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Surface Charge Influence on the Phase Separation and Viscosity of Cellulose Nanocrystals
RISE - Research Institutes of Sweden, Biovetenskap och material, Yta, process och formulering. The Hebrew University of Jerusalem, Israel.
The Hebrew University of Jerusalem, Israel.
The Hebrew University of Jerusalem, Israel.
McGill University, Canada.
Vise andre og tillknytning
2018 (engelsk)Inngår i: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 34, nr 13, s. 3925-3933Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

counterions in the suspensions. The results suggest that there is a threshold surface charge density (∼0.3%S) above which effective volume considerations are dominant across the concentration range relevant to liquid crystalline phase formation. Above this threshold value, phase separation occurs at the same effective volume fraction of CNCs (∼10 vol %), with a corresponding increase in critical concentration due to the decrease in effective diameter that occurs with increasing surface charge. Below or near this threshold value, the formation of end-to-end aggregates may favor gelation and interfere with ordered phase formation.

sted, utgiver, år, opplag, sider
2018. Vol. 34, nr 13, s. 3925-3933
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URN: urn:nbn:se:ri:diva-33532DOI: 10.1021/acs.langmuir.7b04127PubMedID: 29513998Scopus ID: 2-s2.0-85044872380OAI: oai:DiVA.org:ri-33532DiVA, id: diva2:1193381
Tilgjengelig fra: 2018-03-26 Laget: 2018-03-26 Sist oppdatert: 2019-01-10bibliografisk kontrollert

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