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Hydrogen detection in high strength dual phase steel using scanning Kelvin probe technique and XPS analyses
RISE Research Institutes of Sweden, Materials and Production, Corrosion. (Institut de la Corrosion)ORCID iD: 0000-0002-6847-5446
JFE Steel Corporation, Japan.
Univ Brest, France.
RISE Research Institutes of Sweden, Materials and Production, Corrosion. (Institut dela Corrosion)ORCID iD: 0000-0002-6347-994x
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2022 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 197, article id 110072Article in journal (Refereed) Published
Abstract [en]

Hydrogen permeation through high strength DP1180 steel was studied by Scanning Kelvin Probe (SKP) and X-ray photoelectron spectroscopy (XPS). The XPS analyses showed that hydrogen desorption from the steel increased the ratio Fe(II)/Fe(III) related to oxide film reduction. In parallel, a drop of the electrochemical potential in the oxide film was measured by SKP. Analyses of the composition and potential of the surface were correlated based on Nernst red-ox thermodynamic equilibrium. From this approach, it was shown that the SKP potential can be a measure of hydrogen affecting the surface oxide, but additional contributions should be considered. © 2022 The Authors

Place, publisher, year, edition, pages
Elsevier Ltd , 2022. Vol. 197, article id 110072
Keywords [en]
High strength steel, Hydrogen, Scanning Kelvin Probe, XPS, Iron compounds, Oxide films, Probes, Scanning, X ray photoelectron spectroscopy, Dual-phases steels, Film reduction, High-strength, High-strength steels, Hydrogen desorption, Hydrogen detection, Hydrogen permeation, Parallel A, Scanning Kelvin probe techniques, Scanning Kelvin probes
National Category
Metallurgy and Metallic Materials
Identifiers
URN: urn:nbn:se:ri:diva-58510DOI: 10.1016/j.corsci.2021.110072Scopus ID: 2-s2.0-85122635828OAI: oai:DiVA.org:ri-58510DiVA, id: diva2:1638823
Available from: 2022-02-17 Created: 2022-02-17 Last updated: 2023-05-16Bibliographically approved

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Vucko, FlavienDiler, ErwanThierry, Dominique

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