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Synergistic fire-retardancy properties of melamine coated ammonium poly(phosphate) in combination with rod-like mineral filler attapulgite for polymer-modified bitumen roofing membranes
DTU Technical University of Denmark, Denmak.
RISE Research Institutes of Sweden, Safety and Transport, Safety Research. DTU Technical University of Denmark, Denmak.ORCID iD: 0000-0002-7874-2405
DTU Technical University of Denmark, Denmak.
DTU Technical University of Denmark, Denmak.
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2020 (English)In: Fire and Materials, ISSN 0308-0501, E-ISSN 1099-1018, Vol. 44, no 7, p. 966-974Article in journal (Refereed) Published
Abstract [en]

A novel intumescent (carbonization, acid donor and foaming) fire retardant that mimics carbon nanotubes was introduced into bitumen roofing and characterized using cone calorimetry as the main analytical tool. The experimental results indicate that 18% (by mass) attapulgite mineral (ATTP) mixed with base bitumen decreased the peak heat release rate per unit area (pHRRPUA) by 10%. Further, incorporation of melamine coated ammonium polyphosphate (MAPP) decreased the pHRRPUA by 52% and a mixture of these (3:1, ATTP:MAPP) decreased the pHRRPUA by 25% as compared to adding CaCO3 as a filler. The residual mass loss after the cone test was also improved with up to 3%. The indication of a positive synergistic flame retardant effect of the ATTP-MAPP mixture is supported by thermogravimetric analysis. The addition of this rod-like mineral improved the general fire retardant properties of the base bitumen and increased the viscosity. Therefore, the polymer-modified bitumen with both fire retardant and rheological properties (providing mechanical strength) is a promising novel approach in the design of bitumen roofing membranes. 

Place, publisher, year, edition, pages
John Wiley and Sons Ltd , 2020. Vol. 44, no 7, p. 966-974
Keywords [en]
cone calorimetry, fire retardant, intumescent fire retardant, melamine coated ammonium polyphosphate, polymer-modified bitumen, thermogravimetric analysis, Calcite, Calcium carbonate, Carbonization, Filled polymers, Fillers, Fires, Mixtures, Plastic coatings, Roofs, Ammonium polyphosphates, Analytical tool, Peak heat release rates, Rheological property, Roofing membranes, Synergistic flame retardants, Bituminous materials
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-47694DOI: 10.1002/fam.2899Scopus ID: 2-s2.0-85089466051OAI: oai:DiVA.org:ri-47694DiVA, id: diva2:1463256
Note

Funding details: Innovationsfonden, 79‐2012‐1; Funding text 1: The authors appreciate the support from Innovation Fund Denmark (Grant No. 79‐2012‐1) for the financial support of the Safe Flame Retardants (SRF) project.

Available from: 2020-09-01 Created: 2020-09-01 Last updated: 2021-01-12Bibliographically approved

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Mindykowski, Pierrick

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