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Synthesis of unsaturated polyesters for improved interfacial strength in carbon fibre composites
Royal Institute of Technology (KTH).
RISE, Swerea, Swerea SICOMP AB.
LM Glasfiber A/S.
Aalborg University.
2002 (Engelska)Ingår i: Composites. Part A, Applied science and manufacturing, ISSN 1359-835X, E-ISSN 1878-5840, Vol. 33, nr 9, s. 1239-1252Artikel i tidskrift (Refereegranskat)
Abstract [en]

Carbon fibres are gaining use as reinforcement in glass fibre/polyester composites for increased stiffness as a hybrid composite. The mechanics and chemistry of the carbon fibre-polyester interface should be addressed to achieve an improvement also in fatigue performance and off-axis strength. To make better use of the versatility of unsaturated polyesters in a carbon fibre composite, a set of unsaturated polyester resins have been synthesized with different ratios of maleic anhydride, o-phthalic anhydride and 1,2-propylene glycol as precursors. The effective interfacial strength was determined by micro-Raman spectroscopy of a single-fibre composite tested in tension. The interfacial shear strength with untreated carbon fibres increased with increasing degree of unsaturation of the polyester, which is controlled by the relative amount of maleic anhydride. This can be explained by a contribution of chemical bonding of the double bonds in the polymer to the functional groups of the carbon fibre surface. © 2002 Elsevier Science Ltd. All rights reserved.

Ort, förlag, år, upplaga, sidor
2002. Vol. 33, nr 9, s. 1239-1252
Nyckelord [en]
A. Carbon fibre, B. Interface/interphase, B. Stress transfer, Chemistry
Nationell ämneskategori
Materialteknik
Identifikatorer
URN: urn:nbn:se:ri:diva-13215DOI: 10.1016/S1359-835X(02)00077-5OAI: oai:DiVA.org:ri-13215DiVA, id: diva2:973411
Tillgänglig från: 2016-09-22 Skapad: 2016-09-22 Senast uppdaterad: 2017-11-21Bibliografiskt granskad

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Förlagets fulltexthttp://www.sciencedirect.com/science/article/pii/S1359835X02000775
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Composites. Part A, Applied science and manufacturing
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