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Surface forces between water-plasma-modified mica surfaces in solutions of non-ionic surfactant
RISE., SP – Sveriges Tekniska Forskningsinstitut, SP Sveriges tekniska forskningsinstitut, YKI – Ytkemiska institutet.
1994 (Engelska)Ingår i: Colloids and Surfaces A: Physicochemical and Engineering Aspects, ISSN 0927-7757, E-ISSN 1873-4359, Vol. 83, s. 121-128Artikel i tidskrift (Refereegranskat)
Abstract [en]

The results of surface force measurements between water-plasma-modified mica surfaces in solution as a function of non-ionic surfactant (pentaoxyethylene dodecyl ether) concentration are presented. In the absence of surfactant the forces are purely repulsive and characteristic of silica in that there is an electrostatic repulsion and a repulsive deviation from DLVO theory at short separations. Only a slight decrease in the range of the extra repulsion was observed when the surfactant concentration was brought to one-third of the CMC. There was no significant effect on the surface force until the concentration was slightly higher than the CMC at which point a small amount of material became trapped between the surfaces and a small adhesion was observed. After a long equilibration period a long-range, hysteretic but reproducible force was observed. It is speculated that this force might be due to a local surface-induced phase transition. The forces measured in this system are compared with those measured between real silica surfaces.

Ort, förlag, år, upplaga, sidor
1994. Vol. 83, s. 121-128
Nyckelord [en]
Adsorption, non-ionic surfactant, plasma modification, surface forces
Nationell ämneskategori
Naturvetenskap
Identifikatorer
URN: urn:nbn:se:ri:diva-26473OAI: oai:DiVA.org:ri-26473DiVA, id: diva2:1053475
Anmärkning
A909Tillgänglig från: 2016-12-08 Skapad: 2016-12-08 Senast uppdaterad: 2020-12-01Bibliografiskt granskad

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