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Chemistry of corrosion products of Zn and MgZn pure phases under atmospheric conditions
RISE - Research Institutes of Sweden, Materials and Production, KIMAB. Université de Bretagne Occidentale, France. (Institut de la Corrosion)
Université de Bretagne Occidentale, France.
Université de Bretagne Occidentale, France.
RISE - Research Institutes of Sweden, Materials and Production, KIMAB. (Institut de la Corrosion)
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2012 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 65, p. 178-186Article in journal (Refereed) Published
Abstract [en]

We present a corrosion behaviour study of pure phases of zinc and zinc-magnesium contaminated with NaCl and exposed to humid air for 30days: Zn, Mg 2Zn 11 and MgZn 2. The composition of corrosion products is analysed using infrared spectroscopy (FTIR), X-ray diffraction (XRD), ion chromatography (IC), and X-ray photoelectron spectroscopy (XPS). The improved corrosion stability of MgZn 2 is found to be connected to changes in the surface pH and to the nature of the formed corrosion products. The presence of magnesium modifies the proportion of the OH and CO 3 bonds in the corroded products. This explains the improvement in corrosion resistance.

Place, publisher, year, edition, pages
2012. Vol. 65, p. 178-186
Keywords [en]
A. Magnesium, A. Zinc, B. IR spectroscopy, B. XPS, B. XRD, C. Atmospheric corrosion, Atmospheric conditions, Corrosion behaviour, Corrosion products, Corrosion stability, FTIR, Humid air, XRD, Atmospheric chemistry, Atmospheric corrosion, Corrosion resistance, Fourier transform infrared spectroscopy, Magnesium, Photoelectrons, Sodium chloride, X ray diffraction, X ray photoelectron spectroscopy, Zinc
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:ri:diva-40411DOI: 10.1016/j.corsci.2012.08.014Scopus ID: 2-s2.0-84867234475OAI: oai:DiVA.org:ri-40411DiVA, id: diva2:1361438
Available from: 2019-10-16 Created: 2019-10-16 Last updated: 2019-10-16Bibliographically approved

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