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Surfactants in heterophase polymerization: A study of film formation using atomic force microscopy
YKI – Ytkemiska institutet.
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1997 (Engelska)Ingår i: Journal of Applied Polymer Science, ISSN 0021-8995, E-ISSN 1097-4628, Vol. 66, s. 187-198Artikel i tidskrift (Refereegranskat)
Abstract [en]

Film formation of three different latices was studied using atomic force microscopy. The latices were made from a mixture of butyl acrylate, styrene and acrylic acid using either a polymerizable or an unreactive aionic surfactant as emulsifier. Sodium 11-crotonoyloxyundecan- 1-ylsulfate and sodium-3-(sulfopropyl)tetradecylmaleate were used as reactive surfactant and the unreactive surfactant was sodium dodecylsulfate (SDS). The conventional surfactant was found to migrate to the surface of the latex film to a much greater extent than the reactive surfactants; however, also the latter were incompletely anchored to the particle. The maleate surfactant was bound to a higher degree than the crotonate, a finding which is in line with the relative reactivities of the two surfactants.

Ort, förlag, år, upplaga, sidor
1997. Vol. 66, s. 187-198
Nyckelord [en]
Reactive surfactant, polymerizable surfactant, atomic force microscopy, latex, film formation
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Naturvetenskap
Identifikatorer
URN: urn:nbn:se:ri:diva-26633OAI: oai:DiVA.org:ri-26633DiVA, id: diva2:1053636
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A1132Tillgänglig från: 2016-12-08 Skapad: 2016-12-08 Senast uppdaterad: 2017-11-29Bibliografiskt granskad

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