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Facing the rain after the phase out: Performance evaluation of alternative fluorinated and non-fluorinated durable water repellents for outdoor fabrics
Stockholm University, Sweden.ORCID-id: 0000-0001-8001-6851
RISE - Research Institutes of Sweden (2017-2019), Material och produktion, IVF.
RISE - Research Institutes of Sweden (2017-2019), Material och produktion, IVF.
RISE - Research Institutes of Sweden (2017-2019), Material och produktion, IVF.ORCID-id: 0000-0001-6857-3364
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2018 (Engelska)Ingår i: Chemosphere, ISSN 0045-6535, E-ISSN 1879-1298, Vol. 193, s. 675-684Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Fluorinated durable water repellent (DWR) agents are used to obtain water and stain repellent textiles. Due to the on-going phase-out of DWRs based on side-chain fluorinated polymers (SFP) with “long” perfluoroalkyl chains, the textile industry lacks suitable alternatives with comparable material characteristics. The constant development and optimization of SFPs for textile applications initiated more than half a century ago has resulted in a robust and very efficient DWR-technology and textiles with exceptional hydro- and oleo-phobic properties. The industry is now in the predicament that the long-chain SFPs with the best technical performance have undesirable toxicological and environmental behaviour. This study provides a comprehensive overview of the technical performance of presently available fluorinated and non-fluorinated DWRs as part of a chemical alternatives assessment (CAA). The results are based on a study with synthetic outdoor fabrics treated with alternative DWRs and tested for repellency using industrial standard and complementary methods. Using this approach, the complex structure-property relationships of DWR-polymers could be explained on a molecular level. Both short-chain SFPs and non-fluorinated DWRs showed excellent water repellency and durability in some cases while short-chain SFPs were the more robust of the alternatives to long-chain SFPs. A strong decline in oil repellency and durability with perfluoroalkyl chain length was shown for SFP DWRs. Non-fluorinated alternatives were unable to repel oil, which might limit their potential for substitution in textile application that require repellency towards non-polar liquids.

Ort, förlag, år, upplaga, sidor
2018. Vol. 193, s. 675-684
Nyckelord [en]
Chemical alternatives assessment, Per- and polyfluoroalkyl substances outdoor apparel, Water repellency, Oil repellency, Sustainability
Nationell ämneskategori
Textil-, gummi- och polymermaterial Annan kemi
Identifikatorer
URN: urn:nbn:se:ri:diva-32822DOI: 10.1016/j.chemosphere.2017.11.027Scopus ID: 2-s2.0-85035352098OAI: oai:DiVA.org:ri-32822DiVA, id: diva2:1162191
Tillgänglig från: 2017-12-04 Skapad: 2017-12-04 Senast uppdaterad: 2023-06-08Bibliografiskt granskad

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Schellenberger, SteffenHanning, Anne-CharlotteRoos, Sandra

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