Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Modeling of bottle-brush polymer adsorption onto mica and silica surfaces: Effect of side-chain length
RISE, SP – Sveriges Tekniska Forskningsinstitut, SP Sveriges tekniska forskningsinstitut, YKI – Ytkemiska institutet.
2010 (English)In: Macromolecules, ISSN 0024-9297, E-ISSN 1520-5835, Vol. 43, no 4, p. 2076-2083Article in journal (Refereed)
Abstract [en]

Adsorption of a series of charged bottle-brush polymers with side chains of different length on solid surfaces is modeled using a lattice mean-field theory. The bottle-brush polymers are modeled Lis being composed of two types of main-chain segments: charged segments and uncharged segments with ill attached side chain. The composition variable X denotes the percentage of charged main-chain segments and ranges from X = 0 (uncharged bottle-brush polymer) to X = 100 (linear polyelectrolyte). Two types of surfaces are considered: mica-like and silica-like. The mica-like surface possesses a constant negative surface charge density and no nonelectrostatic affinity for either main-chain or side-chain segments, whereas the silica-like Surface has a constant negative surface potential and a positive affinity for the side chains of the bottle-brush polymers. With the mica-like Surface. ill low X the surface excess becomes smaller and at X >= 25 it becomes larger with increasing side-chain length. Hence, the value of X at which the surface excess displays a maximum increases with the side-chain length. However, with the silica-like Surface the surface excess increases with increasing side-chain length at all X < 100, and the maximum of the surface excess appears at X approximate to 10 independent of the side-chain length.

Place, publisher, year, edition, pages
2010. Vol. 43, no 4, p. 2076-2083
Keywords [en]
Modeling of bottle-brush polymer adsorption onto mica and silica surfaces: Effect of side-chain length
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:ri:diva-27303DOI: 10.1021/ma902577mOAI: oai:DiVA.org:ri-27303DiVA, id: diva2:1054307
Note
A2071Available from: 2016-12-08 Created: 2016-12-08 Last updated: 2020-12-01Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full text
By organisation
YKI – Ytkemiska institutet
In the same journal
Macromolecules
Natural Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 36 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf