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Hydrophobization of lignocellulosic materials part III: modification with polymers
RISE Research Institutes of Sweden, Bioeconomy and Health, Material and Surface Design.ORCID iD: 0000-0002-4273-231x
Western Norway University of Applied Sciences, Norway.
RISE Research Institutes of Sweden, Bioeconomy and Health, Material and Surface Design.ORCID iD: 0000-0001-5522-0009
RISE Research Institutes of Sweden, Bioeconomy and Health, Material and Surface Design. NTNU, Norway.ORCID iD: 0000-0003-2271-3637
2022 (English)In: Cellulose, ISSN 0969-0239, E-ISSN 1572-882X, Vol. 29, no 11, p. 5943-5977Article in journal (Refereed) Published
Abstract [en]

This review is the third part of a series of reviews on hydrophobization of lignocellulosic materials, a relevant topic nowadays, due to the need to replace fossil fuel-based materials. The review provides an overview of the hydrophobization of lignocellulosic materials by polymer adsorption, and both chemical and radiation-induced grafting of polymers. While adsorbed polymers are only attached to the surfaces by physical interactions, grafted polymers are chemically bonded to the materials. Radiation-induced grafting is typically the most environmentally friendly grafting technique, even though it provides little control on the polymer synthesis. On the other hand, controlled radical polymerization reactions are more complex but allow for the synthesis of polymers with elaborated architectures and well-defined properties. Overall, a wide range of contact angles can be obtained by polymer adsorption and grafting, from a slight increase in hydrophobicity to superhydrophobic properties. The choice of modification technique depends on the end-use of the modified material, but there is a clear trend towards the use of more environmentally friendly chemicals and processes and the grafting of polymers with complex structures. Graphical abstract: [Figure not available: see fulltext.]. © 2022, The Author(s).

Place, publisher, year, edition, pages
Springer Science and Business Media B.V. , 2022. Vol. 29, no 11, p. 5943-5977
Keywords [en]
Cellulose, Hydrophobization, Polymer adsorption, Polymer grafting, Adsorption, Fossil fuels, Hydrophobicity, Adsorbed polymers, Chemically bonded, Grafted polymers, Hydrophobizations, Lignocellulosic material, Physical interactions, Property, Radiation-induced grafting, Grafting (chemical), Copolymerization, Materials, Polymers, Review, Synthesis, Water Repellence
National Category
Environmental Sciences
Identifiers
URN: urn:nbn:se:ri:diva-59911DOI: 10.1007/s10570-022-04660-0Scopus ID: 2-s2.0-85132259855OAI: oai:DiVA.org:ri-59911DiVA, id: diva2:1686792
Note

 Correspondence Address: Rodríguez-Fabià, S.; RISE PFINorway; email: sandra.fabia@rise-pfi.no; Funding details: Norges Forskningsråd, 274975; Funding text 1: The authors would like to acknowledge the Research Council of Norway, and their funding of the NanoPlasma project (274975).

Available from: 2022-08-11 Created: 2022-08-11 Last updated: 2023-05-25Bibliographically approved

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Rodriguez Fabia, SandraJohansson, LarsSyverud, Kristin

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