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Nanorheological studies of xanthan/water solutions using magnetic nanoparticles
RISE - Research Institutes of Sweden, ICT, Acreo.
RISE - Research Institutes of Sweden, ICT, Acreo.
RISE - Research Institutes of Sweden, ICT, Acreo.
RISE - Research Institutes of Sweden, ICT, Acreo.
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2019 (Engelska)Ingår i: Journal of Magnetism and Magnetic Materials, ISSN 0304-8853, E-ISSN 1873-4766, Vol. 473, s. 268-271Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

We show results of nanorheological studies of different concentrations of xanthan (non-Newtonian fluid) in water using magnetic nanoparticles (MNPs) together with the AC susceptibility (ACS) vs frequency method. For comparison we also show the ACS response for different concentrations of glycerol in water (Newtonian fluid). The ACS response is measured, and the data is modelled using dynamic magnetic models and different viscoelastic models. We study the ACS response (in-phase and out-of-phase ACS components) at different concentrations of xanthan in water (up to 1 wt% xanthan) and with a constant concentration of MNPs. We use MNP systems that show Brownian relaxation (sensitive to changes in the environmental properties around the MNPs). ACS measurements are performed using the DynoMag system. The Brownian relaxation of the MNP system peak is shifting down in frequency and the ACS response is broadening and decreases due to changes in the viscoelastic properties around the MNPs in the xanthan solution. The viscosity and the storage moduli are determined at each excitation frequency and compared with traditional macroscopic small amplitude oscillatory shear rheological measurements. The results from the traditional rheological and nanorheological measurements correlate well at higher xanthan concentration.

Ort, förlag, år, upplaga, sidor
Elsevier B.V. , 2019. Vol. 473, s. 268-271
Nyckelord [en]
AC susceptibility, Brownian relaxation, Glycerol, Magnetic multi-core nanoparticles, Nanorheological measurements, Xanthan, Brownian movement, Digital storage, Magnetic susceptibility, Nanoparticles, Non Newtonian flow, Non Newtonian liquids, Rheology, Viscoelasticity, Ac susceptibility (ACS), Brownian relaxations, Magnetic nano-particles, Magnetic nanoparti cles (MNPs), Multi core, Viscoelastic properties, Nanomagnetics
Nationell ämneskategori
Naturvetenskap
Identifikatorer
URN: urn:nbn:se:ri:diva-35560DOI: 10.1016/j.jmmm.2018.09.103Scopus ID: 2-s2.0-85055085870OAI: oai:DiVA.org:ri-35560DiVA, id: diva2:1261060
Anmärkning

; Funding details: Svenska Forskningsrådet Formas; Funding details: 2016-00253, Svenska Forskningsrådet Formas; Funding text: The authors acknowledge Josefine Mosser for assistance with experimental work. This project receives funding from The Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning ( FORMAS ) under grant number 2016-00253 .

Tillgänglig från: 2018-11-06 Skapad: 2018-11-06 Senast uppdaterad: 2019-06-27Bibliografiskt granskad

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Blomgren, JakobStading, MatsJohansson, Christer

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Blomgren, JakobStading, MatsJohansson, Christer
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Journal of Magnetism and Magnetic Materials
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