Relationship between rheological and morphological characteristics of cellulose nanofibrils in dilute dispersionsVise andre og tillknytning
2019 (engelsk)Inngår i: Carbohydrate Polymers, ISSN 0144-8617, E-ISSN 1879-1344, artikkel-id 115588Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]
The morphology of cellulose nanofibrils (CNFs), the rheological characteristics of their dispersions, and the corresponding relationships, are fundamental for understanding the properties of the material. This work aims at understanding how the morphological characteristics of the CNFs affect the rheology of the dispersions in the dilute region and to establish a relationship between both properties. A strong relationship was observed between the intrinsic viscosity of the CNF dispersions and their aspect ratio, which can be correlated through the expression ρ[η]=0.051p1.85. When comparing the model obtained in this work to the wormlike chain model, it was possible to verify that these models are independent of the flexibility of the CNFs. Regarding the fibrillation process, the dynamic viscosity only reflects part of the behavior of the morphological properties of the CNFs and does not provide reliable data that would allow these characteristics to be inferred, while the intrinsic viscosity does allow this relationship.
sted, utgiver, år, opplag, sider
Elsevier Ltd , 2019. artikkel-id 115588
Emneord [en]
Aspect ratio, Cellulose nanofibrils, Intrinsic viscosity, Morphology, Rheology
HSV kategori
Identifikatorer
URN: urn:nbn:se:ri:diva-42080DOI: 10.1016/j.carbpol.2019.115588Scopus ID: 2-s2.0-85075840651OAI: oai:DiVA.org:ri-42080DiVA, id: diva2:1379203
Merknad
Funding details: CONICYT/FONDAP/15130015, AFB170001; Funding text 1: We thank Innova Chile, Santiago, Chile (project 17COTE-72514), UDT (project CONICYT PIA/APOYO CCTE AFB170007), and the ASIF laboratory (Department of Chemical Engineering, University of Concepcion). FB acknowledges the support of CONICYT/PIA/Concurso Apoyo a Centros Científicos y Tecnológicos de Excelencia con Financiamiento Basal AFB170001 and CRHIAM , project CONICYT/FONDAP/15130015. Appendix A
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