washed and compounded materials had very different mechanical properties, with stiffness measurements of approximately 320 MPa, strength of approximately 20 MPA, and elongation-at-break of approximately 350%. The significantly different mechanical properties of the large-scale-washed and compounded materials were likely due to the melt-filtration included in the compounding through the removal of metal and rubber particles, and they may also have been due to the compatibilizing and stabilizing additive used in the compounding. © 2022 by the authors.

Place, publisher, year, edition, pages
MDPI , 2022. Vol. 7, no 6, article id 90
Keywords [en]
degradation, mechanical properties, melt-compounding, plastics recycling, polyethylene, washing
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:ri:diva-62580DOI: 10.3390/recycling7060090Scopus ID: 2-s2.0-85144731205OAI: oai:DiVA.org:ri-62580DiVA, id: diva2:1729413
Note

Funding details: ID11297; Funding text 1: The authors thank the Norwegian Retailers’ Environment Fund, Plastkretsen AB: s Stiftelse för Forskning and Chalmers University of Technology for the financial support. The Swedish Plastic Recycling AB and the Research Institutes of Sweden (RISE) are acknowledged for their support in sampling and in the melt mass-flow rate measurements, respectively. J. A. Bristow is gratefully acknowledged for his linguistic revision of the manuscript.; Funding text 2: This work was funded by the Norwegian Retailers’ Environment Fund, grant number ID11297, Plastkretsen AB: s Stiftelse för Forskning and Chalmers University of Technology.

Available from: 2023-01-20 Created: 2023-01-20 Last updated: 2024-01-19Bibliographically approved

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Venkatesh, Abhijit

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